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1. 发明授权

US07189289B2 Cleaning agent and method for cleaning heater tubes 有权
公开(公告)号：US07189289B2
公开(公告)日：2007-03-13
申请号：US10503302
申请日：2003-02-06
申请人： Jeon-Keun Oh , Wha-Sik Min , Sam-Ryong Park , Gi-Won Park
发明人： Jeon-Keun Oh , Wha-Sik Min , Sam-Ryong Park , Gi-Won Park
IPC分类号： B08B7/02
CPC分类号： C11D7/105 , C11D11/0041 , C11D17/06
摘要： Disclosed is a cleaning agent for heater tubes, which is capable of eliminating deposits such as soot particulates in tubes installed in industrial heaters that typically use oil, coal or gas. The cleaning agent of the present invention is prepared by formulating a chemical composition comprising ammonium nitrate into pellets. Also, the present invention discloses a method of cleaning heater tubes using the cleaning agent. When being utilized for cleaning the heater tubes, the cleaning agent can improve mechanical and chemical cleaning effects, thus shortening of working time and reducing a required amount of the chemical composition, as well as preventing rapid evaporation of the chemical composition, thus increasing cleaning effect. In addition, the cleaning agent can eliminate the cementing effect of sulfur oxides or vanadic oxides in the heater tubes and thus control stably emission of NOx, by selectively containing other additives including magnesium and urea.

2. 发明授权

US07431749B2 Catalytic filter for removing soot particulates from diesel engine exhaust and method of preparing the same 有权
标题翻译：用于从柴油发动机废气中除去烟灰颗粒的催化过滤器及其制备方法
公开(公告)号：US07431749B2
公开(公告)日：2008-10-07
申请号：US10517679
申请日：2004-04-14
申请人： Yong-Woo Kim , Joon-Seok Min , Sung-Hyoan Kim , Chang-Q Lee , Wha-Sik Min
发明人： Yong-Woo Kim , Joon-Seok Min , Sung-Hyoan Kim , Chang-Q Lee , Wha-Sik Min
IPC分类号： B01D46/00 , B01D53/34 , B01D50/00 , F01N3/022
CPC分类号： B01D53/945 , B01D53/944 , B01D2255/102 , B01D2258/012 , B01J23/56 , B01J23/6525 , B01J35/0006 , B01J35/0013 , B01J35/04 , B01J37/0211 , B01J37/038 , F01N3/035 , Y02A50/2324 , Y02A50/2341 , Y02T10/22 , Y10S55/05 , Y10S55/10 , Y10S55/30
摘要： Disclosed is a catalytic filter for removing soot particulates from diesel engine exhaust, which is comprised of monolithic oxidation catalyst upstream of the catalytic filter, which effectively oxidize gaseous pollutants and volatile organic fractions, and a catalyzed wall-flow filter downstream serving to low temperature combustion of soot particulates collected on the filter. Also, the preparation method of the catalytic filter is provided, including the colloidal mixture solution of platinum group metal salts and other metal salts with a water-soluble polymer and a reducing agent, which is then impregnated on a catalyst support, followed by calcining at high temperatures. In the present invention, use of the catalytic filter provides effective means of abating diesel exhaust pollutant emissions, that is, particulate matter (PM) and gaseous pollutants (HC, CO, NOx).
摘要翻译：公开了一种用于从柴油发动机排气中除去烟灰颗粒的催化过滤器，其由催化过滤器上游的单片氧化催化剂组成，其有效地氧化气态污染物和挥发性有机馏分，以及用于低温燃烧的催化壁流过滤器的烟灰颗粒收集在过滤器上。另外，提供催化过滤器的制备方法，其中包括铂族金属盐和其它金属盐与水溶性聚合物和还原剂的胶体混合溶液，然后将其浸渍在催化剂载体上，随后在高温在本发明中，催化过滤器的使用提供了减轻柴油机尾气污染物排放的有效手段，即颗粒物质（PM）和气态污染物（HC，CO，NOx）。

3. 发明申请

US20070149432A1 Cleaning agent and method for cleaning heater tubes 审中-公开
标题翻译：清洗剂及清洗加热管的方法
公开(公告)号：US20070149432A1
公开(公告)日：2007-06-28
申请号：US11708060
申请日：2007-02-20
申请人： Jeon-Keun Oh , Wha-Sik Min , Sam-Ryong Park , Gi-Won Park
发明人： Jeon-Keun Oh , Wha-Sik Min , Sam-Ryong Park , Gi-Won Park
IPC分类号： B08B7/00 , B08B9/027 , B08B9/00 , B08B3/00
CPC分类号： B24C1/003 , B24C11/00 , B24C11/005
摘要： Disclosed is a cleaning agent for heater tubes, which is capable of eliminating deposits such as soot particulates in tubes installed in industrial heaters that typically use oil, coal or gas. The cleaning agent of the present invention is prepared by formulating a chemical composition comprising ammonium nitrate into pellets. Also, the present invention discloses a method of cleaning heater tubes using the cleaning agent. When being utilized for cleaning the heater tubes, the cleaning agent can improve mechanical and chemical cleaning effects, thus shortening of working time and reducing a required amount of the chemical composition, as well as preventing rapid evaporation of the chemical composition, thus increasing cleaning effect. In addition, the cleaning agent can eliminate the cementing effect of sulfur oxides or vanadic oxides in the heater tubes and thus control stably emission of NOx, by selectively containing other additives including magnesium and urea.
摘要翻译：公开了一种用于加热器管的清洁剂，其能够在通常使用油，煤或气体的工业加热器中安装的管中除去诸如烟灰颗粒的沉积物。通过将包含硝酸铵的化学组合物配制成粒料来制备本发明的清洁剂。此外，本发明公开了一种使用清洁剂清洗加热器管的方法。当用于清洁加热器管时，清洁剂可以改善机械和化学清洁效果，从而缩短工作时间并减少所需量的化学成分，以及防止化学成分的快速蒸发，从而增加清洁效果。此外，清洗剂可以消除加热器管中的硫氧化物或氧化钒的固结作用，从而通过选择性地包含其它添加剂包括镁和尿素来控制NO x的稳定排放。

4. 发明授权

US06790344B1 Liquid-phase adsorption process for removing and concentrating heteroatom compounds in hydrocarbons 失效
标题翻译：用于去除和浓缩烃中杂原子化合物的液相吸附方法
公开(公告)号：US06790344B1
公开(公告)日：2004-09-14
申请号：US09719463
申请日：2000-12-11
申请人： Wha-Sik Min , Sin-Young Khang , Dong-Soon Min , Jae-Wook Ryu , Kwan-Sik Yoo , Jyu-Hwan Kim
发明人： Wha-Sik Min , Sin-Young Khang , Dong-Soon Min , Jae-Wook Ryu , Kwan-Sik Yoo , Jyu-Hwan Kim
IPC分类号： C10G2102
CPC分类号： B01D15/00 , B01J20/103 , C10G25/05 , C10G2300/202 , C10G2300/4056
摘要： Disclosed is a liquid phase adsorption process for removing and concentrating heteroatom compounds in hydrocarbons (HCH), comprising the steps of adsorption, copurging and regeneration. In the adsorption step, a liquid hydrocarbon stream is fed to an adsorber, which adsorbs HCH and returns adsorption effluent. In the copurging step, HCH, which are extracted from the previous regeneration, are applied to the adsorber, displacing the copurging effluent. In the regeneration step, a polar solvent is flowed through the adsorber, purging HCH. Most of the HCH are then set aside for use in the next copuring step, while a small amount of the HCH are taken out from the process as HCH product. The present invention is economically advantageous in effectively removing HCH from hydrocarbon streams and increasing the concentration of HCH within an HCH product.
摘要翻译：公开了一种用于除去和浓缩烃（HCH）中的杂原子化合物的液相吸附方法，包括吸附，复合和再生的步骤。在吸附步骤中，将液体烃流送入吸附器，吸附HCH并返回吸附流出物。在复合步骤中，从先前的再生提取的HCH被施加到吸附器上，从而移出复合流出物。在再生步骤中，极性溶剂流过吸附器，吹扫HCH。然后将大部分HCH放置在下一个复合步骤中使用，同时将少量的HCH作为HCH产物从该方法中取出。本发明在有效地从烃流中去除HCH并增加HCH产物内HCH的浓度方面具有经济上的优势。

5. 发明授权

US06248230B1 Method for manufacturing cleaner fuels 有权
标题翻译：制造清洁燃料的方法
公开(公告)号：US06248230B1
公开(公告)日：2001-06-19
申请号：US09339639
申请日：1999-06-24
申请人： Wha-Sik Min , Kyung-Il Choi , Sin-Young Khang , Dong-Soon Min , Jae-Wook Ryu , Kwan-Sik Yoo , Jyu-Hwan Kim
发明人： Wha-Sik Min , Kyung-Il Choi , Sin-Young Khang , Dong-Soon Min , Jae-Wook Ryu , Kwan-Sik Yoo , Jyu-Hwan Kim
IPC分类号： C10G6704
CPC分类号： C10G67/06 , C10G67/04
摘要： A method is provided for manufacturing cleaner fuels, in which NPC (Natural Polar Compounds), naturally existing in small quantities within various petrolic hydrocarbon fractions, are removed from the petrolic hydrocarbon fractions ranging, in boiling point, from 110 to 560° C. and preferably from 200 to 400° C., in advance of catalytic hydroprocessing. The removal of NPC improves the efficiency of the catalytic process and produces environment-friendly products, such as diesel fuel with a sulfur content of 50 ppm (wt) or lower. Also, the NPC can be used to improve fuel lubricity.
摘要翻译：提供了一种用于制造清洁燃料的方法，其中在各种石油烃馏分中天然存在少量的NPC（天然极性化合物）从沸点为110-560℃的石油烃馏分中除去，优选为200-400℃，在催化加氢处理之前。 NPC的去除提高了催化过程的效率，并且生产了环境友好的产品，例如硫含量为50ppm（wt）或更低的柴油燃料。此外，NPC可用于提高燃油润滑性。

6. 发明授权

US5580442A Method for producing feedstocks of high quality lube base oil from unconverted oil of fuels hydrocracker operating in recycle mode 失效
标题翻译：从循环模式运行的燃料加氢裂化器的未转化油生产高质量润滑油基础油原料的方法
公开(公告)号：US5580442A
公开(公告)日：1996-12-03
申请号：US242758
申请日：1994-05-13
申请人： Sook-hyung Kwon , Wha-sik Min , Yun-kil Lee
发明人： Sook-hyung Kwon , Wha-sik Min , Yun-kil Lee
IPC分类号： C10G7/06 , C10G7/00 , C10G45/00 , C10G45/04 , C10G47/02 , C10G65/12 , C10G69/02 , C10G69/10
CPC分类号： C10G65/12
摘要： A process is disclosed for producing feedstocks for manufacturing high quality lube base oil utilizing unconverted oil, which is produced from a fuels hydrocracker unit. The first step of the process is the distillation of an atmospheric residue under vacuum in a first vacuum distillation unit to produce a vacuum gas oil. The vacuum gas oil is then hydrotreated in a first reaction unit to remove impurities and produce a treated vacuum gas oil. The treated vacuum gas oil is then subjected to hydrocracking in a second reaction unit to yield light hydrocarbons. The light hydrocarbons are then subjected to a series of fractional distillations to separate light oil products and an unconverted oil. All or a fraction of the unconverted oil is fed to a second vacuum distillation unit to produce feedstocks of high quality lube base oil and a remaining portion. The remaining portion and, optionally, a fraction of the unconverted oil is recycled from the second vacuum distillation unit to the second reaction unit.
摘要翻译：公开了一种用于生产用于制造高质量润滑油基础油的原料的方法，其利用由燃料加氢裂化器单元生产的未转化油。该方法的第一步是在真空中在第一真空蒸馏装置中蒸馏大气残留物以产生真空瓦斯油。然后将减压瓦斯油在第一反应单元中加氢处理以除去杂质并产生经处理的真空瓦斯油。然后将经处理的减压瓦斯油在第二反应单元中进行加氢裂化以产生轻质烃。然后轻质烃经受一系列分馏，以分离轻油产物和未转化的油。将未转化的油的全部或一部分进料至第二真空蒸馏装置以产生高质量润滑油基础油和剩余部分的原料。剩余部分和任选的未转化油的一部分从第二减压蒸馏单元再循环到第二反应单元。

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