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    • 2. 发明授权
    • Process for producing an acrylic fiber having high fiber characteristics
    • 具有高纤维特性的丙烯酸纤维的制造方法
    • US4902452A
    • 1990-02-20
    • US78510
    • 1987-07-28
    • Yoshihiro NishiharaYoshifumi FurutaniMasaaki ToramaruToshiyuki Yasunaga
    • Yoshihiro NishiharaYoshifumi FurutaniMasaaki ToramaruToshiyuki Yasunaga
    • D01D5/06D01F6/18
    • D01F6/18D01D5/06
    • A process for producing an acrylic fiber comprising the steps of:(a) dissolving a polymer having a weight-average molecular weight of at least 5.times.10.sup.5 and containing at least 80 wt. % acrylonitrile in a solvent comprising dimethylformamide or dimethylacetamide at a polymer concentration of 5-15 wt. % to provide a spinning solution having a viscosity of 500-1,500 poises at 45.degree. C.;(b) extruding the solution into a gaseous medium to form filaments;(c) introducing the filaments into a coagulation bath comprising water and at least one of dimethylformamide and dimethylacetamide at 0.degree. C. or below; and(d) stretching the coagulated filaments to a draw ratio of at least 3 to provide an acrylic fiber having at least 90% X-ray orientation and an X-ray crystallinity parameter of up to 1 degree. The resulting acrylic fiber has high strength and high modulus.
    • 一种制备丙烯酸纤维的方法,包括以下步骤:(a)将重均分子量为至少5×10 5,含有至少80重量% %丙烯腈在包含二甲基甲酰胺或二甲基乙酰胺的溶剂中,聚合物浓度为5-15wt。 以提供在45℃下具有500-1,500泊的粘度的纺丝溶液。 (b)将溶液挤出到气态介质中以形成长丝; (c)在0℃或更低的温度下将细丝引入包含水和至少一种二甲基甲酰胺和二甲基乙酰胺的凝结浴中; 和(d)将凝固的细丝拉伸至3的拉伸比,以提供具有至多1度的至少90%X射线取向和X射线结晶度参数的丙烯酸类纤维。 得到的丙烯酸纤维具有高强度和高模量。