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1. 发明申请

WO2012088176A1 HIGH MOLECULAR WEIGHT IONOMERS AND IONICALLY CONDUCTIVE COMPOSITIONS FOR USE AS ONE OR MORE ELECTRODE OF A FUEL CELL 审中-公开
标题翻译：高分子量重金属离子和离子导电组合物用作燃料电池的一个或多个电极
公开(公告)号：WO2012088176A1
公开(公告)日：2012-06-28
申请号：PCT/US2011066287
申请日：2011-12-20
申请人： DU PONT , TOYOTA MOTOR CO LTD , TAKAMI MASAYOSHI , YOSHIDA TOSHIHIKO , AIMU MASANORI , PERRY RANDAL L , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
发明人： TAKAMI MASAYOSHI , YOSHIDA TOSHIHIKO , AIMU MASANORI , PERRY RANDAL L , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
IPC分类号： H01M6/18 , H01M4/88 , H01M8/10 , H01M10/0565
CPC分类号： H01M8/1039 , H01M4/8663 , H01M4/8828 , H01M6/183 , H01M8/1004 , H01M8/1027 , H01M10/0565 , H01M2300/0082
摘要： This invention relates to solid polymer electrolyte materials for use in one or more electrode of a fuel cell. The solid polymer electrolyte materials comprise one or more ionomer which comprises polymerized units of monomers A and monomers B, wherein monomers A are perfluoro dioxole or perfluoro dioxolane monomers, and the monomers B are functionalized perfluoro olefins having fluoroalkyl sulfonyl, fluoroalkyl sulfonate or fluoroalkyl sulfonic acid pendant groups, CF2=CF(O)[CF2]nSO2X. The ionomer of the solid polymer electrolyte material has a number average molecular weight, Mn, of greater than 140,000. Specifically, the ionomers of the invention may find use in the catalyst layer of an electrode because the high molecular weight ionomers mitigate the formation of cracks in the catalyst layer.
摘要翻译：本发明涉及用于燃料电池的一个或多个电极的固体聚合物电解质材料。固体聚合物电解质材料包含一种或多种离聚物，其包含单体A和单体B的聚合单元，其中单体A是全氟二氧杂环戊烯单体或全氟二氧戊环单体，单体B是具有氟代烷基磺酰基，氟烷基磺酸酯或氟烷基磺酸的全氟烯烃的官能化侧链基团，CF 2 = CF（O）[CF 2] n SO 2 X。固体高分子电解质材料的离聚物的数均分子量Mn大于14万。具体地，本发明的离聚物可用于电极的催化剂层，因为高分子量离聚物可以减轻催化剂层中的裂纹的形成。

2. 发明申请

WO2012088166A1 IONOMERS AND IONICALLY CONDUCTIVE COMPOSITIONS 审中-公开
标题翻译：离子和离子导电组合物
公开(公告)号：WO2012088166A1
公开(公告)日：2012-06-28
申请号：PCT/US2011/066273
申请日：2011-12-20
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , PERRY, Randal, L. , ROELOFS, Mark, Gerrit , WHELAND, Robert, Clayton , ATEN, Ralph, Munson
发明人： PERRY, Randal, L. , ROELOFS, Mark, Gerrit , WHELAND, Robert, Clayton , ATEN, Ralph, Munson
IPC分类号： C07C9/10 , C08F8/00 , C08F216/12 , C08F234/02 , C08G61/00 , H01M8/02
CPC分类号： C08F14/18 , C08F214/18 , C08F214/182 , C08F216/1408 , C08F216/1466 , C08J5/2237 , C08J2327/18 , C08L23/0876 , H01G11/58 , H01M8/1004 , H01M8/1025 , H01M8/1039 , H01M8/1044
摘要： This invention relates to ionomers and to ionically conductive compositions formed therefrom. The ionomers comprise polymerized units of monomers A and monomers B, wherein monomers A are perfluoro dioxole or perfluoro dioxolane monomers, and the monomers B are functionalized perfluoro olefins having fluoroalkyi sulfonyl, fluoroalkyi sulfonate or fluoroalkyi sulfonic acid pendant groups, CF 2 =CF(O)[CF 2 ] n SO 2 X. The ionically conductive compositions of the invention are useful in fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.
摘要翻译：本发明涉及离聚物和由其形成的离子导电组合物。离聚物包括单体A和单体B的聚合单元，其中单体A是全氟二氧杂环戊烯或全氟二氧戊环单体，单体B是具有氟代烷基磺酰基，氟代烷基磺酸酯或氟代烷基磺酸侧基的CF 2 = CF（O） [CF2] nSO2X。本发明的离子导电组合物可用于燃料电池，电解槽，离子交换膜，传感器，电化学电容器和改性电极。

3. 发明申请

WO2012086185A1 CATHODE CATALYST LAYER, MEMBRANE ELECTRODE ASSEMBLY AND POLYMER ELECTROLYTE FUEL CELL AND MANUFACTURING METHOD THEREOF 审中-公开
标题翻译：阴极催化层，膜电极组件和聚合物电解质燃料电池及其制造方法
公开(公告)号：WO2012086185A1
公开(公告)日：2012-06-28
申请号：PCT/JP2011007116
申请日：2011-12-20
申请人： TOYOTA MOTOR CO LTD , DU PONT , NONOYAMA NOBUAKI , AIMU MASANORI , PERRY RANDAL LEWIS , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
发明人： NONOYAMA NOBUAKI , AIMU MASANORI , PERRY RANDAL LEWIS , ROELOFS MARK GERRIT , WHELAND ROBERT CLAYTON , ATEN RALPH MUNSON
IPC分类号： H01M4/88 , H01M4/86 , H01M8/10
CPC分类号： H01M4/8657 , H01M4/8652 , H01M4/8663 , H01M4/8668 , H01M4/886 , H01M8/1004 , H01M2008/1095 , Y02E60/521 , Y02P70/56
摘要： A cathode catalyst layer used for a polymer electrolyte fuel cell that includes an electrolyte membrane is provided. The cathode catalyst layer comprises a catalyst having weight of not greater than 0.3 mg/cm2 of a reaction surface of the cathode catalyst layer that is adjoining the electrolyte membrane; and an electrolyte resin having oxygen permeability of not less than 2.2*10-14 mol/m/s/Pa in an environment of temperature of 80 degrees Celsius and relative humidity of 50%.
摘要翻译：提供了用于包含电解质膜的固体高分子型燃料电池的阴极催化剂层。阴极催化剂层包含负极与电解质膜相邻的阴极催化剂层的反应面重量不大于0.3mg / cm 2的催化剂; 以及在80℃的温度和50％的相对湿度的环境中具有不低于2.2×10-14mol / m / s / Pa的透氧度的电解质树脂。

4. 发明申请

WO2005119371A1 ULTRAVIOLET-TRANSPARENT ALKANES AND PROCESSES USING SAME IN VACUUM AND DEEP ULTRAVIOLET APPLICATIONS 审中-公开
标题翻译：紫外线透明碱和在真空和深紫外线应用中使用相同的方法
公开(公告)号：WO2005119371A1
公开(公告)日：2005-12-15
申请号：PCT/US2005/019404
申请日：2005-06-01
申请人： E.I. DUPONT DE NEMOURS AND COMPANY , FRENCH, Roger, Harquail , PENG, Sheng , WHELAND, Robert, Clayton
发明人： FRENCH, Roger, Harquail , PENG, Sheng , WHELAND, Robert, Clayton
IPC分类号： G03F7/20
CPC分类号： G03F7/2041
摘要： The present invention is drawn to the use of alkanes that are highly transparent to UV wavelengths ranging from about 170 nm to 260 nm in optical couplants, optical cements, optical elements, optical inspection media for semiconductor wafers and devices, and immersion photolithography, particularly at 193 and 248 nm exposure wavelength.
摘要翻译：本发明涉及在光耦合剂，光学胶粘剂，光学元件，用于半导体晶片和器件的光学检查介质以及浸没式光刻技术中使用对从约170nm至260nm范围内的UV波长高度透明的烷烃，特别是在 193和248 nm的曝光波长。

5. 发明申请

WO0244816A3 ANTIREFLECTIVE LAYER FOR USE IN MICROLITHOGRAPHY 审中-公开
标题翻译：用于微结构的抗反射层
公开(公告)号：WO0244816A3
公开(公告)日：2003-09-12
申请号：PCT/US0143437
申请日：2001-11-21
申请人： DU PONT , BERGER LARRY L , CRAWFORD MICHAEL KARL , FRENCH ROGER HARQUAIL , WHELAND ROBERT CLAYTON , ZUMSTEG FREDERICK CLAUS JR
发明人： BERGER LARRY L , CRAWFORD MICHAEL KARL , FRENCH ROGER HARQUAIL , WHELAND ROBERT CLAYTON , ZUMSTEG FREDERICK CLAUS JR
IPC分类号： G03F7/11 , G03F7/004 , G03F7/09 , H01L21/027
CPC分类号： G03F7/091 , G03F7/0046
摘要： An element having a support, and at least an antireflective layer; wherein the antireflective layer is prepared from a composition having a polymer selected from the group consisting of (a) a fluorine-containing copolymer comprising a repeat unit derived from at least one ethylenically unsaturated compound characterized in that at least one ethylenically unsaturated compound is polycyclic; (b) a branched polymer containing protected acid groups, said polymer comprising one or more branch segment(s) chemically linked along a linear backbone segment; (c) fluoropolymers having at least one fluoroalcohol group having the structure:-C(Rf)(Rf')OHwherein Rf and Rf' are the same or different fluoroalkyl groups of from 1 to about 10 carbon atoms or taken together are (CF2)n wherein n is 2 to 10; (d) amorphous vinyl homopolymers of perfluoro-2,2-dimethyl-1,3-dioxole or CX2=CY2, where X is -F, or -CF3 and Y is H, or amorphous vinyl copolymers of perfluoro-2,2-dimethyl-1,3-dioxole and CX2=CY2; (e) nitrile/fluoroalcohol-containing polymers prepared from substituted or unsubstituted vinyl ethers; and mixtures thereof.
摘要翻译：一种具有支撑体的元件和至少一个抗反射层; 其中所述抗反射层由具有选自以下的聚合物的组合物制备：（a）包含衍生自至少一种烯属不饱和化合物的重复单元的含氟共聚物，其特征在于至少一种烯属不饱和化合物是多环的; （b）含有保护的酸基团的支化聚合物，所述聚合物包含一个或多个沿着线性主链部分化学连接的支链段; （c）具有至少一个具有以下结构的氟代醇的含氟聚合物：具有以下结构的-C（R f）（R f'）OH其中R f和R f'为相同或不同的具有1至约10个碳原子的氟代烷基或一起为（CF 2） n其中n为2至10; （d）全氟-2,2-二甲基-1,3-二氧杂环戊烯或CX2 = CY2的无定形乙烯基均聚物，其中X为-F或-CF 3且Y为H，或全氟-2,2-二甲基-1,3-二氧杂环戊烯的无定形乙烯基共聚物，二甲基-1,3-二氧杂环戊烯和CX2 = CY2; （e）由取代或未取代的乙烯基醚制备的含腈/氟代醇的聚合物; 及其混合物。

6. 发明申请

WO0185811A3 COPOLYMERS FOR PHOTORESISTS AND PROCESSES THEREFOR 审中-公开
标题翻译：用于其光电子和共聚物的方法
公开(公告)号：WO0185811A3
公开(公告)日：2002-06-27
申请号：PCT/US0114532
申请日：2001-05-04
申请人： DU PONT , WHELAND ROBERT CLAYTON , FRENCH ROGER HARQUAIL , SCHADT FRANK LEONARD III , ZUMSTEG FREDERICK C JR
发明人： WHELAND ROBERT CLAYTON , FRENCH ROGER HARQUAIL , SCHADT FRANK LEONARD III , ZUMSTEG FREDERICK C JR
IPC分类号： C08F8/00 , C08F214/18 , C08F220/10 , G03F7/004 , G03F7/038 , G03F7/039 , C09D7/00 , C09D127/12 , H01L21/00
CPC分类号： C08F214/186 , G03F7/0046 , G03F7/0048 , G03F7/0382 , G03F7/0392
摘要： Fluoroolefin/acid group or protected acid group-containing copolymers for photoresist compositions and microlithography methods employing the photoresist compositions are described. These copolymer compositions comprise 1) at least one fluoroolefin, preferably hexafluoroisobutylene, and 2) an acid group or a protected acid group (e.g., a t-alkyl ester, preferably a t-butyl ester), which together impart high ultraviolet (UV) transparency and developability in basic media to these materials. The materials of this invention have high UV transparency, particularly at short wavelengths, e.g., 157 nm and 193 nm, which makes them useful for lithography at these short wavelengths.
摘要翻译：描述了用于光致抗蚀剂组合物的氟烯烃/酸基或被保护的含酸基的共聚物和使用光致抗蚀剂组合物的微光刻方法。这些共聚物组合物包含1）至少一种氟代烯烃，优选六氟异丁烯，以及2）酸性基团或被保护的酸基团（例如，叔烷基酯，优选叔丁基酯），其一起赋予高紫外（UV）这些材料的基本媒体的透明度和可开发性。本发明的材料具有高的UV透明度，特别是在短波长，例如157nm和193nm，这使得它们可用于在这些短波长下的光刻。

7. 发明申请

WO2013021627A1 ELECTRODE FOR FUEL CELL, MANUFACTURING METHOD OF ELECTRODE FOR FUEL CELL, POLYMER ELECTROLYTE FUEL CELL AND CATALYST INK 审中-公开
标题翻译：燃料电池用电极，燃料电池用电极的制造方法，聚合物电解质燃料电池及催化剂墨水
公开(公告)号：WO2013021627A1
公开(公告)日：2013-02-14
申请号：PCT/JP2012/005017
申请日：2012-08-07
申请人： TOYOTA JIDOSHA KABUSHIKI KAISHA , E. I. DU PONT DE NEMOURS AND COMPANY , AIMU, Masanori , PERRY, Randal Lewis , ROELOFS, Mark Gerrit , WHELAND, Robert Clayton , ATEN, Ralph Munson
发明人： AIMU, Masanori , PERRY, Randal Lewis , ROELOFS, Mark Gerrit , WHELAND, Robert Clayton , ATEN, Ralph Munson
IPC分类号： H01M4/86 , H01M4/88
CPC分类号： H01M4/9075 , H01M4/8605 , H01M4/8668 , H01M4/881 , H01M4/8828 , H01M4/8882 , H01M2008/1095 , Y02E60/50
摘要： An electrode (31c) for fuel cell comprises: a catalyst carrier (110) that is an electrically-conductive carrier (130) with a catalyst (120) supported thereon; a first electrolyte resin (141); and a second electrolyte resin (142). the first electrolyte resin has oxygen permeability of less than 2.2 x 10 -14 mol/(m s Pa) in an environment having temperature of 80 degrees Celsius and relative humidity of 50%. the second electrolyte resin has oxygen permeability of not less than 2.2x10 -14 mol/ (m s Pa) in the environment having temperature of 80 degrees Celsius and relative humidity of 50%.
摘要翻译：一种用于燃料电池的电极（31c）包括：催化剂载体（110），其是在其上支撑有催化剂（120）的导电载体（130）第一电解质树脂（141）; 和第二电解质树脂（142）。第一电解质树脂在温度为80摄氏度，相对湿度为50％的环境中具有小于2.2×10-14摩尔/（m·s·Pa）的氧气渗透性。第二电解质树脂在温度为80摄氏度，相对湿度为50％的环境中具有不低于2.2×10 14〜14摩尔/（m·s·Pa）的透氧度。

8. 发明申请

WO2012088176A9 HIGH MOLECULAR WEIGHT IONOMERS AND IONICALLY CONDUCTIVE COMPOSITIONS FOR USE AS ONE OR MORE ELECTRODE OF A FUEL CELL 审中-公开
公开(公告)号：WO2012088176A9
公开(公告)日：2012-06-28
申请号：PCT/US2011/066287
申请日：2011-12-20
申请人： E. I. DU PONT DE NEMOURS AND COMPANY , TOYOTA JIDOSHA KABUSHIKI KAISHA , TAKAMI, Masayoshi , YOSHIDA, Toshihiko , AIMU, Masanori , PERRY, Randal, L. , ROELOFS, Mark, Gerrit , WHELAND, Robert, Clayton , ATEN, Ralph, Munson
发明人： TAKAMI, Masayoshi , YOSHIDA, Toshihiko , AIMU, Masanori , PERRY, Randal, L. , ROELOFS, Mark, Gerrit , WHELAND, Robert, Clayton , ATEN, Ralph, Munson
IPC分类号： H01M6/18 , H01M8/10 , H01M10/0565 , H01M4/88
摘要： This invention relates to solid polymer electrolyte materials for use in one or more electrode of a fuel cell. The solid polymer electrolyte materials comprise one or more ionomer which comprises polymerized units of monomers A and monomers B, wherein monomers A are perfluoro dioxole or perfluoro dioxolane monomers, and the monomers B are functionalized perfluoro olefins having fluoroalkyl sulfonyl, fluoroalkyl sulfonate or fluoroalkyl sulfonic acid pendant groups, CF 2 =CF(O)[CF 2 ]nSO 2 X. The ionomer of the solid polymer electrolyte material has a number average molecular weight, Mn, of greater than 140,000. Specifically, the ionomers of the invention may find use in the catalyst layer of an electrode because the high molecular weight ionomers mitigate the formation of cracks in the catalyst layer.

9. 发明申请

WO2003077034A3 FLUORINE-CONTAINING COMPOUNDS WITH HIGH TRANSPARENCY IN THE VACUUM ULTRAVIOLET 审中-公开
公开(公告)号：WO2003077034A3
公开(公告)日：2003-09-18
申请号：PCT/US2003/007091
申请日：2003-03-06
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , FRENCH, Roger, Harquail , JONES, David, Joseph , WHELAND, Robert, Clayton
发明人： FRENCH, Roger, Harquail , JONES, David, Joseph , WHELAND, Robert, Clayton
IPC分类号： C07C17/00
摘要： This invention concerns radiation durable organic compositions which are well-suited for use in 157 nm lithography by virtue of their high transparency and excellent radiation durability, and to a process for the preparation thereof.

10. 发明申请

WO2002092670A3 FLUOROPOLYMER COMPOSITIONS COMPRISING A FLUOR-CONTAINING LIQUID 审中-公开
公开(公告)号：WO2002092670A3
公开(公告)日：2002-11-21
申请号：PCT/US2002/018397
申请日：2002-05-14
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , FRENCH, Roger, Harquail , WHELAND, Robert, Clayton
发明人： FRENCH, Roger, Harquail , WHELAND, Robert, Clayton
IPC分类号： C08J3/09
摘要： Disclosed are compositions comprising partially fluorinated and fully fluorinated polymers and partially fluorinated and fully fluorinated liquids, said compositions useful in the manufacture of articles substantially transparent to ultraviolet radiation at wavelengths from approximately 150 nanometer to 200 nanometers.

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