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1. 发明申请

WO2010107478A1 METHODS OF PREPARING A POLYMERIZATION CATALYST 审中-公开
标题翻译：制备聚合催化剂的方法
公开(公告)号：WO2010107478A1
公开(公告)日：2010-09-23
申请号：PCT/US2010/000778
申请日：2010-03-15
申请人： CHEVRON PHILLIPS CHEMICAL COMPANY LP , BENHAM, Elizabeth A. , MCDANIEL, Max P. , COLLINS, Kathy S. , WHARRY, Stephen M.
发明人： BENHAM, Elizabeth A. , MCDANIEL, Max P. , COLLINS, Kathy S. , WHARRY, Stephen M.
IPC分类号： C08F10/02 , C08F4/24 , C08F4/69
CPC分类号： C08F10/02 , C08F110/02 , C08F4/69 , C08F4/24 , C08F2500/10 , C08F2500/08 , C08F2500/12
摘要： A method comprising (a) contacting a support and a chromium-containing compound to form chromium-containing support, (b) heat treating the chromium-containing support in an oxidizing atmosphere to form a treated support, (c) contacting the treated support with carbon monoxide to form a CO-contacted support, and (d) contacting the CO-contacted support with hydrogen to form a catalyst. A method comprising oxidizing a chromium-treated support to form a polymerization catalyst, contacting the polymerization catalyst with carbon monoxide to form a reduced polymerization catalyst, contacting the reduced polymerization catalyst with hydrogen to form an activated polymerization catalyst, and contacting the activated polymerization catalyst with ethylene in a reaction zone under suitable reaction conditions to form a random copolymer. A method comprising reducing a polymerization catalyst comprising Cr(VI) to form a polymerization catalyst comprising Cr(II), and treating the polymerization catalyst comprising Cr(II) with hydrogen.
摘要翻译：一种方法，包括（a）使载体和含铬化合物接触以形成含铬载体，（b）在氧化气氛中热处理含铬载体以形成经处理的载体，（c）使经处理的载体与一氧化碳以形成CO-接触的载体，和（d）使CO-接触的载体与氢接触以形成催化剂。一种方法，包括氧化铬处理的载体以形成聚合催化剂，使聚合催化剂与一氧化碳接触以形成还原的聚合催化剂，使还原的聚合催化剂与氢接触以形成活化的聚合催化剂，并使活化的聚合催化剂与乙烯在合适的反应条件下在反应区中形成无规共聚物。一种包括还原包含Cr（VI）的聚合催化剂以形成包含Cr（II）的聚合催化剂并用氢气处理包含Cr（II）的聚合催化剂的方法。

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