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1. 发明申请

WO2004107045A3 METHODS OF CREATING PATTERNS ON SUBSTRATES AND ARTICLES OF MANUFACTURE RESULTING THEREFROM 审中-公开
公开(公告)号：WO2004107045A3
公开(公告)日：2004-12-09
申请号：PCT/US2004/016016
申请日：2004-05-21
申请人： AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH , THE REGENTS OF THE UNIVERSITY OF MICHIGAN , BAO, Lirong , TAN, Li , HUANG, Xudong , KONG, Yen, Peng , GUO, Lingjie, Jay , PANG, Stella, W. , YEE, Albert
发明人： BAO, Lirong , TAN, Li , HUANG, Xudong , KONG, Yen, Peng , GUO, Lingjie, Jay , PANG, Stella, W. , YEE, Albert
IPC分类号： B05D3/10
摘要： Methods of creating patterns on substrates are presented, and articles of manufacture resulting therefrom. One method comprises applying a first surface energy modifier (18) to an applicator (16) to form a coating on the applicator; contacting the coating (18) with a receiving member (4), the receiving member having a topography, the coating only contacting and remaining on at least some protrusions (8); exposing the first modified receiving member (22) to a second surface energy modifier (21), thereby forming a second modified receiving member (24) having surface modified recesses; applying a composition (26) comprising a polymeric material to the second modified receiving member (24), the composition substantially conforming to the topography of the surface modified protrusion's (8) and the surface modified recesses; and contacting the composition-coated, surface modified protrusions with a substrate (11) for a time and under conditions sufficient to transfer the polymeric material (26) on protrusions to the substrate (11). Because the surface energy of the sidewalls is lower than that on the protrusions, polymer dewetting from the sidewalls is promoted, which makes the polymer film discontinuous along the edges of patterns. Therefore, inked polymer patterns from the protrusions of the mold show very smooth edges and smaller dimensions compared to that of the mold.

2. 发明申请

WO2004107403A3 IMPRINTING POLYMER FILM ON PATTERNED SUBSTRATE 审中-公开
公开(公告)号：WO2004107403A3
公开(公告)日：2004-12-09
申请号：PCT/US2004/015889
申请日：2004-05-20
申请人： THE REGENTS OF THE UNIVERSITY OF MICHIGAN , TAN, Li , KONG, Yen-Peng , PANG, Stella, W. , YEE, Albert, F.
发明人： TAN, Li , KONG, Yen-Peng , PANG, Stella, W. , YEE, Albert, F.
IPC分类号： B05D5/12
摘要： A method of applying a pattern on a topography (18) includes first applying a polymer film (10) to an elastomer member (14), such as PDMS, to form a pad (12). The pad (12) is then applied to a substrate having a varying topography (18) under pressure. The polymer film (1) is transferred to the substrate due to the plastic deformation of the polymer film (10) under pressure compared to the elastic deformation of the elastomer member (14) of the pad. Thus, upon removal of the pad (12) from the substrate, the elastic member (14) pulls away from the polymer layer (10) , thereby depositing the polymer layer (1) upon the substrate.

3. 发明申请

WO2004107045A2 METHODS OF CREATING PATTERNS ON SUBSTRATES AND ARTICLES OF MANUFACTURE RESULTING THEREFROM 审中-公开
标题翻译：基板上形成图案的方法及其制造方法
公开(公告)号：WO2004107045A2
公开(公告)日：2004-12-09
申请号：PCT/US2004016016
申请日：2004-05-21
申请人： AGENCY SCIENCE TECH & RES , UNIV MICHIGAN , BAO LIRONG , TAN LI , HUANG XUDONG , KONG YEN PENG , GUO LINGJIE JAY , PANG STELLA W , YEE ALBERT
发明人： BAO LIRONG , TAN LI , HUANG XUDONG , KONG YEN PENG , GUO LINGJIE JAY , PANG STELLA W , YEE ALBERT
IPC分类号： B05D3/10 , B29C33/00 , B44C1/165 , B44C3/08 , C03C17/30 , G03F20060101 , G03F7/00 , G03F
CPC分类号： G03F7/0002 , B82Y10/00 , B82Y30/00 , B82Y40/00
摘要： Methods of creating patterns on substrates are presented, and articles of manufacture resulting therefrom. One method comprises applying a first surface energy modifier (18) to an applicator (16) to form a coating on the applicator; contacting the coating (18) with a receiving member (4), the receiving member having a topography, the coating only contacting and remaining on at least some protrusions (8); exposing the first modified receiving member (22) to a second surface energy modifier (21), thereby forming a second modified receiving member (24) having surface modified recesses; applying a composition (26) comprising a polymeric material to the second modified receiving member (24), the composition substantially conforming to the topography of the surface modified protrusion's (8) and the surface modified recesses; and contacting the composition-coated, surface modified protrusions with a substrate (11) for a time and under conditions sufficient to transfer the polymeric material (26) on protrusions to the substrate (11). Because the surface energy of the sidewalls is lower than that on the protrusions, polymer dewetting from the sidewalls is promoted, which makes the polymer film discontinuous along the edges of patterns. Therefore, inked polymer patterns from the protrusions of the mold show very smooth edges and smaller dimensions compared to that of the mold.
摘要翻译：呈现在基板上形成图案的方法以及由此产生的制品。一种方法包括将第一表面能量调节剂（18）施加到施用器（16）上以在施用器上形成涂层; 使所述涂层（18）与接收构件（4）接触，所述接收构件具有形貌，所述涂层仅接触并保留在至少一些突起（8）上; 将第一改进的接收构件（22）暴露于第二表面能量改性剂（21），从而形成具有表面改性凹槽的第二改进的接收构件（24）; 将包含聚合物材料的组合物（26）施加到第二改性接收构件（24）上，该组合物基本上符合表面改性突起（8）和表面改性凹槽的形貌; 并且使组合物涂覆的表面改性的突起与衬底（11）接触足以将突起上的聚合物材料（26）转移到衬底（11）上的时间和条件。由于侧壁的表面能低于突起上的表面能，因此促进了从侧壁的聚合物去湿，这使得聚合物膜沿着图案的边缘不连续。因此，与模具相比，来自模具的凸起的上色聚合物图案显示出非常光滑的边缘和更小的尺寸。

4. 发明申请

WO2003096123A1 REVERSAL IMPRINT TECHNIQUE 审中-公开
标题翻译：反向印刷技术
公开(公告)号：WO2003096123A1
公开(公告)日：2003-11-20
申请号：PCT/SG2002/000084
申请日：2002-05-08
申请人： INSTITUTE OF MATERIALS RESEARCH AND ENGINEERING , THE REGENTS OF THE UNIVERSITY OF MICHIGAN , HUANG, Xudong , BAO, Li-Rong , CHENG, Xing , GUO, Lingjie, J. , PANG, Stella, W. , YEE, Albert, F.
发明人： HUANG, Xudong , BAO, Li-Rong , CHENG, Xing , GUO, Lingjie, J. , PANG, Stella, W. , YEE, Albert, F.
IPC分类号： G03F7/00
CPC分类号： G03F7/0002 , B29C33/42 , B82Y10/00 , B82Y40/00 , H05K3/0079 , Y10T428/24802
摘要： The present invention relates to a method for imprinting a micro-/nano-structure on a substrate, the method comprising (a) providing a mold containing a desired pattern or relief for a microstructure; (b) applying a polymer coating to the mold; and (c) transferring the polymer coating from the mold to a substrate under suitable temperature and pressure conditions to form an imprinted substrate having a desired micro-/nano-structure thereon.
摘要翻译：本发明涉及一种用于将微/纳米结构压印在基底上的方法，所述方法包括（a）提供含有微结构的所需图案或凹凸的模具; （b）将聚合物涂层施加到模具上; 和（c）在合适的温度和压力条件下将聚合物涂层从模具转移到基底上以形成其上具有所需微/纳米结构的印迹基底。

5. 发明申请

WO03096123A8 REVERSAL IMPRINT TECHNIQUE 审中-公开
标题翻译：反向印刷技术
公开(公告)号：WO03096123A8
公开(公告)日：2004-04-29
申请号：PCT/SG0200084
申请日：2002-05-08
申请人： INST MATERIALS RESEARCH & ENG , UNIV , HUANG XUDONG , BAO LI-RONG , CHENG XING , GUO LINGJIE J , PANG STELLA W , YEE ALBERT F
发明人： HUANG XUDONG , BAO LI-RONG , CHENG XING , GUO LINGJIE J , PANG STELLA W , YEE ALBERT F
IPC分类号： B29C33/42 , B81C1/00 , G03F7/00 , H01L21/027 , H05K3/00 , B41M1/06 , B41M1/26 , B41M1/28 , B41M1/30 , B41M1/34 , B81B7/00 , B82B1/00
CPC分类号： G03F7/0002 , B29C33/42 , B82Y10/00 , B82Y40/00 , H05K3/0079 , Y10T428/24802
摘要： The present invention relates to a method for imprinting a micro-/nano-structure on a substrate, the method comprising (a) providing a mold containing a desired pattern or relief for a microstructure; (b) applying a polymer coating to the mold; and (c) transferring the polymer coating from the mold to a substrate under suitable temperature and pressure conditions to form an imprinted substrate having a desired micro-/nano-structure thereon.
摘要翻译：本发明涉及一种用于将微/纳米结构压印在基底上的方法，所述方法包括（a）提供含有微结构的所需图案或凹凸的模具; （b）将聚合物涂层施加到模具上; 和（c）在合适的温度和压力条件下将聚合物涂层从模具转移到基底上以形成其上具有所需微/纳米结构的印迹基底。

6. 发明申请

WO2005113422A1 IMPRINTING OF SUPPORTED AND FREE-STANDING 3-D MICRO-OR NANO-STRUCTURES 审中-公开
标题翻译：支持和自由置换三维微结构或纳米结构
公开(公告)号：WO2005113422A1
公开(公告)日：2005-12-01
申请号：PCT/SG2005/000159
申请日：2005-05-24
申请人： AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH , THE REGENTS OF THE UNIVERSITY OF MICHIGAN , KONG, Yen Peng , LOW, Hong Yee , PANG, Stella, W. , YEE, Albert, F.
发明人： KONG, Yen Peng , LOW, Hong Yee , PANG, Stella, W. , YEE, Albert, F.
IPC分类号： B81C1/00
CPC分类号： A61M25/00 , B27N3/08 , B28B3/06 , B81C99/0085 , B81C2201/034 , B81C2203/032 , B81C2203/038 , B82Y10/00 , B82Y40/00 , G03F7/0002 , Y10T428/24479 , Y10T428/254
摘要： The present invention is directed to micro- and nano-scale imprinting methods and the use of such methods to fabricate supported and/or free-standing 3-D micro- and/or nano-structures of polymeric, ceramic, and/or metallic materials. In some embodiments, a duo-mold approach is employed in the fabrication of these structures. In such methods, surface treatments are employed to impart differential surface energies to different molds and/or different parts of the mold(s). Such surface treatments permit the formation of three-dimensional (3-D) structures through imprinting and the transfer of such structures to a substrate. In some or other embodiments, such surface treatments and variation in glass transition temperature of the polymers used can facilitate separation of the 3-D structures from the molds to form free-standing micro- and/or nano-structures individually and/or in a film. In some or other embodiments, a "latch-on" assembly technique is utilized to form supported and/or free-standing stacked micro- and/or nano-structures that enable the assembly of polymers without a glass transition temperature and eliminate the heating required to assemble thermoplastic polymers.
摘要翻译：本发明涉及微尺度和纳米级压印方法，并且使用这种方法来制造聚合物，陶瓷和/或金属材料的负载和/或独立的3-D微观和/或纳米结构。在一些实施例中，在制造这些结构中采用双模方法。在这种方法中，使用表面处理以将不同的表面能赋予模具的不同模具和/或模具的不同部件。这种表面处理允许通过压印形成三维（3-D）结构并将这种结构转移到基底上。在一些或其它实施方案中，所使用的聚合物的这种表面处理和玻璃化转变温度的变化可以促进3-D结构与模具的分离，以分别形成独立的和/或纳米结构，电影。在一些或其它实施方案中，使用“闭锁”组装技术来形成支撑和/或独立堆叠的微结构和/或纳米结构，其能够组装聚合物而不具有玻璃化转变温度并消除所需的加热组装热塑性聚合物。

7. 发明申请

WO2004107403A2 IMPRINTING POLYMER FILM ON PATTERNED SUBSTRATE 审中-公开
标题翻译：将聚合物薄膜压印在图案基材上
公开(公告)号：WO2004107403A2
公开(公告)日：2004-12-09
申请号：PCT/US2004015889
申请日：2004-05-20
申请人： UNIV MICHIGAN , TAN LI , KONG YEN-PENG , PANG STELLA W , YEE ALBERT F
发明人： TAN LI , KONG YEN-PENG , PANG STELLA W , YEE ALBERT F
IPC分类号： B05D5/12 , B41M3/12 , B44C1/17 , B44C1/18 , B44C1/24 , H01L20060101 , H01L
CPC分类号： B81C1/0046
摘要： A method of applying a pattern on a topography includes first applying a polymer film to an elastomer member, such as PDMS, to form a pad. The pad is then applied to a substrate having a varying topography under pressure. The polymer film is transferred to the substrate due to the plastic deformation of the polymer film under pressure compared to the elastic deformation of the PDMS member. Thus, upon removal of the pad from the substrate, the PDMS member pulls away from the polymer layer, thereby depositing the polymer layer upon the substrate.
摘要翻译：在图形上施加图案的方法包括首先将聚合物膜施加到诸如PDMS的弹性体构件上以形成垫。然后将该垫施加到在压力下具有变化的形貌的基底。与PDMS构件的弹性变形相比，由于聚合物膜在压力下的塑性变形，聚合物膜被转移到基底。因此，在从衬底移除衬垫时，PDMS构件从聚合物层拉开，从而将聚合物层沉积在衬底上。

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