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    • 1. 发明申请
    • A METHOD FOR PREPARING CATIONIC MICROGEL FOR ELECTRODEPOSITABLE COATING AND AN ELECTRODEPOSITABLE COATING COMPOSITION COMPRISING CATIONIC MICROGEL PREPARED FROM THE SAME
    • 一种制备用于电沉积涂层的阳离子微孔和包含由其制备的阳离子微孔的电沉积涂料组合物的方法
    • WO2008091082A1
    • 2008-07-31
    • PCT/KR2008/000354
    • 2008-01-21
    • KCC CORPORATIONHONG, Seok ChanKIM, Sang HunSOHN, Duck SooYANG, Han JuJUNG, Man YongLEE, Nam JuKIM, Tae Ho
    • HONG, Seok ChanKIM, Sang HunSOHN, Duck SooYANG, Han JuJUNG, Man YongLEE, Nam JuKIM, Tae Ho
    • C09D179/02
    • C09D163/00C08G59/184C08L63/00C09D5/4488C09D179/02C08L2666/22
    • The present invention relates to a method for preparing a cationic microgel for electrodepositable coating and an electrodepositable coating composition comprising cationic microgel prepared by the same method. More specifically, the present invention relates to the method for preparing a cationic microgel for electrodepositable coating and the electrodepositable coating composition comprising cationic microgel prepared from by same method, wherein the method for preparing cationic microgel for electrodepositable coating comprises the steps of (1) preparing tertiary amine salt by reacting a tertiary amine having a hydroxy group with diisocyanate followed by neutralizing the resulting mixture with acid; and (2) dispersing the tertiary amine salt resin and polyepoxy resin polymer in a dispersion media, and then reacting the tertiary amine salt resin and polyepoxy resin polymer in the presence of diamine. The cationic microgel for electrodepositable coating exhibits excellent mechanical properties when applied to electrodepositable coating. The electrodepositable coating with the cationic microgel is excellent for edge coating and provides a good smooth coating film by inhibiting the formation of craters by adequately controlling the flowability during the hardening of the coating film.
    • 本发明涉及一种制备用于电沉积涂层的阳离子微凝胶的方法和包含通过相同方法制备的阳离子微凝胶的电沉积涂料组合物。 更具体地说,本发明涉及制备用于电沉积涂层的阳离子微凝胶的方法和包含由相同方法制备的阳离子微凝胶的电沉积涂料组合物,其中用于制备用于可电沉积涂层的阳离子微凝胶的方法包括以下步骤:(1)制备 通过使具有羟基的叔胺与二异氰酸酯反应,然后用酸中和所得混合物; 和(2)将叔胺盐树脂和聚环氧树脂聚合物分散在分散介质中,然后在二胺的存在下使叔胺盐树脂和聚环氧树脂聚合物反应。 用于电沉积涂料的阳离子微凝胶当用于可电沉积涂层时表现出优异的机械性能。 具有阳离子微凝胶的电沉积涂层对于边缘涂层是优异的,并且通过适当地控制涂膜硬化期间的流动性来抑制凹坑的形成,从而提供良好的光滑涂膜。