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1. 发明申请

WO2007071582A1 MEROCYANINE DERIVATIVES 审中-公开
标题翻译：月桂酰胺衍生物
公开(公告)号：WO2007071582A1
公开(公告)日：2007-06-28
申请号：PCT/EP2006/069516
申请日：2006-12-11
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WAGNER, Barbara , WALTHER, Astrid , HERZOG, Bernd
发明人： WAGNER, Barbara , WALTHER, Astrid , HERZOG, Bernd
IPC分类号： C07C255/31 , C07C317/32 , A61K8/41 , A61Q17/04
CPC分类号： C07C317/44 , C07C255/31 , C07C2601/16
摘要： Disclosed are merocyanine derivatives of formula (1), wherein R 1 and R 2 independently from each other are branched C 4 -C 22 alkyl; or branched C 4 -C 12 alkenyl; R 3 and R 4 independently from each other are cyano; COR 7 , COOR 7 ; CONR 7 R 8 ; SO 2 (C 6 - C 12 )aryl; C 2 -C 12 alk-1-enyl; C 3 -C 12 cycloalk-1-enyl; C 2 -C 12 alk-1-inyl; C 2 -C 12 heteroalkyl; C 3 - C 5 heterocycloalkyl; C 6 -C 10 aryl; or C 1 -C 9 heteroaryl; wherein at least one of R 3 and R 4 is cyano; R 5 and R 6 independently from each other are hydrogen; C 1 -C 6 alkyl; C 5 -C 8 cycloalkyl which may be substituted by one or more than one C 1 -C 4 alkyl; and R 7 and R 8 independently from each other are hydrogen; C 1 -C 22 alkyl; C 2 -C 12 alkenyl; C 2 - C 12 alkinyl; C 3 -C 12 cycloalkyl; C 3 -C 12 cycloalkenyl; -(CH 2 ) t COOH; C 7 -C 12 aralkyl; C 1 - C 12 heteroalkyl; C 2 -C 11 heteroaralkyl; C 6 -C 10 aryl; C 1 -C 9 heteroaryl. The compounds are useful as UV absorbers for protecting human hair and skin against the damaging effect of UV radiation.
摘要翻译：公开了式（1）的部花青衍生物，其中R 1和R 2彼此独立地为支链C 1-4 - 22 烷基; 或支化C 4 -C 12链烯基; R 3和R 4彼此独立地是氰基; COR 7 7，COOR 7; CONR _{7 - [R _{8 ; SO 2（C 6 -C 12）芳基; ç_{2 -C _{12 烷-1-烯基; ç_{3 -C _{12 环烷-1-烯基; ç_{2 -C _{12 烷-1-炔; ç_{2 -C _{12 杂烷基; C 3 -C 5杂环烷基; ç_{6 -C _{10 芳基; 或C 1 -C 9 - 杂芳基; 其中R 3和R 4中的至少一个是氰基; R 5和R 6彼此独立地是氢; ç_{1 -C _{6 烷基; 可以被一个或多于一个C 1 -C 4 - 亚烷基取代的C 5 -C 8环烷基 ; 和R 7和R 8彼此独立地是氢; ç_{1 -C _{22 烷基; ç_{2 -C _{12 烯基; C 2 -C 12炔基; ç_{3 -C _{12 环烷基; ç_{3 -C _{12 环烯基; - （CH _{2 ）_{吨 COOH; ç_{7 -C _{12 芳烷基; C 1 -C 12 - 杂烷基; ç_{2 -C _{11 杂芳烷基; ç_{6 -C _{10 芳基; ç_{1 -C _{9 杂芳基。这些化合物可用作紫外线吸收剂，用于保护人体毛发和皮肤免受紫外线辐射的破坏作用。}}}}}}}}}}}}}}}}}}}}}}}}}}}}}}}}

2. 发明专利

GB0624471D0 Merocyanine Derivatives 未知
公开(公告)号：GB0624471D0
公开(公告)日：2007-01-17
申请号：GB0624471
申请日：2006-12-07
申请人： CIBA SC HOLDING AG , HERZOG BERND , WALTHER ASTRID , WAGNER BARBARA
摘要： Disclosed are merocyanine derivatives of formula (1), wherein R1 and R2 independently from each other are branched C4-C22alkyl; or branched C4-C12 alkenyl; R3 and R4 independently from each other are cyano; COR7, COOR7; CONR7R8; SO2(C6-C12)aryl; C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl; C3-C5heterocycloalkyl; C6-C10aryl; or C1-C9heteroaryl; wherein at least one of R3 and R4 is cyano; R5 and R6 independently from each other are hydrogen; C1-C6alkyl; C5-C8cycloalkyl which may be substituted by one or more than one C1-C4alkyl; and R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; —(CH2)tCOOH; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; C1-C9heteroaryl. The compounds are useful as UV absorbers for protecting human hair and skin against the damaging effect of UV radiation.

3. 发明专利

GB2433499A Merocyanine derivatives useful as UV absorbing agents 未知
公开(公告)号：GB2433499A
公开(公告)日：2007-06-27
申请号：GB0624471
申请日：2006-12-07
申请人： CIBA SC HOLDING AG , WAGNER BARBARA , WALTHER ASTRID , HERZOG BERND
发明人： WAGNER BARBARA , WALTHER ASTRID , HERZOG BERND
IPC分类号： C07C255/31 , A61K8/41 , A61Q17/04
摘要： Merocyanine derivatives of formula (1) wherein R and R are independently branched C4-C22alkyl or branched C4-C12 alkenyl, R3 and R4 are independently cyano, COR , COOR ; CONR R , SO2(C6-C12)aryl, C2-C12alk-1-enyl, C3-C12cycloalk-1-enyl, C2-C12alk-1-inyl: C2-C12heteroalkyl, C3-C5heterocycloalkyl, C6-C10aryl or C1-C9heteroaryl provided at least one of R and R is cyano, R and R are independently hydrogen, C1-C6alkyl, C5-C8cycloalkyl which may be substituted by one or more than one C1-C4alkyl and R and R are independently hydrogen, C1-C22alkyl, C2-C12alkenyl, C2-C12alkinyl, C3-C12cycloalkyl, C3-C12cycloalkenyl, -(CH2)tCOOH, C7-C12aralkyl, C1-C12heteroalkyl, C2-C11heteroaralkyl, C6-C10aryl or C1-C9heteroaryl. A preferred compound is 2- 3-[bis-(2-ethyl-hexyl)-amino]-cyclohex-2-enylidene -malononitrile. The compounds are useful as UV absorbers for protecting human hair and skin against the damaging effect of UV radiation, e.g. in cosmetic compositions such as anti-wrinkle perception modifiers.

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