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    • 3. 发明授权
    • Production of (Mo,W) C hexagonal carbide
    • (Mo,W)C六方晶碳化物的生产
    • US4454105A
    • 1984-06-12
    • US432630
    • 1982-10-05
    • Tsuguyasu WadaEvan K. Ohriner
    • Tsuguyasu WadaEvan K. Ohriner
    • C01B32/949C01B31/34
    • C01B31/34C01P2002/54C01P2006/80
    • Solid solutions of molybdenum and tungsten having molybdenum to tungsten atom ratios between about 1:1 and about 10:1 are produced by heating a mechanically milled mixture of a molybdenum oxide and tungsten oxide to a temperature between about 1000.degree. C. and about 1300.degree. C. at a rate of at least about 20.degree. C. per minute in a hydrogen-containing atmosphere and holding at temperature to reduce the oxides of molybdenum and tungsten and to provide a homogeneous solid solution of molybdenum and tungsten. The homogeneous solid solution is mixed with a stoichiometric excess of carbon and heated to a temperature between about 1200.degree. C. and about 1800.degree. C. under a protective atmosphere to react the carbon with the alloy powder to form a solid solution of hexagonal monocarbides.
    • 通过将氧化钼和氧化钨的机械研磨的混合物加热至约1000℃至约1300℃的温度,制得钼与钨原子之比约为1:1至10:1的钼和钨的固溶体。 C.在含氢气氛中以至少约20℃/分钟的速率保持并保持在温度以降低钼和钨的氧化物并提供均匀的钼和钨的固溶体。 将均匀的固体溶液与化学计量过量的碳混合并在保护气氛下加热至约1200℃至约1800℃的温度,以使碳与合金粉末反应以形成六方晶体单体的固溶体。