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    • 1. 发明申请
    • ELECTROLYTIC CELL FOR WASTE WATER TREATMENT
    • 用于废水处理的电解槽
    • WO1991018837A1
    • 1991-12-12
    • PCT/EP1991000935
    • 1991-05-23
    • TITALYSE SANGUYEN, Trong, ThinhWIAUX, Jean-PolRAETZO, Patrick
    • TITALYSE SA
    • C02F01/46
    • C02F1/46109C02F1/4678C02F2001/46157C02F2101/20C02F2201/4611C02F2201/46115C25C7/04
    • A flow-through electrolytic cell for removing heavy metals from waste water has a cell housing (1) with an inlet (7) and an outlet (8) for solution to be treated at opposite ends. Foam metal cathodes (3) are arranged in the cell housing transverse to the housing and extending over its entire width, with coated titanium mesh anodes (4) interleaved between the cathodes. The anodes (4) are contained in diaphragm-forming boxes (2) of microporous ion-permeable material. Each box (2) forms an anode compartment and has means (5, 6) for circulating anolyte therethrough. The boxes (2) extend partly across and are offset alternately from opposite sides of the cell housing (1) to provide a serpentine path for liquid to be treated (catholyte) flowing from the inlet (7) to the outlet (8) through the cathodes (3). The anolyte circulation includes a siphon (20) for controlling the anolyte head to prevent unwanted mixing of the anolyte and catholyte. The cell is useful for the treatment of rinse waters from chloride-containing baths, organic-containing plating baths, rinse waters containing multi-oxidation-state metallic ions, and spent baths from the electroless plating of nickel.
    • 用于从废水中除去重金属的流通电解池具有一个具有入口(7)和一个出口(8)的电池外壳(1),用于在相对端进行处理。 泡沫金属阴极(3)布置在电池壳体中横向于壳体并且在其整个宽度上延伸,其中涂覆的钛网阳极(4)交错在阴极之间。 阳极(4)包含在微孔离子可渗透材料的隔膜形成盒(2)中。 每个盒(2)形成阳极室,并具有用于使阳极电解液从其中循环的装置(5,6)。 盒子(2)部分地跨越并且与电池壳体(1)的相对侧交替地偏移,以提供用于从入口(7)流到出口(8)的待处理液体(阴极电解液)的蛇形路径 阴极(3)。 阳极电解液循环包括用于控制阳极电解液头的虹吸管(20),以防止阳极电解液和阴极电解液的不希望的混合。 该电池可用于从含氯化物浴,含有机电镀浴,含有多氧化态金属离子的冲洗水和来自镍化学镀的废液处理冲洗水。
    • 4. 发明申请
    • USED BATTERY AND CELL SORTING METHOD AND APPARATUS
    • 使用电池和电池分配方法和装置
    • WO1994019838A1
    • 1994-09-01
    • PCT/IB1994000022
    • 1994-02-24
    • TITALYSE S.A.WIAUX, Jean-PolLAZOUNI, AbdelkrimINDACO, Antoine
    • TITALYSE S.A.
    • H01M06/52
    • B03B9/061B03B2009/066H01M6/52H01M10/54Y02W30/526Y02W30/84
    • A method for sorting used batteries and cells (4) having different shapes and sizes and different chemical compositions, wherein the batteries are magnetically sorted by applying magnetic fields to separate batteries and cells with a ferromagnetic component (6) from non-magnetic batteries and cells (7), whereafter the ferromagnetic batteries (6) are sorted according to their size to divide them preferably into three groups, i.e. ferromagnetic multicells, prismatics and monocells (6.1, 6.2, 6.3), and the non-magnetic batteries and cells (7) are sorted according to their size to divide them into two groups, i.e. non-ferromagnetic multicells and monocells (7.1, 7.2). The ferromagnetic monocells (6.3) are then sorted by a head (12) according to their chemical composition, whereas the non-magnetic multicell are sorted by another sensor (16). After sorting, the batteries and cells are grouped together according to their chemical compatibility and sent to suitable recycling processes.
    • 一种用于分类具有不同形状和大小以及不同化学组成的废旧电池和电池(4)的方法,其中通过施加磁场来对来自非磁性电池和电池的铁磁组件(6)分离电池和电池的电池进行磁分选 (7),之后根据其大小对铁磁性电池(6)进行分类,将其优选分为三组,即铁磁多芯,棱镜和单电池(6.1,6.2,6.3)和非磁性电池和电池(7 )根据其大小进行分类,将其分为两组,即非铁磁多单元和单电池(7.1,7.2)。 铁磁单电池(6.3)然后根据它们的化学成分由磁头(12)分选,而非磁性单体电池被另一个传感器(16)排序。 分选后,电池和电池根据其化学相容性分组在一起,并发送到合适的回收工艺。
    • 5. 发明申请
    • ELECTROLYTIC CELL
    • 电解槽
    • WO1994015877A1
    • 1994-07-21
    • PCT/IB1994000006
    • 1994-01-17
    • TITALYSE SAWIAUX, Jean-PolJEANMONOD, ChristineIMBRUGLIA, Piero
    • TITALYSE SA
    • C02F01/46
    • C02F1/46104C02F1/46109C02F1/4672C02F1/4678C02F2001/46133C02F2101/18C02F2101/20C02F2101/30C02F2201/003C02F2201/4611C02F2301/024C02F2301/026
    • An electrolytic cell for processing effluents loaded with heavy metals and oxidizable or reducible chemical compounds, including a cylindrical assembly with at least one anode and one cathode. The cell has a generally cylindrical hollow anode (5) with its inner and outer surfaces operably linked to two cathodes, i.e. a peripheral cathode (20) facing the outer anode portion for depositing metals, and an auxiliary inner cathode (21) facing the inner anode portion. The anode is selectively connected to the peripheral cathode or to both cathodes in order to perform electrolysis either between the peripheral cathode and the outer anode surface during a phase in which metal is deposited on the peripheral cathode, or between both cathodes and both sides of the anode during a phase in which the remaining dissolved chemical compounds are oxidized. The cell suitably comprises at least one electrolyte supply tube (10) provided with electrolyte supply ports arranged at different levels to cause a tangential electrolyte flow between the peripheral cathode and the cylindrical anode.
    • 一种用于处理负载有重金属和可氧化或可还原的化合物的流出物的电解池,包括具有至少一个阳极和一个阴极的圆柱形组件。 电池具有大致圆柱形的中空阳极(5),其内表面和外表面可操作地连接到两个阴极,即面向外阳极部分的用于沉积金属的外围阴极(20)和面向内部阳极的辅助内阴极 阳极部分。 阳极选择性地连接到外围阴极或两个阴极,以便在周边阴极和外部阳极表面之间进行电解,其中金属沉积在外围阴极上,或阴极和阴极两侧之间 在其中剩余的溶解的化合物被氧化的阶段中的阳极。 电池适当地包括至少一个电解质供应管(10),该电解质供给管(10)设置有以不同水平布置的电解质供给口,以在外围阴极和圆筒形阳极之间引起切向电解质流动。