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    • 1. 发明申请
    • PLASMA-POLYMERISATION OF POLYCYCLIC COMPOUNDS
    • 多环化合物的等离子体聚合
    • WO2005092521A2
    • 2005-10-06
    • PCT/DK2005/000206
    • 2005-03-23
    • FORSKNINGSCENTER RISØDANMARKS TEKNISKE UNIVERSITETWINTER-JENSEN, BjørnWEST, Keld
    • WINTER-JENSEN, BjørnWEST, Keld
    • B05D7/24
    • B05D1/62H01L51/0016H01L51/0037Y10T428/265Y10T428/31504Y10T428/31855
    • The present invention relates to a method for the preparation of a layer of a plasma-­polymerised material on the surface of a substrate, e.g. a substrate of a glass, an organosiloxane-based or polysiloxane-based material, silicon, fluoro-polymer (e.g. Teflon ® ), etc. The present invention also relates to novel objects and microstructured or micro­patterned devices, e.g. by lift-off techniques, in particular such objects and devices that have layers of electrically conducting materials providing a conductivity of at least 0.01 S/cm. A feature of the invention is the plasma-polymerization of a compound including at least one polycyclic compound, said polycyclic compounds) comprising a non-aromatic heterocyclicring fused to an aromatic or heteroaromatic ring or ring system. Examples of such compounds are 3,4-ethylenedioxythiophene (EDT). forming layers of poly(ethylenedioxythiophene) (PEDT), and piperonylamine, piperonyloyl chloride, safrole, 3,4-ethylenedioxypyrrole, 3,4-ethylenedioxy-N-methylpyrrole, and 3,4-­methylenedioxythiophene.
    • 本发明涉及一种在衬底的表面上制备等离子体聚合材料层的方法,例如, 玻璃基底,有机硅氧烷基或聚硅氧烷基材料,硅,氟聚合物(例如Teflon)等。本发明还涉及新颖的物体和微结构或微图案化的器件,例如, 通过剥离技术,特别是具有提供至少0.01S / cm的电导率的导电材料层的这些物体和装置。 本发明的一个特征是包含至少一种多环化合物(所述多环化合物)的化合物的等离子体聚合,所述多环化合物包括与芳族或杂芳族环或环系稠合的非芳族杂环。 这些化合物的实例是3,4-亚乙基二氧噻吩(EDT)。 形成聚(亚乙二氧基噻吩)(PEDT)和胡椒基胺,哌嗪酰氯,黄樟脑,3,4-亚乙二氧基吡咯,3,4-亚乙二氧基-N-甲基吡咯和3,4-亚甲基二氧噻吩的层。