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    • 2. 发明授权
    • Polyurethane elastomers, method of producing them and their use
    • 聚氨酯弹性体,制造方法及其用途
    • US06458866B1
    • 2002-10-01
    • US09051351
    • 1998-05-15
    • Wilhelm OppermannFrank HermanutzPeter HirtMichael SchweizerOliver Oess
    • Wilhelm OppermannFrank HermanutzPeter HirtMichael SchweizerOliver Oess
    • C08G1832
    • D01F6/70C08G18/675C08G18/676C08G18/678C08G18/679Y10S528/906
    • The invention concerns a polyurethane elastomer containing structural units of type (a), in which: the group —O—R1—O—is a macrodiol group with a molecular weight of approximately 500 to 10000, R2 is a bivalent aliphatic, cycloaliphatic and/or aliphatic-cycloaliphatic group; and X is a short-chain olefinically unsaturated group, Y is NH or O, n is an integer from 1 to 10 and m is an integer of at least 4. The invention also concerns a method of preparing this polyurethane elastomer which can be melt-spun to form fibres or melt-extruded to form foils. The fibres or foils can be exposed to energy-rich radiation such that crosslinking of the polyurethane occurs. Fibres according to the invention display superior properties in terms of textile-mechanical properties, in particular good tensile strength, elongation at tear, residual elongation and heat distortion temperature.
    • 本发明涉及含有(a)型结构单元的聚氨酯弹性体,其中:-O-R 1 -O-为分子量约500〜10000的大二醇基,R2为二价脂族,脂环族和/ 或脂肪族 - 脂环族基团; X为短链烯属不饱和基团,Y为NH或O,n为1〜10的整数,m为4以上的整数。本发明还涉及制备该聚氨酯弹性体的方法,该聚氨酯弹性体可熔融 - 纺成纤维或熔融挤出以形成箔。 纤维或箔可以暴露于能量丰富的辐射,从而发生聚氨酯的交联。 根据本发明的纤维在纺织 - 机械性能,特别是良好的拉伸强度,撕裂伸长率,残余伸长率和热变形温度方面表现出优异的性能。
    • 5. 发明授权
    • Method for producing polyurethane elastomer fibers and fibers produced according to this method
    • 根据该方法制造聚氨酯弹性体纤维和纤维的方法
    • US06485665B1
    • 2002-11-26
    • US09555829
    • 2000-07-19
    • Frank HermanutzPeter HirtOliver OessWilhelm Oppermann
    • Frank HermanutzPeter HirtOliver OessWilhelm Oppermann
    • B29C3510
    • D01F6/70Y10S528/906
    • Polyurethane elastomer fibers with superior mechanical and heat distortion properties are obtained by a method in which (a) a segmented polyurethane polymer is produced on the basis of a macro-diol, an aliphatic diisocyanate, and a chain extender with at least two hydroxy and/or amino groups, where the polymer has a molar excess of isocyanate groups over the hydroxy and/or amino groups from the macro-diol and chain extender; (b) the polyurethane polymer is melt-extruded to form a fiber; and (c) The extruded fiber is subjected to a post-treatment. Steps (a) and (b) are carried out under temperature conditions and within a time interval where essentially no allophanate will be formed, while step (c) is performed under temperature conditions and within a time interval in which the polyurethane polymer is cross-linked through the formation of allophanate.
    • 通过以下方法获得具有优异机械和热变形性能的聚氨酯弹性体纤维:其中(a)基于大分子二醇,脂族二异氰酸酯和扩链剂制备分段聚氨酯聚合物,其具有至少两个羟基和/ 或氨基,其中聚合物在大分子二醇和扩链剂的羟基和/或氨基上具有摩尔过量的异氰酸酯基团;(b)将聚氨酯聚合物熔融挤出以形成纤维; 步骤(a)和(b)在温度条件下并且在基本上不会形成脲基甲酸酯的时间间隔内进行,而步骤(c)在 在聚氨酯聚合物通过形成脲基甲酸酯交联的时间间隔内。