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    • 2. 发明授权
    • Curable polyorganosiloxane composition
    • 可固化的聚有机硅氧烷组合物
    • US4921926A
    • 1990-05-01
    • US271985
    • 1988-11-16
    • Tsuneo MotegiYasuji MatsumotoKiyoshi TakedaShuji Chiba
    • Tsuneo MotegiYasuji MatsumotoKiyoshi TakedaShuji Chiba
    • C08K5/14C08L83/04C08L83/06C08L83/07
    • C08L83/04C08G77/16C08G77/18C08G77/20
    • A curable polyorganosiloxane composition is disclosed, comprising: (A) 100 parts by weight of polyorganosiloxane having at least two hydroxyl groups or hydrolyzable groups bonded to a silicon atom in the molecule thereof and having a viscosity at 25.degree. C. of 10 to 1,000,000 cSt, (B) 0 to 2,000 parts by weight of polyorganosiloxane having at least two alkenyl groups bonded to a silicon atom in the molecule thereof and having a viscosity at 25.degree. C. of 10 to 1,000,000 cSt, (C) 0.5 to 20 parts by weight of an organosilicon compound having more than 2 (on the average) hydrolyzable groups bonded to a silicon atom in the molecule thereof, (D) 0 to 10 parts by weight of a catalyst for a condensation reaction, and (E) 0.1 to 5 parts by weight of an organic peroxide, wherein at least 0.01 mol % of all organic groups bonded to a silicon atom as contained in (A) to (C) is an alkenyl group. The composition has both condensation reaction curability and ultraviolet ray curability.
    • 公开了一种可固化聚有机硅氧烷组合物,其包含:(A)100重量份具有至少两个羟基的聚有机硅氧烷或与其分子中的硅原子键合的可水解基团,并且在25℃下的粘度为10至1,000,000cSt ,(B)0〜2,000重量份具有至少两个与分子中的硅原子键合的烯基的聚有机硅氧烷,其在25℃下的粘度为10〜1,000,000cSt,(C)为0.5〜20份, (D)0〜10重量份用于缩合反应的催化剂的(E)0.1〜5(重量)的有机硅化合物, (A)〜(C)中所含的与硅原子键合的全部有机基团的至少0.01摩尔%为烯基的有机过氧化物。 该组合物具有缩合反应固化性和紫外线固化性。
    • 3. 发明授权
    • Primer composition
    • 底漆组成
    • US4721750A
    • 1988-01-26
    • US25538
    • 1987-03-13
    • Nobuo NakamuraTsuneo MotegiYasuji Matsumoto
    • Nobuo NakamuraTsuneo MotegiYasuji Matsumoto
    • C09D143/04C08K5/10C08F8/42C08F130/08C08F230/08
    • C09D143/04
    • A primer composition comprising:(A) 100 parts by weight of copolymer obtained by reacting(1) an acrylic compound represented by the following general formula: ##STR1## wherein R.sup.1 and R.sup.2 respectively represent groups selected from the group consisting of a hydrogen atom and monovalent substituted or non-substituted hydrocarbon group; with(2) a silane compound represented by the following formula: ##STR2## wherein R.sup.3 represents a group selected from the group consisting of a hydrogen atom and monovalent substituted or non-substituted hydrocarbon groups, R.sup.4 represents a monovalent substituted or non-substituted hydrocarbon group, and Q.sup.1 represents a divalent hydrocarbon group having 1 to 6 carbon atoms, in the weight ratio of 0.1 to 1,000 wt % with respect to the component (1), in the presence of a free-radical initiator;(B) 0.1 to 500 parts by weight of at least one compound selected from the group consisting of titanium alkoxides, titanium chelate compounds, aluminum alkoxides, aluminum chelate compounds, and iron salts of organic acids;(C) 0.1 to 500 parts by weight of organo silicon compound having at least one unsaturated carbon, attached to a silicon atom, in a molecule;(D) a platinum, palladium, or rhodium catalyst in an amount of 0.1 to 10,000 ppm in terms of each element of the platinum, palladium and rhodium with respect to the component (A); and(E) an organic solvent in an amount of 250 to 3,500 parts by weight with respect to the total amount of (A) through (D) converted into 100 parts by weight.
    • 一种底漆组合物,其包含:(A)100重量份通过使(1)由以下通式表示的丙烯酸化合物:其中R1和R2分别表示选自氢原子和 一价取代或未取代的烃基; (2)由下式表示的硅烷化合物:其中R 3表示选自氢原子和一价取代或未取代的烃基的基团,R 4表示一价取代或未取代的烃 在自由基引发剂的存在下,Q1表示碳原子数为1〜6的2价烃基,重量比为0.1〜1000重量%,相对于成分(1) (B)0.1〜500重量份的选自钛醇盐,钛螯合物,铝醇盐,铝螯合物和有机酸的铁中的至少一种化合物; (C)0.1〜500重量份在分子中具有至少一个与硅原子连接的不饱和碳的有机硅化合物; (D)相对于组分(A)的铂,钯和铑的每种元素的量为0.1至10,000ppm的铂,钯或铑催化剂; 和(E)相对于(A)〜(D)的总量转化成100重量份的有机溶剂的量为250〜3,500重量份。