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1. 发明公开

EP0564644A1 METHOD FOR THE PRODUCTION OF H 2?O 2? USING FULLERENES 失效
标题翻译：工艺生产氢富勒烯的使用。
公开(公告)号：EP0564644A1
公开(公告)日：1993-10-13
申请号：EP92924120.0
申请日：1992-10-26
申请人： VASILEVSKIS, Janis
发明人： VASILEVSKIS, Janis
IPC分类号： C01B , B01J21 , B01J23 , C01B15 , C01B31
CPC分类号： B82Y30/00 , B82Y40/00 , C01B15/024 , C01B15/029 , C01B32/15 , C01B32/152
摘要： La présente invention décrit un procédé pour la production de H2O2 à l'aide de fullerène. Ledit procédé consiste à hydrogéner les fullerènes et à faire réagir les fullerènes hydrogénés avec O2 pour produire H2O2. Le procédé utilise de préférence un mélange de réaction à deux phases, constitué d'un solvant et d'eau. Le solvant solvate les fullerènes et tout catalyseur d'hydrogénation applicable. Le H2O2 passe dans la phase aqueuse pour être extrait du processus.

2. 发明申请

WO1993009060A1 METHOD FOR THE PRODUCTION OF H2O2 USING FULLERENES 审中-公开
标题翻译：使用FULLERENES生产H2O2的方法
公开(公告)号：WO1993009060A1
公开(公告)日：1993-05-13
申请号：PCT/US1992009052
申请日：1992-10-26
申请人： VASILEVSKIS, Janis
IPC分类号： C01B15/024
CPC分类号： B82Y30/00 , B82Y40/00 , C01B15/024 , C01B15/029 , C01B32/15 , C01B32/152
摘要： This invention is a process for the production of H2O2 using fullerene. The process involves the hydrogenation of the fullerenes and the reaction of the hydrogenated fullerenes with O2 to produce H2O2. Preferably the process utilizes a two-phase reaction mixture of a solvent and water. The solvent solvates the fullerenes and any applicable hydrogenation catalyst. The H2O2 is extracted into the water phase for removal from the process.
摘要翻译：本发明是使用富勒烯生产H 2 O 2的方法。该方法包括富勒烯的氢化和氢化富勒烯与O 2的反应产生H 2 O 2。优选地，该方法利用溶剂和水的两相反应混合物。溶剂溶剂化富勒烯和任何适用的氢化催化剂。将H 2 O 2萃取到水相中以从该方法中除去。

3. 发明公开

EP0564644A4 EP0564644A4 - 失效
标题翻译： EP0564644A4 - Google专利
公开(公告)号：EP0564644A4
公开(公告)日：1994-03-30
申请号：EP92924120
申请日：1992-10-26
申请人： VASILEVSKIS, JANIS
发明人： VASILEVSKIS, JANIS
IPC分类号： B01J21/18 , B01J23/40 , C01B20060101 , C01B15/022 , C01B15/024 , C01B15/029 , C01B31/02
CPC分类号： B82Y30/00 , B82Y40/00 , C01B15/024 , C01B15/029 , C01B32/15 , C01B32/152
摘要： This invention is a process for the production of H2O2 using fullerene. The process involves the hydrogenation of the fullerenes and the reaction of the hydrogenated fullerenes with O2 to produce H2O2. Preferably the process utilizes a two-phase reaction mixture of a solvent and water. The solvent solvates the fullerenes and any applicable hydrogenation catalyst. The H2O2 is extracted into the water phase for removal from the process.
摘要翻译：本发明是使用富勒烯生产H 2 O 2的方法。该方法涉及富勒烯的氢化和氢化富勒烯与O 2的反应以产生H 2 O 2。优选该方法使用溶剂和水的两相反应混合物。溶剂溶解了富勒烯和任何适用的氢化催化剂。 H 2 O 2被萃取到水相中以从该过程中除去。

4. 发明专利

AU3055492A METHOD FOR THE PRODUCTION OF H2O2 USING FULLERENES 未知
公开(公告)号：AU3055492A
公开(公告)日：1993-06-07
申请号：AU3055492
申请日：1992-10-26
申请人： VASILEVSKIS JANIS
发明人： JANIS VASILEVSKIS
IPC分类号： B01J21/18 , B01J23/40 , C01B20060101 , C01B15/022 , C01B15/024 , C01B15/029 , C01B31/02
摘要： This invention is a process for the production of H2O2 using fullerene. The process involves the hydrogenation of the fullerenes and the reaction of the hydrogenated fullerenes with O2 to produce H2O2. Preferably the process utilizes a two-phase reaction mixture of a solvent and water. The solvent solvates the fullerenes and any applicable hydrogenation catalyst. The H2O2 is extracted into the water phase for removal from the process.

5. 发明申请

WO9628420A3 PREPARATION OF N-ARYLMETHYL AZIRIDINE DERIVATIVES,PREPARATION OF N-ARYLMETHYL AZIRIDINE DERIVATIVES, 1,4,7,10-TETRAAZACYCLODODECANE DERIVATIVES OBTAIN 1,4,7,10-TETRAAZACYCLODODECANE DERIVATIVES OBTAINED THEREFROM AND N-ARYLMETHYL-ETHANOL-AMINE SULPHOED THEREFROM AND N-ARYLMETHYL-ETHANOL-AMINE SULPHONATE ESTERS AS INTERMEDIATES NATE ESTERS AS INTERMEDIATES 审中-公开
标题翻译：制备N-甲基甲基咪唑衍生物，制备N-芳基甲基咪唑衍生物，1,4,7,10-四氮杂十二烷基衍生物，得到由其获得的1,4,7,10-四氮杂环十二烷基衍生物和由其形成的N-芳基甲基 - 乙醇胺作为中间体的N-亚磺酰基 - 乙醇 - 氨基磺酸盐作为中间体
公开(公告)号：WO9628420A3
公开(公告)日：1996-12-12
申请号：PCT/GB9600552
申请日：1996-03-08
申请人： NYCOMED SALUTAR INC , UNIV IOWA RES FOUND , COCKBAIN JULIAN , MESSERLE LOUIS , AMARASINGHE GANDARA , FELLMANN JERE DOUGLAS , GARRITY MARTHA , VARADARAJAN JOHN , VASILEVSKIS JANIS
发明人： MESSERLE LOUIS , AMARASINGHE GANDARA , FELLMANN JERE DOUGLAS , GARRITY MARTHA , VARADARAJAN JOHN , VASILEVSKIS JANIS
IPC分类号： A61K49/00 , A61K49/06 , C07C303/44 , C07C305/06 , C07D203/08 , C07D255/00 , C07D257/02 , C07D259/00 , C07C305/04
CPC分类号： C07D203/08 , A61K49/0002 , A61K49/06 , C07C303/44 , C07D255/00 , C07D257/02 , C07D259/00 , C07C305/06
摘要： Aziridines may be subjected to a cyclooligomerization reaction to produce polyazacycloalkane compounds useful for example in the preparation of chelating agents for use in diagnostic imaging contrast agents. N-benzyl-aziridine in particular is useful as it can be cyclotetramerized and debenzylated to yield cyclen, a key intermediate in chelating agent preparation. The invention provides a particularly attractive route to production of N-benzyl and other N-arylmethyl aziridines of formula (I), (where each R1 independently is hydrogen or a group Ar and Ar is an optionally substituted phenyl group), said process comprising reacting a purified N-arylmethylethanolamine-sulphonate ester with a base. N-arylmethyl-ethanolamine sulphonate ester of the formula: R'NHCH2CH2OSO3H, wherein the N-arylmethyl group R' is an N-(bisarylmethyl) or N-(triarylmethyl) group, as intermediates. In a further aspect the invention provides compounds of formula (II), where Ar and R1 are as hereinbefore defined and at least two differing ArCHR1 moieties are present.
摘要翻译：氮杂环丁烷可以被喷射到环烯化反应中以产生用于例如制备用于诊断成像造影剂的螯合剂的多氮杂环烷烃化合物。特别是N-苄基 - 氮丙啶是有用的，因为它可以进行环化聚合和脱苄基化，以产生螯合剂，螯合剂制备中的关键中间体。本发明提供了生产式（I）的N-苄基和其它N-芳基甲基氮丙啶的特别有吸引力的途径，其中每个R 1独立地为氢或基团AR，Ar为任选取代的苯基。该方法包括使纯化的N-芳基甲基乙醇胺 - 磺酸酯磺酸酯与碱反应。作为中间体，式R'NHCH2CH2OSO3H的N-芳基甲基 - 乙醇胺磺酸酯，其中N-芳基甲基R'是N-（二芳基甲基）或N-（三芳基甲基）基团。在另一方面，本发明提供式（II）的化合物，其中Ar和R 1如上所定义，并且存在至少两个不同的ArCHR 21部分。

6. 发明申请

WO1996028432A1 PROCESS FOR TETRAAZACYCLOALKANE PREPARATION 审中-公开
标题翻译：四氯化碳制剂的制备方法
公开(公告)号：WO1996028432A1
公开(公告)日：1996-09-19
申请号：PCT/GB1996000462
申请日：1996-03-01
申请人： NYCOMED IMAGING A/S , COCKBAIN, Julian , SANDNES, Rolf, Wiggo , VASILEVSKIS, Janis , UNDHEIM, Kjell , GACEK, Michel
发明人： NYCOMED IMAGING A/S , COCKBAIN, Julian
IPC分类号： C07D257/02
CPC分类号： C07D257/02
摘要： The present invention provides a synthetic route for tetraazacycloalkane preparation which facilitates heteropoly-N-alkylation of the macrocyclic product, and is thereby beneficial for the production of chelating agents and chelates useful in diagnostic imaging. The process involves (i) reacting a tetraazaalkane with a bridging agent to couple for amine nitrogens of said tetraazaalkane to a bridging moiety to yield a fused tricyclic intermediate, (ii) reacting said intermediate to introduce an alkylene bridge between the secondary amine nitrogens in the outer rings of the fused tricyclic intermediate, optionally be decoupling an alkanediylidene bridging moiety from the tertiary amine nitrogens at the ring fusion sites of the fused tricyclic intermediate, and (iii) where necessary, decoupling said bridging moiety to yield a macrocyclic tetraazacycloalkane.
摘要翻译：本发明提供了促进大环杂多杂-N-烷基化的四氮杂环烷烃制备的合成路线，从而有利于制备可用于诊断成像的螯合剂和螯合物。该方法包括（i）使四氮杂链烷烃与桥连剂反应以将所述四氮杂烷的胺氮偶联至桥连部分以产生稠合的三环中间体，（ii）使所述中间体在仲胺氮中引入亚烷基桥，稠合三环中间体的外环任选地在稠合三环中间体的环融合位点处将烷二亚烷基桥连部分与叔胺氮键分离，和（iii）必要时将所述桥连部分解偶联以产生大环四氮杂环烷烃。

7. 发明申请

WO1996028420A2 PREPARATION OF N-ARYLMETHYL AZIRIDINE DERIVATIVES, 1,4,7,10-TETRAAZACYCLODODECANE DERIVATIVES OBTAINED THEREFROM AND N-ARYLMETHYL-ETHANOL-AMINE SULPHONATE ESTERS AS INTERMEDIATES 审中-公开
标题翻译： N-芳基甲基咪唑衍生物的制备，其中获得的1,4,7,10-四氮杂环十二烷基衍生物和作为中间体的N-亚磺酰基 - 乙磺酰胺磺酸盐
公开(公告)号：WO1996028420A2
公开(公告)日：1996-09-19
申请号：PCT/GB1996000552
申请日：1996-03-08
申请人： NYCOMED SALUTAR, INC. , UNIVERSITY OF IOWA RESEARCH FOUNDATION , COCKBAIN, Julian , MESSERLE, Louis , AMARASINGHE, Gandara , FELLMANN, Jere, Douglas , GARRITY, Martha , VARADARAJAN, John , VASILEVSKIS, Janis
发明人： NYCOMED SALUTAR, INC. , UNIVERSITY OF IOWA RESEARCH FOUNDATION , COCKBAIN, Julian
IPC分类号： C07D203/08
CPC分类号： C07D203/08 , A61K49/0002 , A61K49/06 , C07C303/44 , C07D255/00 , C07D257/02 , C07D259/00 , C07C305/06
摘要： Aziridines may be subjected to a cyclooligomerization reaction to produce polyazacycloalkane compounds useful for example in the preparation of chelating agents for use in diagnostic imaging contrast agents. N-benzyl-aziridine in particular is useful as it can be cyclotetramerized and debenzylated to yield cyclen, a key intermediate in chelating agent preparation. The invention provides a particularly attractive route to production of N-benzyl and other N-arylmethyl aziridines of formula (I), (where each R1 independently is hydrogen or a group Ar and Ar is an optionally substituted phenyl group), said process comprising reacting a purified N-arylmethylethanolamine-sulphonate ester with a base. N-arylmethyl-ethanolamine sulphonate ester of the formula: R'NHCH2CH2OSO3H, wherein the N-arylmethyl group R' is an N-(bisarylmethyl) or N-(triarylmethyl) group, as intermediates. In a further aspect the invention provides compounds of formula (II), where Ar and R1 are as hereinbefore defined and at least two differing ArCHR1 moieties are present.
摘要翻译：氮丙啶可以进行环烯基化反应以产生用于例如制备用于诊断成像造影剂的螯合剂的多氮杂环烷烃化合物。特别是N-苄基 - 氮丙啶是有用的，因为它可以进行环化聚合和脱苄基化，以产生螯合剂，螯合剂制备中的关键中间体。本发明提供了生产式（I）的N-苄基和其它N-芳基甲基氮丙啶的特别有吸引力的途径（其中每个R 1独立地为氢或基团Ar，Ar为任选取代的苯基），所述方法包括使纯化的N-芳基甲基乙醇胺 - 磺酸酯与碱。具有下式的N-芳基甲基 - 乙醇胺磺酸酯：R'NHCH2CH2OSO3H，其中N-芳基甲基R'为N-（二芳基甲基）或N-（三芳基甲基）基团，为中间体。在另一方面，本发明提供式（II）化合物，其中Ar和R 1如上所定义，并且存在至少两个不同的ArCHR 1部分。

8. 发明专利

NO932330L 未知
公开(公告)号：NO932330L
公开(公告)日：1993-08-12
申请号：NO932330
申请日：1993-06-24
申请人： VASILEVSKIS JANIS
发明人： VASILEVSKIS JANIS
IPC分类号： B01J21/18 , B01J23/40 , C01B20060101 , C01B15/022 , C01B15/024 , C01B15/029 , C01B31/02
摘要： This invention is a process for the production of H2O2 using fullerene. The process involves the hydrogenation of the fullerenes and the reaction of the hydrogenated fullerenes with O2 to produce H2O2. Preferably the process utilizes a two-phase reaction mixture of a solvent and water. The solvent solvates the fullerenes and any applicable hydrogenation catalyst. The H2O2 is extracted into the water phase for removal from the process.

9. 发明专利

FI932982A 未知
公开(公告)号：FI932982A
公开(公告)日：1993-08-16
申请号：FI932982
申请日：1993-06-28
申请人： VASILEVSKIS JANIS
发明人： VASILEVSKIS JANIS
IPC分类号： B01J21/18 , B01J23/40 , C01B20060101 , C01B15/022 , C01B15/024 , C01B15/029 , C01B31/02
摘要： This invention is a process for the production of H2O2 using fullerene. The process involves the hydrogenation of the fullerenes and the reaction of the hydrogenated fullerenes with O2 to produce H2O2. Preferably the process utilizes a two-phase reaction mixture of a solvent and water. The solvent solvates the fullerenes and any applicable hydrogenation catalyst. The H2O2 is extracted into the water phase for removal from the process.

10. 发明专利

NO932330A 未知
公开(公告)号：NO932330A
公开(公告)日：1993-08-12
申请号：NO932330
申请日：1993-06-24
申请人： VASILEVSKIS JANIS
发明人： VASILEVSKIS JANIS
IPC分类号： B01J21/18 , B01J23/40 , C01B20060101 , C01B15/022 , C01B15/024 , C01B15/029 , C01B31/02
CPC分类号： B82Y30/00 , B82Y40/00 , C01B15/024 , C01B15/029 , C01B32/15 , C01B32/152

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