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1. 发明授权

US07688075B2 Lithium sulfur rechargeable battery fuel gauge systems and methods 有权
标题翻译：锂硫可再充电电池燃油表系统及方法
公开(公告)号：US07688075B2
公开(公告)日：2010-03-30
申请号：US11111262
申请日：2005-04-20
申请人： Tracy E Kelley , Chariclea Scordilis-Kelley , Vincent J Puglisi
发明人： Tracy E Kelley , Chariclea Scordilis-Kelley , Vincent J Puglisi
IPC分类号： G01N27/413 , H02J7/00
CPC分类号： G01R31/3662 , G01R31/3679
摘要： Systems and methods for accurately determining the state of charge and the relative age of lithium sulfur batteries are provided. The cell resistance and taper input charge of a particular type of lithium sulfur battery are respectively measured to determine the state of charge and age of the battery.
摘要翻译：提供了准确确定充电状态和锂硫电池相对年龄的系统和方法。分别测量特定类型的锂硫电池的电池电阻和锥度输入电荷，以确定电池的充电状态和使用寿命。

2. 发明授权

US06436575B1 Pasted positive electrode and process for its production 失效
标题翻译：粘贴正极及其生产工艺
公开(公告)号：US06436575B1
公开(公告)日：2002-08-20
申请号：US09191562
申请日：1998-11-13
申请人： John J. Weckesser , Canan Balaban , Vincent J. Puglisi , Robert Czajkowski , Guy Rampel , James Waggoner
发明人： John J. Weckesser , Canan Balaban , Vincent J. Puglisi , Robert Czajkowski , Guy Rampel , James Waggoner
IPC分类号： H01M464
CPC分类号： H01M4/742 , H01M4/32 , H01M4/52 , H01M4/621
摘要： The present invention provides a positive electrode for a rechargeable cell including a two dimensional electrically conductive substrate supporting a coating comprising nickel hydroxide and a binder, preferably a styrene-ethylene/butylene-styrene triblock copolymer binder. The coating is formed by applying a paste to the two-dimensional substrate surface. The present invention also includes the cell made therefrom. The present invention further provides a method of producing this electrode including the steps of forming the paste and coating the paste onto the two-dimensional substrate. The capacity, midpoint voltage and power delivery of the coated electrode are comparable to or exceed those of traditional sintered and foam positive electrodes.
摘要翻译：本发明提供了一种用于可再充电电池的正电极，其包括支撑包含氢氧化镍和粘合剂，优选苯乙烯 - 乙烯/丁烯 - 苯乙烯三嵌段共聚物粘合剂的涂层的二维导电基材。通过将糊剂施加到二维基材表面来形成涂层。本发明还包括由其制成的电池。本发明还提供一种制造该电极的方法，包括以下步骤：形成糊状物并将该糊剂涂覆在二维基质上。涂覆电极的容量，中点电压和功率输出与传统烧结和泡沫正极的容量，中点电压和功率输出相当或超过传统烧结和泡沫正极的容量，中点电压和功率输送。

3. 发明授权

US4292143A Method of making sintered plaque nickel electrodes 失效
标题翻译：制造烧结斑块镍电极的方法
公开(公告)号：US4292143A
公开(公告)日：1981-09-29
申请号：US126640
申请日：1980-03-03
申请人： Harvey N. Seiger , Vincent J. Puglisi
发明人： Harvey N. Seiger , Vincent J. Puglisi
IPC分类号： H01M4/29 , H01M4/32 , H01M4/80 , H01M10/44 , C25D11/00
CPC分类号： H01M4/29 , H01M4/32 , H01M4/80
摘要： The improved method of the invention comprises electrochemically depositing nickel hydroxide into the pores of a clean sintered nickel plaque cathode from heated aqueous electrolyte at acid pH in a treating zone containing an anode, while minimizing corrosion of the plaque. The electrochemical deposition is continued only until a loading level of about 2 grams per cubic centimeter of void volume in the plaque is obtained. This is in order to avoid thickening, swelling and stressing of the plaque. The method is carried out without the need for a wetting agent in the electrolyte. The plaque should be sufficiently clean so as to be readily wetted throughout by the electrolyte. Such a clean condition can be produced by heating the plaque to at least about 700.degree. C. Plaque corrosion is minimized by polarizing the plaque cathode as by the use of a sacrificial cadmium cathode. Plaque corrosion can also be minimized by maintaining an electric current in the electrolyte whenever the plaque is present therein. It is preferred to carry out the deposition while applying a substantially constant level of current to the electrodes. Loading levels of nickel hydroxide in excess of 7.7 ampere hours per cubic inch can be effected for an improved product.
摘要翻译：本发明的改进方法包括在含有阳极的处理区中将氢氧化镍电化学沉积在酸性pH下的加热的含水电解质的清洁的烧结镍斑块阴极的孔中，同时最小化斑块的腐蚀。电化学沉积继续进行，直到得到斑块中约2克/立方厘米空隙体积的负载水平。这是为了避免斑块的增厚，肿胀和压力。该方法在电解质中不需要润湿剂的情况下进行。斑块应足够清洁，以便易于被电解液润湿。这样一个干净的条件可以通过将该板加热到至少约700℃来产生。通过使用牺牲镉阴极使斑块阴极极化，使得斑块腐蚀最小化。当斑块存在于其中时，通过保持电解质中的电流也可以最小化斑块腐蚀。优选在对电极施加大致恒定电流的电流的同时进行沉积。可以对改进的产品进行氢氧化镍的装载量超过7.7安培小时/立方英寸。

4. 发明授权

US5466546A Positive nickel electrode for nickel metal hydride cells 失效
标题翻译：用于镍金属氢化物电池的正镍电极
公开(公告)号：US5466546A
公开(公告)日：1995-11-14
申请号：US24148
申请日：1993-03-01
申请人： Saverio F. Pensabene , Vincent J. Puglisi
发明人： Saverio F. Pensabene , Vincent J. Puglisi
IPC分类号： H01M4/02 , H01M4/32 , H01M4/52 , H01M10/34
CPC分类号： H01M4/32 , H01M10/345 , H01M4/52 , H01M2004/028
摘要： A positive electrode for use in a rechargeable nickel metal hydride cell and method of manufacture is disclosed. The electrode includes an electrically conductive substrate and an electrochemically active material. The active material includes nickel hydroxide carried by the substrate. A calcium-containing compound is deposited onto the active material to coat the active material with calcium.
摘要翻译：公开了一种用于可再充电镍金属氢化物电池的正电极及其制造方法。电极包括导电基底和电化学活性材料。活性材料包括由基底承载的氢氧化镍。将含钙化合物沉积在活性材料上以用钙涂覆活性材料。

5. 发明授权

US5002842A End plate for a metal gas cell 失效
标题翻译：金属气室的端板
公开(公告)号：US5002842A
公开(公告)日：1991-03-26
申请号：US465694
申请日：1990-01-16
申请人： Vincent J. Puglisi , Guy G. Rampe , Kenneth R. Richardson , Orville G. Prickett
发明人： Vincent J. Puglisi , Guy G. Rampe , Kenneth R. Richardson , Orville G. Prickett
IPC分类号： H01M2/02 , H01M10/34
CPC分类号： H01M10/345 , H01M2/0255
摘要： A support assembly, including an end plate, for use in metal gas cells. The support assembly inhibits a plate stack which is positioned within a pressure vessel from impinging the walls of the pressure vessel. The support assembly comprises a first and a second weld ring and a first and a second end plate, each of the end plates being attached to a different end of the plate stack. The first and second weld rings mate with the first and second end plates, respectively, and cooperate to support the plate stack. The end plate comprises two plates secured together. A raised portion on one of the plates forming the end plate has a radially extending embossment formed therein to increase the rigidity thereof. The pressure vessel is constructed of generally cylindrical container defining two circumferentially extending lips, each of which is secured to an end portion.
摘要翻译：一种用于金属气体池的支撑组件，包括端板。支撑组件抑制位于压力容器内的板堆撞击压力容器的壁。支撑组件包括第一和第二焊接环以及第一和第二端板，每个端板附接到板堆叠的不同端部。第一和第二焊接圈分别与第一和第二端板配合，并配合以支撑板堆叠。端板包括固定在一起的两个板。形成端板的一个板上的凸起部分具有形成在其中的径向延伸的压花以增加其刚度。压力容器由通常为圆柱形的容器构成，限定两个周向延伸的唇缘，每个唇缘固定到端部。

6. 发明授权

US5141523A Rechargeable nickel electrode containing electrochemical cell and method 失效
标题翻译：含电化学电池的可充电镍电极及方法
公开(公告)号：US5141523A
公开(公告)日：1992-08-25
申请号：US719459
申请日：1991-06-24
申请人： Arthur J. Catotti , Saverio F. Pensabene , Douglas B. Frye , Vincent J. Puglisi
发明人： Arthur J. Catotti , Saverio F. Pensabene , Douglas B. Frye , Vincent J. Puglisi
IPC分类号： H01M4/02 , H01M4/38 , H01M4/48 , H01M4/52 , H01M4/62 , H01M4/66 , H01M4/80 , H01M6/10 , H01M10/34
CPC分类号： H01M4/803 , H01M10/34 , H01M4/622 , H01M4/623 , H01M6/10 , H01M2004/027 , H01M4/383 , H01M4/48 , H01M4/52 , H01M4/661 , H01M4/808 , Y10T29/49115
摘要： A sealed rechargeable nickel electrode containing electrochemical cell has a pasted negative electrode having paste layers adhered to a nonforaminous conductive substrate, which retards growth (swelling) of the nickel electrode on cycling.
摘要翻译：包含电化学电池的密封可再充电镍电极具有糊状负极，其具有粘附到非阻隔导电基底上的糊层，其延迟镍电极在循环时的生长（膨胀）。

7. 发明授权

US5106707A Rechargeable nickel electrode containing electrochemical cell 失效
标题翻译：含镍电极电解电容器
公开(公告)号：US5106707A
公开(公告)日：1992-04-21
申请号：US529084
申请日：1990-05-25
申请人： Arthur J. Catotti , Saverio F. Pensabene , Douglas B. Frye , Vincent J. Puglisi
发明人： Arthur J. Catotti , Saverio F. Pensabene , Douglas B. Frye , Vincent J. Puglisi
IPC分类号： H01M4/02 , H01M4/04 , H01M4/24 , H01M4/38 , H01M4/48 , H01M4/52 , H01M4/62 , H01M4/66 , H01M4/80 , H01M6/10 , H01M10/34
CPC分类号： H01M4/661 , H01M10/34 , H01M4/0404 , H01M4/24 , H01M4/622 , H01M4/623 , H01M4/803 , H01M6/10 , H01M2004/021 , H01M2004/027 , H01M4/043 , H01M4/0497 , H01M4/383 , H01M4/48 , H01M4/52 , H01M4/808
摘要： A sealed rechargeable nickel electrode containing electrochemical cell has a pasted negative electrode having paste layers adhered to a nonforaminous conductive substrate, which retards growth (swelling) of the nickel electrode on cycling.
摘要翻译：包含电化学电池的密封可再充电镍电极具有糊状负极，其具有粘附到非阻隔导电基底上的糊层，其延迟镍电极在循环时的生长（膨胀）。

8. 发明授权

US5064735A Cadium electrode and process for its production 失效
标题翻译： CADIUM电极及其生产工艺
公开(公告)号：US5064735A
公开(公告)日：1991-11-12
申请号：US382816
申请日：1989-07-19
申请人： Guy G. Rampel , Vincent J. Puglisi
发明人： Guy G. Rampel , Vincent J. Puglisi
IPC分类号： H01M4/44 , H01M4/24 , H01M4/26 , H01M4/36 , H01M4/52 , H01M4/62 , H01M4/66 , H01M4/74 , H01M4/80 , H01M10/52
CPC分类号： H01M4/666 , H01M4/246 , H01M4/26 , H01M4/364 , H01M4/621 , H01M4/622 , H01M4/623 , H01M4/742 , H01M4/745 , H01M4/747 , H01M4/801 , H01M4/806 , H01M10/526 , H01M4/52 , H01M4/62 , H01M4/661 , H01M4/808 , Y10T29/49115
摘要： A cadmium electrode for use in rechargeable alkaline cells is disclosed featuring use of dispersed polyamide having specific properties. The polyamide serves as a binder as well as an anti-agglomerant to retard cadmium agglomeration during use of the electrode. The use of elemental silver additive dispersed throughout the electrode is also disclosed, as is the use of zirconium material as an elecrolyte wicking and anti-compressive agent. A process for making any of the foregoing electrodes is disclosed featuring the step of forming a paste by mixing together the polymeric resin, active cadmium material and a non-aqueous solvent, applying the paste to a conductive substrate and removing the solvent. Alternatively, known prefabricated cadmium electrodes, such as Teflon-bonded or sintered types, are post-treated through dipping or the like in a solution of the aforementioned polyamide.

9. 发明授权

US4950564A Metal gas cell 失效
标题翻译：金属气室
公开(公告)号：US4950564A
公开(公告)日：1990-08-21
申请号：US189264
申请日：1988-05-02
申请人： Vincent J. Puglisi , Guy G. Rampel , Kenneth R. Richardson , Orville G. Prickett
发明人： Vincent J. Puglisi , Guy G. Rampel , Kenneth R. Richardson , Orville G. Prickett
IPC分类号： H01M4/64 , H01M2/02 , H01M10/34 , H01M12/08
CPC分类号： H01M10/345 , H01M2/0255
摘要： A support assembly, including an end plate, for use in metal gas cells. The support assembly inhibits a plate stack which is positioned within a pressure vessel from impinging the walls of the pressure vessel. The support assembly comprises a first and a second weld ring and a first and a second end plate, each of the end plates being attached to a different end of the plate stack. The first and second weld rings mate with the first and second end plates, respectively, and cooperate to support the plate stack. The end plate comprises two plates secured together. A raised portion on one of the plates forming the end plate has a radially extending embossment formed therein to increase the rigidity thereof. The pressure vessel is constructed of generally cylindrical container defining two circumferentially extending lips, each of which is secured to an end portion.

10. 发明授权

US4120757A Method of making sintered plaque cadmium electrodes 失效
标题翻译：制造烧结镉镉电极的方法
公开(公告)号：US4120757A
公开(公告)日：1978-10-17
申请号：US854928
申请日：1977-11-25
申请人： Harvey N. Seiger , Vincent J. Puglisi
发明人： Harvey N. Seiger , Vincent J. Puglisi
IPC分类号： H01M4/29 , C25D9/08 , C25B1/16 , C25B11/06
CPC分类号： H01M4/29
摘要： The improved method of the invention comprises electrochemically depositing cadmium hydroxide into the pores of a sintered nickel plaque cathode from a heated electrolyte at acid pH and at controlled density in a treating zone containing an anode, at least periodically contacting the electrolyte during the electro chemical deposition with neutralizing agent selected from cadmium oxide and cadmium hydroxide to neutralize acid generated at the anode, and continuing the electrochemical deposition until an improved loading level of cadmium hydroxide within the cathode is obtained. The acid pH preferably is between 2 - 5 and the electrolyte preferably is in a concentration of 2 - 3 M and at an average temperature of about 85.degree. - 105.degree. C. Preferably, the current density is maintained at a level of less than one ampere per square inch in order to improve the loading level, which may be as high as about 2.6 grams of cadmium hydroxide per cubic centimeter of void volume in the cathode. The neutralizing agent may be disposed in a porous container in a separate reservoir zone connected to the treating zone so that the electrolyte can circulate therebetween and into direct contact with the neutralizing agent. The method results in a loading level of cadmium hydroxide in the sintered nickel plaque cathode as high as or higher than previously obtained and in a shorter period of time. The method is simple, inexpensive and efficient.
摘要翻译：本发明的改进方法包括将氢氧化镉电化学沉积在烧结的镍斑块阴极的孔中，从酸性pH下的加热电解质和含有阳极的处理区的受控密度，在电化学沉积期间至少周期性地接触电解质使用选自氧化镉和氢氧化镉的中和剂来中和阳极产生的酸，并且继续进行电化学沉积，直到获得阴极内氢氧化镉的改善的负载水平。酸性pH优选在2-5之间，电解质优选浓度为2-3M，平均温度约为85-105℃。优选地，电流密度保持在小于1的水平安培每平方英寸，以提高负载水平，其可以高达约2.6克氢氧化镉/立方厘米的阴极中的空隙体积。中和剂可以设置在与处理区连接的单独储存区中的多孔容器中，使得电解质可以在其间循环并与中和剂直接接触。该方法导致烧结镍斑块阴极中的氢氧化镉的负载水平高达或高于先前获得的并且在更短的时间段内。该方法简单，便宜，高效。

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