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1. 发明授权

US4730020A Water-dilutable coating compositions for base coats for wet-on-wet application of clear coat on base coat 失效
标题翻译：用于底漆的水可稀释涂料组合物，用于在底漆上湿式湿涂施用透明涂层
公开(公告)号：US4730020A
公开(公告)日：1988-03-08
申请号：US833162
申请日：1986-02-27
申请人： Werner Wilfinger , Herbert Zima , Herbert Stania
发明人： Werner Wilfinger , Herbert Zima , Herbert Stania
IPC分类号： C09D5/38 , C08L57/00 , C08L61/20 , C09D125/14 , C09D133/04 , C09D133/06 , C08F20/58
CPC分类号： C09D125/14 , C09D133/066 , C08L57/00 , C08L61/20
摘要： Water-dilutable coating compositions comprising a combination of specifically selected acrylic copolymers, dissolved in a specifically defined solvent blend, combined with coloring and/or optical effect imparting pigments, and, optionally, polymer dispersions and amine resins, are described. The compositions when used as a base coat for wet-on-wet application of a multi-coat paint system exhibit excellent performance on application and give finishes with outstanding properties.
摘要翻译：描述了包含特定选择的丙烯酸共聚物，溶解在特定定义的溶剂共混物中的组合的水可稀释涂料组合物，与着色和/或光学效应赋予颜料组合，以及任选的聚合物分散体和胺树脂。当用作多层涂漆系统的湿 - 湿应用的底涂层时的组合物在应用上表现出优异的性能，并且具有优异的性能。

2. 发明授权

US4453982A Stabilized metal pigments and method of producing same 失效
标题翻译：稳定金属颜料及其制备方法
公开(公告)号：US4453982A
公开(公告)日：1984-06-12
申请号：US447098
申请日：1982-12-06
申请人： Werner Wilfinger , Klaus L. Behmel , Herbert Stania
发明人： Werner Wilfinger , Klaus L. Behmel , Herbert Stania
IPC分类号： C09C1/62 , C09C1/64 , C09C3/10 , C09C1/00
CPC分类号： C09C1/644 , C09C1/62 , C09C3/10 , C01P2004/20 , C01P2004/84
摘要： Metal pigments stabilized against chemical influences particularly for use in aqueous paint systems by blending with the reaction product of an amine-aldehyde condensation product etherified with low molecular weight alcohols and an acidic phosphoric acid derivative of the general formulaP (O) R.sub.x (OH).sub.yor a derivative of a polyphosphoric acid of the general formula[P (O) R.sub.x (OH).sub.y-z O.sub.0.5 z ]n,wherein R is a radical linked to the phosphoric or polyphosphoric acid radical through a C--P-- or C--O--P--linkage and which contains a group reactive with said amine-aldehyde condensation product; x being a number less than 3 and x+y equaling 3, z being the number of P--O--links stemming from a P-atom and being less than y, and n being the degree of polymerization.
摘要翻译：与通过与低分子量醇与通式P（O）Rx（OH）的酸性磷酸衍生物醚化的胺 - 醛缩合产物的反应产物共混而稳定化的特别用于水性涂料体系的金属颜料， y或通式[P（O）Rx（OH）y z O O）的多磷酸衍生物。

3. 发明授权

US06462124B2 Water-dilutable coating of oh-acrlylate or polyesterurethane resin and blocked acid catalyst 失效
标题翻译：水可稀释的欧酰丙酸酯或聚酯聚氨酯树脂涂料和封闭的酸催化剂
公开(公告)号：US06462124B2
公开(公告)日：2002-10-08
申请号：US09808996
申请日：2001-03-16
申请人： Werner Wilfinger , Ingo Kriessmann , Friedrich Herrmann , Angelika Boehme
发明人： Werner Wilfinger , Ingo Kriessmann , Friedrich Herrmann , Angelika Boehme
IPC分类号： C08K320
CPC分类号： C09D133/06 , C08K5/42 , C09D201/06 , C08L33/06 , C08L2666/14 , C08L2666/28 , C08L2666/02
摘要： A base-neutralized, water-diluted coating comprises (A) a polyhydroxyl-functional resin of an acrylate resin or an oil-free polyester containing urethane groups, (B) an amino resin partially etherified with an alcohol, (C) a basic neutralizing agent, (D) water, and (E) a water-insoluble crosslinking catalyst of a strong organic or inorganic acid such as p-toluenesulfonic acid blocked with a monoepoxide, diepoxide or lactone.
摘要翻译：碱中和的水稀释涂层包含（A）丙烯酸酯树脂的多羟基官能树脂或含有氨基甲酸酯基团的无油聚酯，（B）与醇部分醚化的氨基树脂，（C）碱性中和试剂，（D）水和（E）用单环氧化物，二环氧化物或内酯封端的强有机或无机酸如对甲苯磺酸的水不溶性交联催化剂。

4. 发明授权

US06204332B1 Water-dilutable coating composition of polyhydroxyl condensation or addition resin, amino resin and blocked acid catalyst 失效
标题翻译：水可稀释的多羟基缩合或加成树脂涂料组合物，氨基树脂和封闭的酸催化剂
公开(公告)号：US06204332B1
公开(公告)日：2001-03-20
申请号：US09080298
申请日：1998-05-18
申请人： Werner Wilfinger , Ingo Kriessmann , Friedrich Herrmann , Angelika Boehme
发明人： Werner Wilfinger , Ingo Kriessmann , Friedrich Herrmann , Angelika Boehme
IPC分类号： C08K320
CPC分类号： C09D133/06 , C08K5/42 , C09D201/06 , C08L33/06 , C08L2666/14 , C08L2666/28 , C08L2666/02
摘要： A water-dilutable coating after base neutralization comprises a polyhydroxyl-functional resin including a condensation resin such as a polyester or alkyd resin, and/or a polyhydroxyl-functional addition resin such as an acrylate resin or the reaction product of a carboxyl-functional acrylate resin and a hydroxyl-functional acrylate resin, and/or an emulsion copolymer, an at least partially monoalcohol-etherified amino resin, and a strong organic or inorganic acid crosslinking catalyst non-ionically blocked with a monoepoxide, a diepoxide or a lactone.
摘要翻译：碱中和后的水可稀释涂层包括包含缩聚树脂如聚酯或醇酸树脂的多羟基官能树脂和/或多羟基官能加成树脂如丙烯酸酯树脂或羧基官能丙烯酸酯的反应产物树脂和羟基官能的丙烯酸酯树脂，和/或乳液共聚物，至少部分一元醇醚化的氨基树脂和用单环氧化物，二环氧化物或内酯非离子封闭的强有机或无机酸交联催化剂。

5. 发明授权

US06228931B1 Water-dilutable film-forming binders 有权
标题翻译：水可稀释的成膜粘合剂
公开(公告)号：US06228931B1
公开(公告)日：2001-05-08
申请号：US09264883
申请日：1999-03-09
申请人： Werner Wilfinger , Ingo Kreissmann , Kurt Gossak , Johann Luttenberger
发明人： Werner Wilfinger , Ingo Kreissmann , Kurt Gossak , Johann Luttenberger
IPC分类号： C08J305
CPC分类号： C08G81/021 , C09D5/027
摘要： A low-solvent aqueous binder includes: a water-insoluble synthetic resin component A; and an emulsifier resin B in a mass ratio of A to B of from 70:30 to 30:70. The emulsifier resin B is a reaction product of a water-insoluble synthetic resin B1 that includes hydroxyl groups as functional groups, a synthetic resin B2 that includes carboxyl groups as functional groups, and a neutralizing agent for the carboxyl groups of B. The amount of the neutralizing agent is such that the neutralizing agent is able to neutralize from 5 to 200% of the carboxyl groups of B. A process for preparing a low-solvent aqueous binder includes: mixing the water-insoluble synthetic resin component B1 comprising hydroxyl functional groups and the synthetic resin B2 in bulk or dissolved in an organic solvent to form a mixture; removing the solvent by applying subatmospheric pressure and heating until the content of the mixture is at least 85% by mass; maintaining the mixture at a temperature from 90° to 150° C. until the reaction product of the mixture is homogeneously emulsifiable in a mass ratio of 3 parts of resin to 7 parts of water; neutralizing the reaction product by adding a neutralizing agent in an amount sufficient to neutralize from 5 to 200% of carboxyl groups that have remained following the reaction; adding the water-insoluble synthetic resin A in a mass ratio of A to B of from 70:30 to 30:70, and emulsifying the mixture in water.
摘要翻译：低溶剂水性粘合剂包括：不溶于水的合成树脂组分A; 和A〜B的质量比为70:30〜30:70的乳化树脂B. 乳化树脂B是包含羟基作为官能团的水不溶性合成树脂B1，包含羧基作为官能团的合成树脂B2和B的羧基中和剂的反应产物。中和剂使得中和剂能够中和B的羧基的5〜200％。制备低溶剂水性粘合剂的方法包括：将包含羟基官能团的水不溶性合成树脂组分B1 和合成树脂B2本体或溶解在有机溶剂中以形成混合物; 通过施加低于大气压并加热直到混合物的含量为至少85质量％除去溶剂; 将混合物保持在90℃至150℃的温度下，直到混合物的反应产物以3份树脂与7份水的质量比均匀乳化; 通过加入足以中和反应后残留的羧基的5〜200％的中和剂中和反应产物; 将A〜B的质量比为70:30〜30:70的水不溶性合成树脂A加入水中，使其混合。

6. 发明授权

US4396651A Process for spraying water-dilutable paint systems 失效
标题翻译：喷涂水可稀释漆系统的工艺
公开(公告)号：US4396651A
公开(公告)日：1983-08-02
申请号：US970955
申请日：1978-12-19
申请人： Klaus Behmel , Werner Gessner , Norbert Wamser , Werner Wilfinger
发明人： Klaus Behmel , Werner Gessner , Norbert Wamser , Werner Wilfinger
IPC分类号： B05D7/24 , B05B7/08 , B05D1/02 , B05D1/34
CPC分类号： B05D1/02 , B05B7/08 , B05D1/34
摘要： A spray coating process for application of water-dilutable paint systems which includes spraying a water-dilutable paint through a main nozzle which atomizes the paint and simultaneously therewith spraying at least one additional material from at least one lateral ancillary nozzle into and/or around the paint stream from the main nozzle. The additional material can be water to control the water content of the paint film, or it can be an additive such as a leveling aid for the paint. The spraying of the additional material into and around the paint stream while it is being projected to the surface to be painted causes the material to locate primarily at the surface of the atomized paint droplets.
摘要翻译：一种用于施加水可稀释涂料体系的喷涂方法，其包括通过主喷嘴喷洒水可稀释涂料，所述主喷嘴使涂料雾化，同时从至少一个侧辅助喷嘴喷射至少一种附加材料和/ 油漆从主喷嘴流出。附加材料可以是水以控制漆膜的含水量，或者可以是添加剂，例如涂料的流平助剂。当附加材料投射到待涂漆的表面时，将附加材料喷射到涂料流中和周围，导致材料主要位于雾化漆液滴的表面。

7. 发明授权

US5811484A Process for the preparation of water-dilutable coating binders based on acrylate copolymers, and their use 失效
标题翻译：基于丙烯酸酯共聚物制备水可稀释涂料粘合剂的方法及其用途
公开(公告)号：US5811484A
公开(公告)日：1998-09-22
申请号：US663127
申请日：1996-06-24
申请人： Werner Wilfinger , Ingo Kriessmann , Kurt Gossak
发明人： Werner Wilfinger , Ingo Kriessmann , Kurt Gossak
IPC分类号： C08G81/00 , B05D7/26 , C08F8/14 , C08F8/44 , C08G81/02 , C09D133/06 , C09D133/14 , C09D161/20 , C08L33/00
CPC分类号： C08F8/14 , C08F8/44 , C09D133/06
摘要： A process is disclosed for preparing water-dilutable, acrylate copolymer-based lacquer binders. A polycarboxylic component is reacted with an epoxide group-containing polyhydroxylic component, and the carboxylic groups are then at least partially neutralized. As epoxide group-containing monomers for the polyhydroxylic components, glycidyl(meth)acrylate and/or glycidylallylether are used in proportions from 0.1 to 3% by weight. Associated with cross-linking components and if required with other lacquer binders, these lacquer binders are suitable for producing water-dilutable baking enamels with a low auxiliary organic solvent content.
摘要翻译： PCT No.PCT / AT94 / 00203 Sec。 371日期1996年6月24日 102（e）1996年6月24日PCT 1994年12月22日PCT公布。第WO95 / 17450号公报日期1995年6月29日公开了一种制备水可稀释丙烯酸酯共聚物基漆粘合剂的方法。使多元羧酸成分与含环氧基的多羟基成分反应，然后将羧基至少部分中和。作为多羟基成分的含环氧基的单体，使用0.1〜3重量％的（甲基）丙烯酸缩水甘油酯和/或缩水甘油基醚。与交联组分相关，如果需要与其它漆粘合剂相关，这些漆粘合剂适用于生产具有低辅助有机溶剂含量的水可稀释烘烤搪瓷。

8. 发明授权

US5708072A Process for the preparation of water-dilutable coating binders, and the use thereof 失效
标题翻译：水可稀释涂料粘合剂的制备方法及其用途
公开(公告)号：US5708072A
公开(公告)日：1998-01-13
申请号：US647897
申请日：1996-06-05
申请人： Laszlo Tulacs , Hans Hiden , Werner Wilfinger , Johann Luttenberger
发明人： Laszlo Tulacs , Hans Hiden , Werner Wilfinger , Johann Luttenberger
IPC分类号： B05D1/36 , C08F2/14 , C08F283/00 , C09D133/06 , C09D151/00 , C09D151/08 , C09D175/04 , C08L75/00
CPC分类号： C08F283/006 , C09D151/08
摘要： A process is disclosed for preparing water-dilutable enamel paint binders based on oligourethane-acrylate copolymers. A specific monomer mixture is polymerized in the presence of a water-insoluble oligourethane obtained by reacting an aliphatic ester diol with a diisocyanate. Water dilutability is achieved by using (meth)acrylic acid. These enamel paint binders are used in combination with cross-linking components and if required other enamel paint binders to formulate baking enamels.
摘要翻译： PCT No.PCT / AT94 / 00186 Sec。 371日期：1996年6月5日 102（e）日期1996年6月5日PCT 1994年12月5日PCT公布。 WO95 / 16004 PCT出版物日期1995年6月15日公开了一种基于低聚氨酯 - 丙烯酸酯共聚物制备水可稀释搪瓷涂料粘合剂的方法。在通过使脂族酯二醇与二异氰酸酯反应得到的水不溶性低聚氨酯的存在下，将特定的单体混合物聚合。通过使用（甲基）丙烯酸来实现水的稀释。这些搪瓷涂料粘合剂与交联组分和必要的其它搪瓷涂料粘合剂结合使用以配制烘烤搪瓷。

9. 发明授权

US5136000A Methods for preparing and using a water dilutable copolymer and aqueous coating composition prepared therewith 失效
标题翻译：制备和使用水可稀释共聚物及其制备的水性涂料组合物的方法
公开(公告)号：US5136000A
公开(公告)日：1992-08-04
申请号：US753225
申请日：1991-08-30
申请人： Johannes Luttenberger , Herbert Zima , Werner Wilfinger , Ingo Kriessmann , Hermann Schaffer
发明人： Johannes Luttenberger , Herbert Zima , Werner Wilfinger , Ingo Kriessmann , Hermann Schaffer
IPC分类号： C08F2/38 , C08F20/26 , C08F220/04 , C08F220/26 , C08F220/28 , C08G18/62 , C08L33/06 , C08L61/20 , C09D5/00 , C09D5/02 , C09D133/00 , C09D133/02 , C09D133/04 , C09D133/06 , C09D161/20 , C09D161/28 , C09D175/04
CPC分类号： C08G18/6279 , C08F220/04 , C08F220/28 , C08G18/6254 , C09D133/066 , C08L33/06 , C08L61/20
摘要： A copolymer containing a hydroxy and a carboxyl moiety and is dilutable with water after neutralization with an organic base, which copolymer is from an alkyl ester and/or hydroxyalkyl ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid in which the alkyl moiety is interrupted by one or more oxygen atoms and the alkyl moiety of the hydroxyalkyl ester can contain one or more hydroxyl groups, an .alpha.,.beta.-ethylenically unsaturated carboxylic acid, and an optionally copolymerizable vinyl monomer, and has an acid number of from about 20 to about 50, and an OH number of from about 40 to about 90, and contains incorporated by polymerization from about 0.5 to about 5% wt. based on the monomers used for its preparation of one or more perfluoroalkyl ethyl ester of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid containing a C.sub.6-18 alkyl moiety.
摘要翻译：含有羟基和羧基部分的共聚物，在与有机碱中和后可用水稀释，该共聚物来自烷基部分被中断的α，β-烯键式不饱和羧酸的烷基酯和/或羟烷基酯通过一个或多个氧原子，并且羟烷基酯的烷基部分可以含有一个或多个羟基，α，β-烯属不饱和羧酸和任选可共聚的乙烯基单体，并且其酸值为约20至约 50，OH值为约40至约90，并且通过聚合包含约0.5至约5重量％基于用于制备含有C 6-18烷基部分的α，β-烯属不饱和羧酸的一种或多种全氟烷基乙酯的单体。

10. 发明授权

US4717424A Metal pigments stabilized with carboxy-alkylene phosphoric acid ester or carboxy-alkylene phosphonic or phosphinic acid 失效
标题翻译：用羧基亚烷基磷酸酯或羧基亚烷基膦酸或次膦酸稳定的金属颜料
公开(公告)号：US4717424A
公开(公告)日：1988-01-05
申请号：US877002
申请日：1986-06-20
申请人： Werner Wilfinger , Maximilian Friedl
发明人： Werner Wilfinger , Maximilian Friedl
IPC分类号： C09C1/00 , C09C1/40 , C09C1/62 , C09C1/64 , C09C3/08 , C09D5/00 , C09D5/02 , C09D5/38 , C09D7/12
CPC分类号： C09C1/62 , C09C1/644 , C09C3/08 , C09D5/38 , C01P2004/20 , C01P2004/61
摘要： The invention is concerned with stabilized metal pigments, in particular aluminum pigments, particularly against water and moisture, with improved resistance characteristics in aqueous paints. The stabilization of the metal particles is carried out through treatment with carboxyalkylene phosphoric acid esters, and/or carboxyalkylene phosphonic acids, and/or carboxyalkylene phosphinic acids. The carboxylic group of the compounds can be at least partially neutralized if desired.
摘要翻译：本发明涉及稳定的金属颜料，特别是涉及水和水分的铝颜料，具有改善的水性涂料中的电阻特性。通过用羧基亚烷基磷酸酯和/或羧基亚烷基膦酸和/或羧基亚烷基次膦酸处理来进行金属颗粒的稳定化。如果需要，化合物的羧基可以至少部分中和。

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