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    • 4. 发明授权
    • Process for preparing siloxane-based compositions and derivative compositions thereof
    • 制备硅氧烷基组合物及其衍生物组合物的方法
    • US08742008B2
    • 2014-06-03
    • US12440603
    • 2007-09-18
    • Qionghua ShenWalter J. Sherwood, Jr.Christopher K. Whitmarsh
    • Qionghua ShenWalter J. Sherwood, Jr.Christopher K. Whitmarsh
    • C08L83/00C08L83/04
    • C08G77/12C08G77/06C08G77/20C08G77/44C08L83/04C08L83/14C09D183/04H05K1/032H05K1/0373
    • A process for forming a new group of siloxane-based compositions by a one-step co-hydrolysis and the compositions formed thereof. The siloxane-based compositions being functionalized with a carbon-carbon double (C═C) bond and a silicon-hydrogen (Si—H) bond. The C═C bond and hydrogen (H) each being attached directly to a silicon (Si) atom of the silicon-oxygen (Si—O) backbone of the siloxane-based composition. The C═C bond may be from a vinyl or an aromatic radical like a phenyl substituent. The C═C bond substituent provides the functionality needed for forming crosslinkages through standard dehydrocoupling catalysts without the need for siloxane fluids or organic compounds containing alkyl or aryl functional groups. The process provides for varying proportions of silanes as starting monomers to tailor the desired silicon, carbon, hydrogen and oxygen ratios in the siloxane-based compositions or resins. The siloxane-based compositions may be used as precursors or replacement resins in the fabrication of other materials.
    • 通过一步共水解形成新的基于硅氧烷的组合物组合物的方法及其形成的组合物。 基于硅氧烷的组合物用碳 - 碳双(C = C)键和硅 - 氢(Si-H)键进行官能化。 C = C键和氢(H)各自直接连接到硅氧烷基组合物的硅 - 氧(Si-O)主链的硅(Si)原子上。 C = C键可以是乙烯基或芳基,如苯基取代基。 C = C键取代基提供通过标准脱氢键合催化剂形成交联所需的官能度,而不需要硅氧烷流体或含有烷基或芳基官能团的有机化合物。 该方法提供不同比例的硅烷作为起始单体,以定制硅氧烷基组合物或树脂中所需的硅,碳,氢和氧比。 基于硅氧烷的组合物可以在其它材料的制造中用作前体或替代树脂。
    • 5. 发明申请
    • PROCESS FOR PREPARING SILOXANE-BASED COMPOSITIONS AND DERIVATIVE COMPOSITIONS THEREOF
    • 制备基于硅氧烷的组合物及其衍生物组合物的方法
    • US20090275695A1
    • 2009-11-05
    • US12440603
    • 2007-09-18
    • Qionghua ShenWalter J. Sherwood, JR.Christopher K. Whitmarsh
    • Qionghua ShenWalter J. Sherwood, JR.Christopher K. Whitmarsh
    • C08L83/06C08G77/20C08G77/14C08G77/08
    • C08G77/12C08G77/06C08G77/20C08G77/44C08L83/04C08L83/14C09D183/04H05K1/032H05K1/0373
    • A process for forming a new group of siloxane-based compositions by a one-step co-hydrolysis and the compositions formed thereof. The siloxane-based compositions being functionalized with a carbon-carbon double (C═C) bond and a silicon-hydrogen (Si—H) bond. The C═C bond and hydrogen (H) each being attached directly to a silicon (Si) atom of the silicon-oxygen (Si—O) backbone of the siloxane-based composition. The C═C bond may be from a vinyl or an aromatic radical like a phenyl substituent. The C═C bond substituent provides the functionality needed for forming crosslinkages through standard dehydrocoupling catalysts without the need for siloxane fluids or organic compounds containing alkyl or aryl functional groups. The process provides for varying proportions of silanes as starting monomers to tailor the desired silicon, carbon, hydrogen and oxygen ratios in the siloxane-based compositions or resins. The siloxane-based compositions may be used as precursors or replacement resins in the fabrication of other materials.
    • 通过一步共水解形成新的基于硅氧烷的组合物组合物的方法及其形成的组合物。 基于硅氧烷的组合物用碳 - 碳双(C-C)键和硅 - 氢(Si-H)键进行官能化。 C-C键和氢(H)各自直接连接到硅氧烷基组合物的硅 - 氧(Si-O)主链的硅(Si)原子上。 C-C键可以是乙烯基或芳基,如苯基取代基。 C-C键取代基提供通过标准脱氢耦合催化剂形成交联所需的官能团,而不需要硅氧烷流体或含有烷基或芳基官能团的有机化合物。 该方法提供不同比例的硅烷作为起始单体,以定制硅氧烷基组合物或树脂中所需的硅,碳,氢和氧比。 基于硅氧烷的组合物可以在其它材料的制造中用作前体或替代树脂。