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1. 发明申请

WO2008040750A1 A PROCESS FOR TREATING ELEMENTAL SULPHUR FOR SMELL IMPROVEMENT 审中-公开
标题翻译：一种处理元素硫以进行小型改进的方法
公开(公告)号：WO2008040750A1
公开(公告)日：2008-04-10
申请号：PCT/EP2007/060490
申请日：2007-10-03
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , MESTERS, Carolus Matthias Anna Maria , SCHOONEBEEK, Ronald Jan , VAN TRIER, Rob Aloysius Maria , VERBIST, Guy Lode Magda Maria
发明人： MESTERS, Carolus Matthias Anna Maria , SCHOONEBEEK, Ronald Jan , VAN TRIER, Rob Aloysius Maria , VERBIST, Guy Lode Magda Maria
IPC分类号： C01B17/02 , C04B28/36
CPC分类号： C04B28/36 , C01B17/0232 , C01B17/0243 , C01B17/905
摘要： A process for treating a stream of elemental sulphur comprising an organic polysulphide and/or a thiol for smell improvement, the process comprising the following steps: (a) providing a molten stream of elemental sulphur comprising an organic polysulphide and/or a thiol at a temperature in the range of from 120 to 160 °C; (b) admixing a liquid unsaturated compound with the stream of molten elemental sulphur in an amount in the range of from 0.01 to 10.0 wt% based on the weight of sulphur to allow the organic polysulphide and/or thiol to react with the unsaturated compound.
摘要翻译：一种用于处理包含有机多硫化物和/或硫醇以改善气味的元素硫流的方法，所述方法包括以下步骤：（a）提供包含有机多硫化物和/或硫醇的元素硫的熔融流，温度范围为120〜160℃; （b）将液体不饱和化合物与熔融元素硫流混合，其量为基于硫重量的0.01至10.0重量％，以使有机多硫化物和/或硫醇与不饱和化合物反应。

2. 发明申请

WO2006134130A1 MODIFIED SULPHUR AND PRODUCT COMPRISING MODIFIED SULPHUR AS BINDER 审中-公开
标题翻译：改性硫和包含改性硫磺的产品作为粘合剂
公开(公告)号：WO2006134130A1
公开(公告)日：2006-12-21
申请号：PCT/EP2006/063220
申请日：2006-06-14
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , REYNHOUT, Marinus Johannes , VAN TRIER, Rob Aloysius Maria , VERBIST, Guy Lode Magda Maria
发明人： REYNHOUT, Marinus Johannes , VAN TRIER, Rob Aloysius Maria , VERBIST, Guy Lode Magda Maria
IPC分类号： C04B28/36 , C04B24/00
CPC分类号： C04B28/36 , C04B2111/20 , C04B14/06 , C04B24/00 , C04B40/0263
摘要： The invention provides modified sulphur prepared by admixing molten elemental sulphur with one or more olefinic sulphur modifiers, wherein at least 50 wt% of the olefinic sulphur modifiers is 5-ethylidene-2-norbornene and/or 5-vinyl-2-norbornene and wherein the total amount of olefinic sulphur modifiers is in the range of from 0.1 to 20 wt% based on the weight of sulphur. The invention further provides a product comprising such modified sulphur as binder which is prepared by admixing such modified sulphur, a filler and/or aggregate, and optionally elemental sulphur at a temperature above the melting temperature of sulphur and solidifying the mixture obtained by cooling the mixture to a temperature below the melting temperature of sulphur.
摘要翻译：本发明提供通过将熔融元素硫与一种或多种烯烃硫改性剂混合制备的改性硫，其中至少50wt％的烯烃硫改性剂是5-亚乙基-2-降冰片烯和/或5-乙烯基-2-降冰片烯，其中烯烃硫改性剂的总量基于硫的重量计在0.1至20重量％的范围内。本发明还提供了包含这种改性硫作为粘合剂的产品，其通过在高于硫的熔融温度的温度下混合这种改性硫，填料和/或骨料以及任选的元素硫而制备，并固化通过冷却混合物获得的混合物达到低于硫的熔融温度的温度。

3. 发明申请

WO2009150193A1 SULPHUR CEMENT PRE-COMPOSITION AND PROCESS FOR PREPARING SUCH SULPHUR CEMENT PRE-COMPOSITION 审中-公开
标题翻译：硫磺水泥前体组合物和制备这种硫酸钙组合物的方法
公开(公告)号：WO2009150193A1
公开(公告)日：2009-12-17
申请号：PCT/EP2009/057221
申请日：2009-06-10
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , LANKSHEAR, Michael David , VAN TRIER, Rob Aloysius Maria , VERBIST, Guy Lode Magda Maria
发明人： LANKSHEAR, Michael David , VAN TRIER, Rob Aloysius Maria , VERBIST, Guy Lode Magda Maria
IPC分类号： C04B28/36
CPC分类号： C04B24/40 , C04B28/36
摘要： The present invention provides a sulphur cement pre- composition, comprising sulphur and at least an organotitanate, which organotitanate is of the general molecular formula (1) or (2) : wherein OR 1 , OR 2 and OR 3 are independently chosen from acyloxy, phosphato, pyrophosphate, sulfonato and glycoxy; and XO and X'O are independently chosen from alkoxy or neoalkoxy group or XO and X'O together form a glycoxy group. The invention further provides a process for preparing such sulphur cement pre-composition, processes for the preparation of a sulphur cement product, a sulphur cement product and the use of such sulphur cement pre-composition. The invention even further relates to the use of an organotitanate stabilizing agent.
摘要翻译：本发明提供一种含硫和至少有机钛酸盐的硫磺水泥预组合物，有机钛酸盐具有通式（1）或（2）：其中OR 1，OR 2和OR 3独立地选自酰氧基，磷酸根，焦磷酸盐，磺化和糖醇; XO和X'O独立地选自烷氧基或新烷氧基，或XO和X'O一起形成糖氧基。本发明还提供了制备这种硫磺水泥预处理剂的方法，硫磺水泥产品的制备方法，硫磺水泥产品以及这种硫磺水泥预组合物的用途。本发明还涉及有机钛酸盐稳定剂的用途。

4. 发明申请

WO2008152054A1 SULPHUR CEMENT PRE-COMPOSITION AND PROCESS FOR PREPARING SUCH SULPHUR CEMENT PRE-COMPOSITION 审中-公开
标题翻译：硫磺水泥前体组合物和制备这种硫酸钙组合物的方法
公开(公告)号：WO2008152054A1
公开(公告)日：2008-12-18
申请号：PCT/EP2008/057277
申请日：2008-06-11
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VERBIST, Guy Lode Magda Maria , VAN TRIER, Rob Aloysius Maria , LANKSHEAR, Michael David
发明人： VERBIST, Guy Lode Magda Maria , VAN TRIER, Rob Aloysius Maria , LANKSHEAR, Michael David
IPC分类号： C04B24/40 , C04B28/36
CPC分类号： C04B28/36 , C04B24/405 , C04B40/0039 , C04B12/00
摘要： The present invention provides a sulphur cement pre- composition, comprising sulphur and at least an organotitanate, which organotitanate is of the general molecular formula (1): wherein R 1 is C n H (2n) - S a R 4 or C m H (2m+1) and n is an integer in the range of from 1 to 4, m is an integer in the range or form 1 to 30 and a is an integer in the range of from 2 to 8, R4 is S, H, or C p H( 2p+1) and p is an integer in the range of from 1 to 8, XO is an alkoxy or neoalkoxy group, R 2 and R 3 are, independently, a C n H (2n) - S a R 4 , alkyl, neoalkyl, acyl or aryl group. The invention further provides a process for preparing such sulphur cement pre-composition, processes for the preparation of a sulphur cement product, a sulphur cement product and the use of such sulphur cement pre-composition. The invention even further relates to the use of an organotitanate stabilizing agent.
摘要翻译：本发明提供一种含硫和至少一种有机钛酸盐的硫磺水泥预组合物，有机钛酸盐具有通式（1）：其中R1是CnH（2n） - _{SaR4或CmH（2m + 1 ），n为1〜4的整数，m为1〜30的整数，a为2〜8的整数，R4为S，H或CpH（ 2p + 1），p为1〜8的整数，XO为烷氧基或新烷氧基，R2和R3独立地为CnH（2n）-SaR4，烷基，新烷基，酰基或芳基。本发明还提供了制备这种硫磺水泥预处理剂的方法，硫磺水泥产品的制备方法，硫磺水泥产品以及这种硫磺水泥预组合物的用途。本发明还涉及有机钛酸盐稳定剂的用途。}

5. 发明申请

WO2007065920A2 PROCESS FOR THE PREPARATION OF SULPHUR CEMENT OR A SULPHUR CEMENT-AGGREGATE COMPOSITE 审中-公开
标题翻译：制备硫酸钙或硫酸钙复合材料的方法
公开(公告)号：WO2007065920A2
公开(公告)日：2007-06-14
申请号：PCT/EP2006/069404
申请日：2006-12-07
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VERBIST, Guy Lode Magda Maria , VAN TRIER, Rob Aloysius Maria
发明人： VERBIST, Guy Lode Magda Maria , VAN TRIER, Rob Aloysius Maria
IPC分类号： C04B28/36 , C01B17/04
CPC分类号： C04B28/365 , C04B12/00 , C04B28/36 , C04B14/06 , C04B24/42
摘要： The present invention provides a process for the preparation of sulphur cement or a sulphur cement-aggregate composite comprising the following steps: (a) admixing at least an inorganic filler and/or aggregate and a polysulphide-containing organosilane having at least two organosilyl groups and allowing the organosilane to react with the inorganic filler and/or aggregate; (b) admixing during or after step (a) elemental sulphur with the inorganic filler and/or aggregate at a temperature at which sulphur is liquid to obtain an admixture comprising molten sulphur and inorganic filler and/or aggregate; and (c) solidifying the admixture to obtain sulphur cement or a sulphur cement-aggregate composite. The invention further provides sulphur cement or a sulphur cement-aggregate composite obtainable by such process and the use of a polysulphide-containing organosilane having at least two organosilyl groups as coupling agent in sulphur cement or a sulphur cement-aggregate composite.
摘要翻译：本发明提供一种制备硫磺水泥或硫磺水泥 - 骨料复合材料的方法，包括以下步骤：（a）至少混合至少一种无机填料和/或骨料和含有至少两个有机甲硅烷基的多硫化物的有机硅烷，使有机硅烷与无机填料和/或骨料反应; （b）步骤（a）期间或之后将硫元素与无机填料和/或骨料在硫气的温度下混合，得到包含熔融硫和无机填料和/或骨料的混合物; 和（c）固化混合物以获得硫磺水泥或硫磺水泥骨料复合材料。本发明还提供了可通过这种方法获得的硫磺水泥或硫磺水泥 - 骨料复合材料，并且使用具有至少两个有机甲硅烷基作为硫磺水泥或硫磺水泥骨料复合材料中的偶联剂的多硫化物的有机硅烷。

6. 发明申请

WO2007065920A3 PROCESS FOR THE PREPARATION OF SULPHUR CEMENT OR A SULPHUR CEMENT-AGGREGATE COMPOSITE 审中-公开
标题翻译：制备硫化水泥或硫化水泥 - 骨料复合材料的方法
公开(公告)号：WO2007065920A3
公开(公告)日：2007-09-20
申请号：PCT/EP2006069404
申请日：2006-12-07
申请人： SHELL INT RESEARCH , VERBIST GUY LODE MAGDA MARIA , VAN TRIER ROB ALOYSIUS MARIA
发明人： VERBIST GUY LODE MAGDA MARIA , VAN TRIER ROB ALOYSIUS MARIA
IPC分类号： C04B28/36
CPC分类号： C04B28/365 , C04B12/00 , C04B28/36 , C04B14/06 , C04B24/42
摘要： The present invention provides a process for the preparation of sulphur cement or a sulphur cement-aggregate composite comprising the following steps: (a) admixing at least an inorganic filler and/or aggregate and a polysulphide-containing organosilane having at least two organosilyl groups and allowing the organosilane to react with the inorganic filler and/or aggregate; (b) admixing during or after step (a) elemental sulphur with the inorganic filler and/or aggregate at a temperature at which sulphur is liquid to obtain an admixture comprising molten sulphur and inorganic filler and/or aggregate; and (c) solidifying the admixture to obtain sulphur cement or a sulphur cement-aggregate composite. The invention further provides sulphur cement or a sulphur cement-aggregate composite obtainable by such process and the use of a polysulphide-containing organosilane having at least two organosilyl groups as coupling agent in sulphur cement or a sulphur cement-aggregate composite.
摘要翻译：本发明提供了制备硫磺水泥或硫磺水泥 - 骨料复合物的方法，其包括以下步骤：（a）将至少一种无机填料和/或聚集体与具有至少两个有机甲硅烷基的含多硫化物的有机硅烷混合，使有机硅烷与无机填料和/或聚集体反应; （b）在步骤（a）期间或之后，将元素硫与无机填料和/或聚集体在硫为液体的温度下混合以获得包含熔融硫和无机填料和/或聚集体的混合物; 和（c）固化该混合物以获得硫磺水泥或硫磺水泥 - 骨料复合材料。本发明进一步提供了通过该方法可获得的硫磺水泥或硫磺水泥 - 骨料复合材料以及在硫磺水泥或硫磺水泥 - 骨料复合材料中使用具有至少两个有机甲硅烷基团的作为偶联剂的含多硫化物的有机硅烷。

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