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    • 2. 发明授权
    • Tough, long-lasting dental composites
    • 坚韧,持久的牙科复合材料
    • US07977404B2
    • 2011-07-12
    • US11912145
    • 2006-04-19
    • Herbert WolterCarsten GellermannWerner Storch
    • Herbert WolterCarsten GellermannWerner Storch
    • A61K6/08A61K6/083A61K6/093C07F7/10C07F7/18C07F7/08
    • A61K6/0008A61K6/0017A61K6/0023A61K6/093C08G77/26Y10S977/919C08L83/16
    • A dental composite containing a nanoparticulate filler has a resin matrix with structural element (Ib) R is an open-chain and/or cyclic alkylene, arylene, or alkylene arylene with 1-10 C, optionally modified by oxygen, sulfur, carboxyl or amino, R1 is an open-chain and/or cyclic alkylene, arylene, or alkylene arylene with 1-10 C, optionally modified by oxygen, sulfur, carboxyl or amino; R′ is an open-chain and/or cyclic alkyl, alkenyl, aryl, alkyl aryl, or aryl alkyl with 1-20 C; B and B′ are identical or different and are a straight-chain or branched organically polymerizable group with (meth)acrylate residue; R3 are identical or different and a bond to another Si or hydrogen, alkyl with 1-10 C, or a bond to another metal atom; a is 1 or 2 and b is 0 or 1.
    • 含有纳米颗粒填料的牙科复合材料具有带有结构元件(Ib)的树脂基质,R是具有1-10个碳原子的开链和/或环状亚烷基,亚芳基或亚烷基亚芳基,任选被氧,硫,羧基或氨基 R1是具有1-10个碳原子的开环和/或环状亚烷基,亚芳基或亚烷基亚芳基,任选被氧,硫,羧基或氨基部分改性; R'是具有1-20 C的开链和/或环烷基,烯基,芳基,烷基芳基或芳基烷基; B和B'相同或不同,为具有(甲基)丙烯酸酯残基的直链或支链的有机聚合性基团; R3相同或不同,与另一个Si或氢的键,1-10个碳原子的烷基或与另一个金属原子的键; a为1或2,b为0或1。
    • 5. 发明授权
    • Hydrolyzable and polymerizable silanes
    • 可水解和可聚合的硅烷
    • US5717125A
    • 1998-02-10
    • US439204
    • 1995-05-11
    • Herbert WolterWerner Storch
    • Herbert WolterWerner Storch
    • C07F7/18C08F230/08C08G77/20C08G77/22C08G77/58C08G79/00C07F7/08C07F7/10
    • C07F7/184C07F7/1836C08F230/08C08G77/20C08G77/22C08G77/58C08G79/00
    • The invention includes hydrolyzable and polymerizable silanes, methods of making them and using them to obtain silicic acid(hetero)polycondensates and silicic acid(hetero)polymerizates. The hydrolyzable and polymerizable silanes have the formula I, ##STR1## wherein A=O, S, NH or C(O)O; wherein B=a straight chain or branched organic residue with at least one C.dbd.C double bond and from 4 to 50 carbon atoms; R is an alkyl group, alkenyl group, aryl group, alkylaryl group or an arylalkyl group; R' is a substituted or unsubstituted alkylene group, arylene group, arylenealkylene group or alkylenearylene group each having zero to ten carbon atoms, with the proviso that the substituted groups each have at least one oxygen atom, sulfur atom and/or amine group substituent; R.sup.1 represents nitrogen, a substituted or unsubstituted alkylene, arylene and alkylenearylene group each having from 1 to 10 carbon atoms, wherein said substituted alkylene groups, arylene groups and alkylenearylene groups each have at least one oxygen atom, sulfur atom and/or amine group substitutent; X represents hydrogen, halogen, a hydroxy group, an alkoxy group, acyloxy group, alkylcarbonyl group, alkoxycarbonyl group or --NR".sub.2 ; R" is H, alkyl or aryl; Z=CO or CHR.sup.4, wherein R.sup.4 is H, alkyl, aryl or alkylaryl; and wherein a=1, 2 or 3; b=0, 1 or 2; with the proviso that a+b necessarily=3; and c=1, 2, 3 or 4; and d=0 or 1.
    • 本发明包括可水解和可聚合的硅烷,制备它们并使用它们获得硅酸(杂)缩聚物和硅酸(杂)聚合物的方法。 可水解和可聚合的硅烷具有式I,B =具有至少一个C = C双键和4至50个碳原子的直链或支链有机残基; R是烷基,烯基,芳基,烷基芳基或芳基烷基; R'是取代或未取代的亚烷基,亚芳基,亚芳基亚烷基或亚烷基亚芳基,各自具有0至10个碳原子,条件是取代基各自具有至少一个氧原子,硫原子和/或胺基取代基; R1表示氮,取代或未取代的亚烷基,亚芳基和亚烷基亚芳基各自具有1至10个碳原子,其中所述取代的亚烷基,亚芳基和亚烷基亚芳基各自具有至少一个氧原子,硫原子和/或胺基取代基 ; X表示氢,卤素,羟基,烷氧基,酰氧基,烷基羰基,烷氧基羰基或-NR'2; R“是H,烷基或芳基; Z = CO或CHR4,其中R4是H,烷基,芳基或烷基芳基; 并且其中a = 1,2或3; b = 0,1或2; 条件是a + b必须= 3; 和c = 1,2,3或4; 和d = 0或1。
    • 6. 发明授权
    • Oxygenator membrane
    • 氧气膜
    • US06339108B1
    • 2002-01-15
    • US09393655
    • 1999-09-10
    • Herbert WolterThomas BallwegWerner Storch
    • Herbert WolterThomas BallwegWerner Storch
    • C03G7700
    • B01D71/44B01D71/70C08F283/12C08G77/26C08G77/28C08L51/08C08L51/085Y10S261/28
    • The invention relates to an oxygenator membrane based on organically modified silicic-acid polycondensates into a process for preparation thereof. The oxygenator membrane is obtainable by processing a viscous to resinous liquid by conventional methods to form a membrane, drying this membrane, if desired, and subjecting it to curing induced thermally and/or radiatively and/or chemically. The viscous to resinous liquid is obtained by hydrolytic polycondensation of one or more compounds of the general formula I and/or II and/or III and/or IV and/or of precondensates derived from these compound by hydrolytic condensation and, if desired, of one or more compounds of the general formula V, and, if desired, by addition of one or more monomers and/or oligomers which are capable of undergoing addition copolymerization and/or (poly)addition reaction and/or of one or more curing catalysts.
    • 本发明涉及一种基于有机改性硅酸缩聚物的氧合膜,用于其制备方法。 氧合膜可以通过常规方法处理粘稠的树脂液体来获得,以形成膜,如果需要,干燥该膜,并对其进行热和/或辐射和/或化学诱导的固化。 通过水解缩合从一种或多种通式I和/或III和/或IV和/或IV和/或IV和/或IV和/或衍生自这些化合物的预缩合物水解缩聚获得粘稠的树脂液体,如果需要, 一种或多种通式V的化合物,如果需要,通过加入一种或多种能够进行加成共聚和/或(多)加成反应和/或一种或多种固化催化剂的单体和/或低聚物 。
    • 8. 发明授权
    • Hydrolyzable and polymerizable and/or polyadditive silanes
    • 可水解和可聚合的和/或多种加成硅烷
    • US06222055B1
    • 2001-04-24
    • US09399301
    • 1999-09-17
    • Herbert WolterWerner Storch
    • Herbert WolterWerner Storch
    • C07F710
    • C08G77/28C07F7/1804C08G77/20C08G77/26
    • Hydrolysable and polymerizable or polyadditive silanes and methods of their production and the production of (hetero)silicic acid polycondensates or of polymers. The silanes in accordance with the invention are of general formula in which the groups and indices are equal or different and have the following meaning: R=hydrogen, R2—R1—R4—SiXxR33-x, carbonyl, alkyl, alkenyl, aryl, alkylaryl or arylalkyl; R1=alkylene, arylene, arylenealkene or alkenearylene; R2=alkylene, arylene, arylenealkene or alkenearylene; R3=Alkyl, alkenyl, aryl, alkylaryl or arylalkyl; R4=—(CHR6—CHR6)n—, where n=0 or 1, —CHR6—CHR6—S—R5—; —CO—S—R5—, —CHR6—CHR6—NR6R5—, —Y—CS—NH—R5—, —S—R5—, —Y—CO—NH—R5—, —CO—O—R5—, —Y—CO—C2H3(COOH)—R5—, —Y—CO—C2H3(OH)—R5— or —CO—NR6—R5—; R5=alkene, arylene, arylenealkene or alkenearylene; R6=hydrogen, alkyl or aryl with 1 to 10 carbon atoms; R9=hydrogen, alkyl, alkene, aryl, alkylaryl or arylalkyl; X=hydrogen, halogen, hydroxy, alkoxy, acyloxy, alkylcarbonyl, alkoxycarbonyl or NR″2, where R″=hydrogen, alkyl or aryl; Y=—O—, —S— or —NR6—; Z=—O— or —(CHR6)m—, where m=1 or 2; a=1, 2 or 3, with b=1 for a=2 or 3; b=1, 2 or 3, with a=1 for b=2 or 3; c=1 to 6; x=1, 2 or 3; a+x=2, 3 or 4.
    • 可水解和可聚合或多加成硅烷及其生产方法和(异)硅酸缩聚物或聚合物的生产。 根据本发明的硅烷具有通式,其基团和指数相同或不同并且具有以下含义:R =氢,R 2 -R 1 -R 4 -Si X x R 33-x,羰基,烷基,烯基,芳基,烷基芳基或 芳基烷基; R 1 =亚烷基,亚芳基,亚芳基烯烃或亚烯基芳基; R 2 =亚烷基,亚芳基,亚芳基烯烃或亚烯基亚芳基; R 3 =烷基,烯基,芳基,烷芳基或芳基烷基; R 4 = - (CHR 6 -CHR 6) 1,-CHR6-CHR6-S-R5-; -CO-S-R5-,-CHR6-CHR6-NR6R5-,-Y-CS-NH-R5-,-S-R5-,-Y-CO-NH-R5-,-CO-O-R5-, -Y-CO-C2H3(COOH)-R5-,-Y-CO-C2H3(OH)-R5-或-CO-NR6-R5-; R5 =烯烃,亚芳基,亚芳基烯或烯丙烯; R6 =氢,烷基或 具有1至10个碳原子的芳基; R 9 =氢,烷基,烯烃,芳基,烷基芳基或芳基烷基; X =氢,卤素,羟基,烷氧基,酰氧基,烷基羰基,烷氧基羰基或NR'2,其中R“ 烷基或芳基; Y = -O-,-S-或-NR 6 - ; Z = -O-或 - (CHR 6)m - ,其中m = 1或2; a = 1,2或3,其中b = 1 对于a = 2或3; b = 1,2或3,对于b = 2或3,a = 1; c = 1至6; x = 1,2或3; a + x = 2,3或4。
    • 9. 发明申请
    • Tough, Long-Lasting Dental Composites
    • 坚韧,持久的牙科复合材料
    • US20080187499A1
    • 2008-08-07
    • US11912145
    • 2006-04-19
    • Herbert WolterCarsten GellermannWerner Storch
    • Herbert WolterCarsten GellermannWerner Storch
    • A61K8/30A61Q11/00
    • A61K6/0008A61K6/0017A61K6/0023A61K6/093C08G77/26Y10S977/919C08L83/16
    • A dental composite containing a nanoparticulate filler has a resin matrix with structural element (Ib) R is an open-chain and/or cyclic alkylene, arylene, or alkylene arylene with 1-10 C, optionally modified by oxygen, sulfur, carboxyl or amino, R1 is an open-chain and/or cyclic alkylene, arylene, or alkylene arylene with 1-10 C, optionally modified by oxygen, sulfur, carboxyl or amino; R′ is an open-chain and/or cyclic alkyl, alkenyl, aryl, alkyl aryl, or aryl alkyl with 1-20 C; B and B′ are identical or different and are a straight-chain or branched organically polymerizable group with (meth)acrylate residue; R3 are identical or different and a bond to another Si or hydrogen, alkyl with 1-10 C, or a bond to another metal atom; a is 1 or 2 and b is 0 or 1.
    • 含有纳米颗粒填料的牙科复合材料具有带有结构元件(Ib)的树脂基质,R是具有1-10个碳原子的开链和/或环状亚烷基,亚芳基或亚烷基亚芳基,任选被氧,硫,羧基或氨基 R 1是具有1-10个碳原子的开链和/或环状亚烷基,亚芳基或亚烷基亚芳基,任选被氧,硫,羧基或氨基部分改性; R'是具有1-20 C的开链和/或环烷基,烯基,芳基,烷基芳基或芳基烷基; B和B'相同或不同,为具有(甲基)丙烯酸酯残基的直链或支链的有机聚合性基团; R 3相同或不同,与另一个Si或氢的键,与1-10个C的烷基或与另一个金属原子的键; a为1或2,b为0或1。