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1. 发明授权

US08598280B2 Poly(meth)acrylimide having improved optical and color properties, particularly under thermal load 有权
标题翻译：具有改善的光学和颜色特性的聚（甲基）丙烯酰亚胺，特别是在热负载下
公开(公告)号：US08598280B2
公开(公告)日：2013-12-03
申请号：US12922627
申请日：2009-02-27
申请人： Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
发明人： Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
IPC分类号： C08F8/32 , C08F8/30 , C08F8/40
CPC分类号： C08K5/5313 , C08L33/24
摘要： Process for preparing molding materials MM with improved optical and color properties, consisting of a polymer PM which contains units of the formula I in which R1 and R2 are each hydrogen and methyl and R3 is hydrogen, C1-C18-alkyl, C5-C8-cycloalkyl, C6-C10-aryl, C6-C10-aryl-C1-C4-alkyl, where these radicals may be up to trisubstituted by radicals selected from the group consisting of C1-C4-alkoxy and halogen, prepared in an imidation reaction known per se in a reactive extruder, in which, on completion of the imidation reaction, an amount of one or more reducing phosphorus compounds P which is effective for color stabilization is added to the polymer PM, characterized in that the phosphorus compounds are organic phosphorus compounds OP selected from the group consisting of compounds of the formula II in which R4 and R5 are each independently hydrogen or an aromatic 6-membered ring which may be up to pentasubstituted by a C1-C4-alkyl and/or C5-C8-cycloalkyl groups. Shaped bodies obtainable by the process, especially light waveguides, have a low tendency to yellowing under thermal stress, coupled with a low haze, and also a stable and high transparency.
摘要翻译：用于制备具有改进的光学和颜色特性的成型材料MM的方法由包含式I的单元的聚合物PM组成，其中R 1和R 2各自为氢，甲基和R 3为氢，C 1 -C 18烷基，C 5 -C 8 - 环烷基，C 6 -C 10 - 芳基，C 6 -C 10 - 芳基-C 1 -C 4 - 烷基，其中这些基团可以被三取代的基团选自C1-C4-烷氧基和卤素，在酰亚胺化反应中制备已知本身在反应性挤出机中，其中在完成酰亚胺化反应时，将一种或多种对颜色稳定有效的还原磷化合物P的量加入到聚合物PM中，其特征在于磷化合物是有机磷化合物 OP选自由式II化合物组成的组，其中R 4和R 5各自独立地为氢或可被C 1 -C 4 - 烷基和/或C 5 -C 8 - 环烷基直接五取代的芳族六元环。通过该方法可获得的成形体，特别是光波导，在热应力下具有低的黄变倾向，并伴有低雾度，并且还具有稳定和高透明度。

2. 发明申请

US20150376437A1 PMMA PROVIDED WITH IMPACT RESISTANCE AND HAVING IMPROVED OPTICAL PROPERTIES 有权
标题翻译： PMMA具有抵抗力并具有改进的光学性能
公开(公告)号：US20150376437A1
公开(公告)日：2015-12-31
申请号：US14772618
申请日：2014-03-19
申请人： Victor KHRENOV , Werner HÖSS , Reiner MÜLLER , Lukas Friedrich DÖSSEL , Dominic STÖRKLE
发明人： Werner HOESS , Victor KHRENOV , Reiner MUELLER , Lukas Friedrich DOESSEL , Dominic STOERKLE
IPC分类号： C09D133/08 , C09D125/12 , C09D125/14
CPC分类号： C09D133/08 , C08F220/14 , C08F220/18 , C08F285/00 , C08L51/003 , C08L2207/53 , C09D125/12 , C09D125/14 , C08F2220/1808 , C08F220/40 , C08F2220/1825 , C08F212/08 , C08L33/12
摘要： The invention relates to a moulding composition modified for impact resistance, in particular to impact-resistant PMMA with improved optical properties at elevated temperatures, to moulded items obtainable therefrom, and also to the use of the moulding composition and of the moulded items.
摘要翻译：本发明涉及改性耐冲击性的成型组合物，特别涉及在高温下具有改进的光学性能的耐冲击PMMA，以及由其获得的模制品，以及模塑组合物和模制品的用途。

3. 发明申请

US20130203918A1 WEATHERING-RESISTANT, COLORED MOLDINGS WITH IMPROVED GLOSS AND WIPE RESISTANCE 有权
标题翻译：耐候耐用，具有改进的胶和耐擦性的彩色模具
公开(公告)号：US20130203918A1
公开(公告)日：2013-08-08
申请号：US13824624
申请日：2011-08-22
申请人： Victor Khrenov , Andreas Mischlich , Ursula Golchert , Stefan Nau , Anton Halblaender , Klaus Schultes , Marc Poth , Antonios Manis , Kathrin Lehmann , Zhen Zhu
发明人： Victor Khrenov , Andreas Mischlich , Ursula Golchert , Stefan Nau , Anton Halblaender , Klaus Schultes , Marc Poth , Antonios Manis , Kathrin Lehmann , Zhen Zhu
IPC分类号： C08K5/5419
CPC分类号： C08K5/5419 , C08L33/08 , C08L33/10 , C08L83/04 , C08L83/00
摘要： The present invention relates to weathering-resistant, colored moldings made of poly(alkyl) (meth)acrylate with improved gloss and resistance to mechanical influences acting on the surface of the molding, in particular with improved wipe resistance and improved scratch resistance, and also to molding compositions for producing the same.
摘要翻译：本发明涉及具有改善的光泽度和抗机械影响的聚（烷基）（甲基）丙烯酸酯制成的耐候性着色模制品，特别是具有改进的耐擦拭性和改善的耐刮擦性，以及成型用组合物。

4. 发明申请

US20130096244A1 WATER-BASED LIQUID COLOR CONTAINING THERMOSTABLE DISPERSION ADDITIVES FOR THE COLORING POLY(METH)ACRYLATES 审中-公开
标题翻译：含有聚合（甲基）丙烯酸酯的可热分解添加剂的水基液体颜料
公开(公告)号：US20130096244A1
公开(公告)日：2013-04-18
申请号：US13806322
申请日：2011-07-05
申请人： Sabine Schwarz-Barac , Roger Recktenwald , Thorsten Goldacker , Ursula Golchert , Victor Khrenov , Stefan Nau , Nils Mehler , Krzysztof Sado , Ernst Becker , Norbert Bendzko , Joachim Henn , Markus Vogt , Markus Schubert , Daniel Cleff , Birgit Riedel-Bendzko
发明人： Sabine Schwarz-Barac , Roger Recktenwald , Thorsten Goldacker , Ursula Golchert , Victor Khrenov , Stefan Nau , Nils Mehler , Krzysztof Sado , Ernst Becker , Norbert Bendzko , Joachim Henn , Markus Vogt , Markus Schubert , Daniel Cleff , Birgit Riedel-Bendzko
IPC分类号： C08L33/10
CPC分类号： C08L33/10 , C08K5/0008 , C08K5/0041 , C09B67/0013 , C09B67/009 , C08L33/12
摘要： The invention relates to a method for coloring thermoplastic molding compounds, preferably a polymethyl(meth)acrylate molding compound, using novel aqueous colorant preparations. The invention further relates to a novel water-based colorant preparation.
摘要翻译：本发明涉及使用新的含水着色剂制剂着色热塑性模塑料，优选聚（甲基）丙烯酸（甲基）丙烯酸甲酯模塑料的方法。本发明还涉及一种新型的水性着色剂制剂。

5. 发明申请

US20130096237A1 COMPOSITE MATERIAL MADE OF A MATERIAL CONTAINING CELLULOSE WITH PMMA AS A PLASTIC MATRIX USING DIFFERENT COUPLING COMPONENTS 审中-公开
标题翻译：包含纤维素的材料与PMMA的复合材料作为使用不同的耦合组分的塑料基质
公开(公告)号：US20130096237A1
公开(公告)日：2013-04-18
申请号：US13703746
申请日：2011-06-01
申请人： Carlo Schuetz , Christian Roth , Ruediger Carloff , Klaus Schultes , Victor Khrenov , Eric Reinheimer
发明人： Carlo Schuetz , Christian Roth , Ruediger Carloff , Klaus Schultes , Victor Khrenov , Eric Reinheimer
IPC分类号： C08L33/12
CPC分类号： C08L33/12 , B29C48/92 , B29C2948/92704 , C08J5/045 , C08J5/10 , C08J2333/06 , C08J2400/22 , C08L97/02 , C08L2666/26 , C08L33/08
摘要： The invention relates to novel composite materials with improved mechanical properties and improved weathering resistance, said composite materials being made of at least one material containing cellulose, preferably wood, and at least one plastic, and to a method for producing said composite materials and for using same.
摘要翻译：本发明涉及具有改善的机械性能和改善的耐候性的新型复合材料，所述复合材料由至少一种含有纤维素，优选木材和至少一种塑料的材料制成，以及一种生产所述复合材料并用于相同。

6. 发明申请

US20110015317A1 POLY(METH)ACRYLIMIDE HAVING IMPROVED OPTICAL AND COLOR PROPERTIES, PARTICULARLY UNDER THERMAL LOAD 有权
标题翻译：具有改进的光学和颜色特性的聚（甲基）丙烯酰亚胺，特别是在热负载下
公开(公告)号：US20110015317A1
公开(公告)日：2011-01-20
申请号：US12922627
申请日：2009-02-27
申请人： Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
发明人： Victor Khrenov , Krzysztof Sado , Nils Mehler , Klaus Schultes , Klaus Albrecht
IPC分类号： C08K5/5313
CPC分类号： C08K5/5313 , C08L33/24
摘要： Process for preparing moulding materials MM with improved optical and colour properties, consisting of a polymer PM which contains units of the formula I in which R1 and R2 are each hydrogen and methyl and R3 is hydrogen, C1-C18-alkyl, C5-C8-cycloalkyl, C6-C10-aryl, C6-C10-aryl-C1-C4-alkyl, where these radicals may be up to trisubstituted by radicals selected from the group consisting of C1-C4-alkoxy and halogen, prepared in an imidation reaction known per se in a reactive extruder, in which, on completion of the imidation reaction, an amount of one or more reducing phosphorus compounds P which is effective for colour stabilization is added to the polymer PM, characterized in that the phosphorus compounds are organic phosphorus compounds OP selected from the group consisting of compounds of the formula II in which R4 and R5 are each independently hydrogen or an aromatic 6-membered ring which may be up to pentasubstituted by a C1-C4-alkyl and/or C5-C8-cycloalkyl groups. Shaped bodies obtainable by the process, especially light waveguides, have a low tendency to yellowing under thermal stress, coupled with a low haze, and also a stable and high transparency.
摘要翻译：用于制备具有改进的光学和颜色特性的成型材料MM的方法由包含式I的单元的聚合物PM组成，其中R 1和R 2各自为氢，甲基和R 3为氢，C 1 -C 18烷基，C 5 -C 8 - 环烷基，C 6 -C 10 - 芳基，C 6 -C 10 - 芳基-C 1 -C 4 - 烷基，其中这些基团可以被三取代的基团选自C1-C4-烷氧基和卤素，在酰亚胺化反应中制备已知本身在反应性挤出机中，其中在完成酰亚胺化反应时，将一种或多种对颜色稳定有效的还原磷化合物P的量加入到聚合物PM中，其特征在于磷化合物是有机磷化合物 OP选自由式II的化合物组成的组，其中R 4和R 5各自独立地为氢或可被C 1 -C 4 - 烷基和/或C 5 -C 8 - 环烷基直接五取代的芳香族6元环。通过该方法可获得的成形体，特别是光波导，在热应力下具有低的黄变倾向，并伴有低雾度，并且还具有稳定和高透明度。

7. 发明申请

US20070154709A1 Nanoparticles 审中-公开
标题翻译：纳米颗粒
公开(公告)号：US20070154709A1
公开(公告)日：2007-07-05
申请号：US10587299
申请日：2004-12-15
申请人： Matthias Koch , Victor Khrenov , Markus Klapper , Klaus Muellen
发明人： Matthias Koch , Victor Khrenov , Markus Klapper , Klaus Muellen
IPC分类号： B32B15/00
CPC分类号： B82Y30/00 , C01B13/14 , C01B13/32 , C01G9/02 , C01P2002/84 , C01P2004/62 , C01P2004/64 , C09C1/043 , C09C3/10 , Y10T428/294
摘要： The invention relates to polymer-modified nanoparticles which are suitable as UV stabilisers in polymers, characterised in that they are obtainable by a process in which, in a step a), an inverse emulsion comprising one or more water-soluble precursors of the nanoparticles or a melt is prepared with the aid of a random copolymer of at least one monomer containing hydrophobic radicals and at least one monomer containing hydrophilic radicals, and, in a step b), particles are produced, and to the use thereof for UV protection in polymers.
摘要翻译：本发明涉及适合作为聚合物中的UV稳定剂的聚合物改性的纳米颗粒，其特征在于它们可通过以下方法获得：在步骤a）中，包含一种或多种纳米颗粒的水溶性前体的反相乳液或借助于至少一种含有疏水基团的单体和至少一种含有亲水基团的单体的无规共聚物制备熔体，并且在步骤b）中，制备颗粒，并且其用于聚合物中的UV保护。

8. 发明授权

US09988548B2 PMMA provided with impact resistance and having improved optical properties 有权
公开(公告)号：US09988548B2
公开(公告)日：2018-06-05
申请号：US14772618
申请日：2014-03-19
申请人： Werner Hoess , Victor Khrenov , Reiner Mueller , Lukas Friedrich Doessel , Dominic Stoerkle
发明人： Werner Hoess , Victor Khrenov , Reiner Mueller , Lukas Friedrich Doessel , Dominic Stoerkle
IPC分类号： C08L83/00 , C09D133/08 , C08F220/14 , C08F220/18 , C08F285/00 , C08L51/00 , C09D125/12 , C09D125/14
CPC分类号： C09D133/08 , C08F220/14 , C08F220/18 , C08F285/00 , C08L51/003 , C08L2207/53 , C09D125/12 , C09D125/14 , C08F2220/1808 , C08F220/40 , C08F2220/1825 , C08F212/08 , C08L33/12
摘要： The invention relates to a molding composition modified for impact resistance, in particular to impact-resistant PMMA with improved optical properties at elevated temperatures, to molded items obtainable therefrom, and also to the use of the molding composition and of the molded items.

9. 发明授权

US08962728B2 Weathering-resistant, colored moldings with improved gloss and wipe resistance 有权
标题翻译：防风化，着色的模制品具有改善的光泽和耐擦拭性
公开(公告)号：US08962728B2
公开(公告)日：2015-02-24
申请号：US13824624
申请日：2011-08-22
申请人： Victor Khrenov , Andreas Mischlich , Ursula Golchert , Stefan Nau , Anton Halblaender , Klaus Schultes , Marc Poth , Antonios Manis , Kathrin Lehmann , Zhen Zhu
发明人： Victor Khrenov , Andreas Mischlich , Ursula Golchert , Stefan Nau , Anton Halblaender , Klaus Schultes , Marc Poth , Antonios Manis , Kathrin Lehmann , Zhen Zhu
IPC分类号： C08K5/5419
CPC分类号： C08K5/5419 , C08L33/08 , C08L33/10 , C08L83/04 , C08L83/00
摘要： The present invention relates to weathering-resistant, colored moldings made of poly(alkyl)(meth)acrylate with improved gloss and resistance to mechanical influences acting on the surface of the molding, in particular with improved wipe resistance and improved scratch resistance, and also to molding compositions for producing the same.
摘要翻译：本发明涉及具有改善的光泽度和抗机械影响的聚（烷基）（甲基）丙烯酸酯制成的耐候性着色模制品，特别是具有改进的耐擦拭性和改善的耐刮擦性，以及成型用组合物。

10. 发明申请

US20130079439A1 COMPOSITE MATERIAL MADE OF A MATERIAL CONTAINING CELLULOSE AND A PLASTIC MATERIAL 审中-公开
标题翻译：含有纤维素和塑料的材料的复合材料
公开(公告)号：US20130079439A1
公开(公告)日：2013-03-28
申请号：US13702243
申请日：2011-06-01
申请人： Carlo Schuetz , Christian Roth , Ruediger Carloff , Klaus Schultes , Victor Khrenov , Eric Reinheimer
发明人： Carlo Schuetz , Christian Roth , Ruediger Carloff , Klaus Schultes , Victor Khrenov , Eric Reinheimer
IPC分类号： C08L97/02
CPC分类号： C08L97/02 , C08J5/04 , C08J2301/02 , C08J2333/12 , C08J2397/02 , C08L1/02 , C08L33/04 , C08L33/12 , C08L2205/02 , C08L2666/26 , C08L2666/04 , C08L91/06
摘要： The invention relates to novel composite materials which are made of at least one material containing cellulose, preferably wood, and at least one plastic material, and which have improved mechanical and weather resistance properties.
摘要翻译：本发明涉及由含有纤维素，优选木材和至少一种塑料材料的至少一种材料制成并具有改进的机械和耐候性能的新型复合材料。

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