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    • 3. 发明授权
    • Halogen-containing resin lens material
    • 含卤素树脂镜片材料
    • US4704006A
    • 1987-11-03
    • US823832
    • 1986-01-29
    • Teruo SakagamiYasufumi FujiiNaohiro Murayama
    • Teruo SakagamiYasufumi FujiiNaohiro Murayama
    • C08F220/30G02B1/04
    • C08F220/30G02B1/04
    • A halogen-containing resin lens material, having a refractive index of n.sub.D =1.55 or higher, an Abbe number of 27 or higher and good dyeable property and comprising a copolymer containing 10 to 90 wt. % of a monomer (I) represented by the formula (I) shown below: ##STR1## wherein: R.sup.1 represents hydrogen or CH.sub.3 group; X.sup.1 a halogen atom except for fluorin; and p the number of substituted halogens which is an integer selected from 1 to 5, and n is an integer selected from 1 to 4, R.sup.1 existing in plural number and being either identical or different, X.sup.1 when existing in plural number being either identical or different and 10 to 70 wt. % of a crosslinking monomer having two or more polymerizable functional groups (the percentages being based on the copolymer weight).
    • 折射率为nD = 1.55以上,阿贝数为27以上,可染性良好的含卤素树脂透镜材料,含有10〜90重量%的共聚物。 (I)表示的单体(I)的%:(I)其中:R1表示氢或CH3组; X1除氟以外的卤素原子; p是选自1至5的整数的取代卤素的数目,n是选自1至4的整数,R1多个并且相同或不同,当存在多个相同或相同时,X1 不同的和10至70wt。 具有两个或更多个可聚合官能团的交联单体的%(百分比基于共聚物重量)。
    • 4. 发明授权
    • Halogen-containing lens material
    • US4578445A
    • 1986-03-25
    • US716460
    • 1985-03-27
    • Teruo SakagamiYasufumi FujiiNaohiro Murayama
    • Teruo SakagamiYasufumi FujiiNaohiro Murayama
    • C08F20/00C08F20/22C08F20/26C08F20/30C08F220/00C08F220/28C08F220/30C08F290/00C08F299/02G02B1/04C08F220/22
    • C08F220/30C08F220/28G02B1/04
    • A lens material having a refractive index n.sub.D.sup.20 of at least 1.57 or more and an Abbe's number .nu. of at least 30, comprising: a copolymer comprising (I) 10 to 85% by weight of a halogen-containing monomer represented by the following formula (1), (II) 15 to 90% by weight of a halogen-containing monomer represented by the following formula (2), and (III) 0 to 20% by weight of a monomer copolymerizable with the above mentioned monomers, the composition of the copolymer being based on the total quantity of the monomers (I), (II), and (III): ##STR1## wherein: D represents ##STR2## in which n represents an integer selected from the group consisting of 0, 1, and 2; each R.sup.1 represents hydrogen or a methyl group; Y represents CHOH; and r represents 0 or 1; each of X.sup.1 and X.sup.2 represents, independently from each other, a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and a hydroxyl group (OH group), with the proviso that the number of substitution of the OH group is only one; X.sup.3 represents a methyl group in which one through three of the hydrogen atoms are substituted by a member selected from the group consisting of bromine, iodine and D, with the proviso that the number of substitution of D is only one; wherein at least one of X.sup.1, X.sup.2, and X.sup.3 contains at least one bromine or iodine; ##STR3## wherein: each R.sup.2 represents hydrogen or a methyl group; p represents an integer selected from the group consisting of 0, 1, 2, and 3; X.sup.4 represents bromine or iodine; and q represents an integer selected from the group consisting of 1, 2, 3, 4, and 5.An example of the copolymer is 1-methacryloxy-2,2-di(bromomethyl)-3-bromopropane/methacryloxypolyethyoxy-2,4,6-tribromobenzene/styrene/divinylbenzene having a n.sub.D.sup.20 of 1.596 and a .nu. of 35.3.