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1. 发明申请

US20090044723A1 Carbon-Containing Refractory, Production Method Thereof, and Pitch-Containing Refractory Raw Material 失效
$Carbon-Containing Refractory, Production Method Thereof, and Pitch-Containing Refractory Raw Material$
标题翻译：含碳耐火材料，其生产方法和含沥青的耐火原料
公开(公告)号：US20090044723A1
公开(公告)日：2009-02-19
申请号：US11989199
申请日：2006-07-21
申请人： Toshiyuki Hokii , Hiroyuki Fuchimoto , Toshihiro Suruga , Jyouki Yoshitomi , Keisuke Asano
发明人： Toshiyuki Hokii , Hiroyuki Fuchimoto , Toshihiro Suruga , Jyouki Yoshitomi , Keisuke Asano
IPC分类号： C08L95/00
CPC分类号： C04B35/043 , C04B35/013 , C04B35/103 , C04B35/6269 , C04B35/62839 , C04B35/634 , C04B2235/3821 , C04B2235/401 , C04B2235/402 , C04B2235/425 , C04B2235/428 , C04B2235/5436 , C04B2235/96 , C04B2235/9669 , C04B2235/9676
摘要： A configuration in which particles of pitch 2 having a softening point in the range of 70 to 200° C. and a diameter equal to or smaller than 30 μm are held on the surfaces of particles of a refractory raw material 3 having a diameter equal to or smaller than 50 μm is employed. This pitch-containing refractory raw material 1 can be used with the pitch being in a fine-particle form without any aggregation even after the long-term storage. Using it as a part of a raw material formulation allows the fine particles of pitch to be uniformly dispersed during the mixing or kneading process. The resulting carbon-containing refractory has an excellent corrosion resistance. It also provides suppressed increase in the Young's modulus while maintaining the level of strength, thereby being excellent in thermal spalling resistance even with the carbon content ratio being low.
摘要翻译：具有软化点在70〜200℃，直径等于或小于30μm的沥青2的颗粒被保持在直径相等的耐火材料3的颗粒表面上或小于50um。即使在长期保存后，也可以使用这种含沥青的耐火材料1，其间距为微细颗粒形式，而不会聚集。使用它作为原料配方的一部分，可以在混合或捏合过程中使沥青的细颗粒均匀分散。所得到的含碳耐火材料具有优异的耐腐蚀性。同时，在保持强度的同时，还可以抑制杨氏模量的增加，即使碳含量比低，耐散热性优异。

2. 发明授权

US08093169B2 High-durability sleeve bricks 有权
标题翻译：高耐久性套砖
公开(公告)号：US08093169B2
公开(公告)日：2012-01-10
申请号：US12513729
申请日：2007-11-06
申请人： Masato Tanaka , Eiichiro Hatae , Toshiyuki Hokii , Joki Yoshitomi
发明人： Masato Tanaka , Eiichiro Hatae , Toshiyuki Hokii , Joki Yoshitomi
IPC分类号： C04B35/043
CPC分类号： C04B35/043 , B22F2003/248 , B22F2998/10 , C04B35/013 , C04B35/0435 , C04B35/62665 , C04B35/63496 , C04B2235/3206 , C04B2235/3217 , C04B2235/3222 , C04B2235/3244 , C04B2235/3418 , C04B2235/3804 , C04B2235/3808 , C04B2235/3813 , C04B2235/3821 , C04B2235/3826 , C04B2235/401 , C04B2235/402 , C04B2235/404 , C04B2235/421 , C04B2235/422 , C04B2235/424 , C04B2235/425 , C04B2235/428 , C04B2235/48 , C04B2235/5292 , C04B2235/5427 , C04B2235/5436 , C04B2235/5472 , C04B2235/77 , C04B2235/94 , C04B2235/95 , C04B2235/96 , C21C5/4653 , C22C29/12 , F27D1/0006 , C22C1/05 , B22F1/0059 , B22F3/04 , B22F3/24
摘要： Disclosed is a magnesia-carbon based sleeve brick for steelmaking converters, which is obtained by adding, to a refractory raw material mix containing 60 to 95 mass % of a magnesia raw material and 5 to 20 mass % of graphite, a metal powder of one or more selected from the group consisting of Al, Si, Mg, Ca, Cr and an alloy thereof, in an amount of greater than 3 to 6 mass %, and an organic binder, in addition to 100 mass % of the refractory raw material mix, and subjecting the resulting mixture to kneading, forming and heat treatment, wherein the sleeve brick is used under a condition that a thickness thereof is set at 70 mm or less. This makes it possible to prevent cracking which would otherwise occur in the sleeve brick itself, to allow the sleeve brick to have enhanced durability. One or more selected from the group consisting of B, B4C, MgB2, CaB6, and CrB may be further added in an amount of 0.1 to 3 mass %, in addition to 100 mass % of the refractory raw material mix, to enhance strength and oxidation resistance and further enhance the durability. The magnesia raw material may comprise a first particle fraction having a particle diameter of greater than 10 to 500 μm and occupying 20 to 50 mass % in the refractory raw material mix, and a second particle fraction having a particle diameter of 10 μm or less and occupying 5 mass % or less in the refractory raw material mix, to additionally enhance corrosion resistance and thermal shock resistance.
摘要翻译：公开了一种用于炼钢转炉的氧化镁 - 碳基套筒砖，其通过在含有60〜95质量％的氧化镁原料和5〜20质量％的石墨的耐火材料混合物中添加一种金属粉末或更多选自Al，Si，Mg，Ca，Cr及其合金，其含量大于3〜6质量％，除了100质量％的耐火材料之外，还包含有机粘合剂混合并对所得混合物进行捏合，成形和热处理，其中在其厚度设定为70mm以下的条件下使用套筒砖。这使得可以防止否则将在套筒砖本身中发生的开裂，以允许套筒砖具有增强的耐用性。除了100质量％的耐火材料混合物之外，还可以以0.1〜3质量％的量添加从B，B4C，MgB2，CaB6和CrB组成的组中选择的一种以上，以提高强度，抗氧化性，进一步提高耐久性。氧化镁原料可以包含在耐火原料混合物中粒径大于10〜500μm，占20〜50质量％的第一粒子级分，粒径为10μm以下的第二粒子级分，在耐火原料混合物中占5质量％以下，另外提高耐腐蚀性和耐热冲击性。

3. 发明申请

US20090075808A1 Refractory, Method for Manufacturing Refractory, and Refractory Raw Material 有权
$Refractory, Method for Manufacturing Refractory, and Refractory Raw Material$
标题翻译：耐火材料，耐火材料制造方法和耐火材料
公开(公告)号：US20090075808A1
公开(公告)日：2009-03-19
申请号：US11887744
申请日：2006-04-19
申请人： Katsumi Morikawa , Koichi Haren , Joki Yoshitomi , Toshiyuki Hokii , Keisuke Asano
发明人： Katsumi Morikawa , Koichi Haren , Joki Yoshitomi , Toshiyuki Hokii , Keisuke Asano
IPC分类号： C04B35/52
CPC分类号： C04B35/013 , B82Y30/00 , C04B35/103 , C04B35/63 , C04B35/66 , C04B2235/3217 , C04B2235/3241 , C04B2235/3244 , C04B2235/3272 , C04B2235/3275 , C04B2235/3289 , C04B2235/402 , C04B2235/404 , C04B2235/405 , C04B2235/424 , C04B2235/425 , C04B2235/428 , C04B2235/441 , C04B2235/444 , C04B2235/48 , C04B2235/5248 , C04B2235/5288 , C04B2235/5436 , C04B2235/5445 , C04B2235/96 , C04B2235/9607 , C04B2235/9669
摘要： A carbon-containing refractory is provided, which can improve the thermal shock resistance, the abrasion resistance, and the corrosion resistance without degrading the oxidation resistance.In a carbon-containing refractory composed of a refractory aggregate, a carbon based raw material, and a carbon bond connecting between the refractory aggregate or the carbon based raw material, transition metal-containing nanoparticles having particle diameters of 1,000 nm or less and containing a transition metal are contained in the above-described carbon bond while being dispersed. When the carbon-containing refractory is heat-treated, flexible structures of carbon fiber-shaped textures having diameters of 50 nm or less are formed in the inside of a carbon bond and, thereby, an increase in strength, a reduction in modulus of elasticity, and a reduction in thermal expansion coefficient are facilitated. Therefore, a carbon-containing refractory exhibiting high thermal shock resistance, high abrasion resistance, and high corrosion resistance are provided.
摘要翻译：提供含碳耐火材料，其可以在不降低抗氧化性的情况下提高耐热冲击性，耐磨性和耐腐蚀性。在由耐火骨料，碳基原料和连接耐火骨料或碳基原料的碳键构成的含碳耐火材料中，含有粒径为1000nm以下的含过渡金属的纳米粒子，过渡金属分散在上述碳键中。当对含碳耐火材料进行热处理时，在碳质内部形成直径为50nm以下的碳纤维状织构的柔性结构，强度提高，弹性模量降低，并且促进了热膨胀系数的降低。因此，提供了具有高耐热冲击性，高耐磨性和高耐腐蚀性的含碳耐火材料。

4. 发明授权

US08182599B2 Carbon-containing refractory, production method thereof, and pitch-containing refractory raw material 失效
$Carbon-containing refractory, production method thereof, and pitch-containing refractory raw material$
标题翻译：含碳耐火材料，其制造方法和含沥青的耐火材料
公开(公告)号：US08182599B2
公开(公告)日：2012-05-22
申请号：US11989199
申请日：2006-07-21
申请人： Toshiyuki Hokii , Hiroyuki Fuchimoto , Toshihiro Suruga , Jyouki Yoshitomi , Keisuke Asano
发明人： Toshiyuki Hokii , Hiroyuki Fuchimoto , Toshihiro Suruga , Jyouki Yoshitomi , Keisuke Asano
IPC分类号： C08L95/00 , B29C59/00
CPC分类号： C04B35/043 , C04B35/013 , C04B35/103 , C04B35/6269 , C04B35/62839 , C04B35/634 , C04B2235/3821 , C04B2235/401 , C04B2235/402 , C04B2235/425 , C04B2235/428 , C04B2235/5436 , C04B2235/96 , C04B2235/9669 , C04B2235/9676
摘要： A configuration in which particles of pitch 2 having a softening point in the range of 70 to 200° C. and a diameter equal to or smaller than 30 μm are held on the surfaces of particles of a refractory raw material 3 having a diameter equal to or smaller than 50 μm is employed. This pitch-containing refractory raw material 1 can be used with the pitch being in a fine-particle form without any aggregation even after the long-term storage. Using it as a part of a raw material formulation allows the fine particles of pitch to be uniformly dispersed during the mixing or kneading process. The resulting carbon-containing refractory has an excellent corrosion resistance. It also provides suppressed increase in the Young's modulus while maintaining the level of strength, thereby being excellent in thermal spalling resistance even with the carbon content ratio being low.
摘要翻译：具有软化点在70〜200℃，直径等于或小于30μm的沥青2的颗粒被保持在直径相等的耐火材料3的颗粒表面上或小于50μm。即使在长期保存后，也可以使用这种含沥青的耐火材料1，其间距为微细颗粒形式，而不会聚集。使用它作为原料配方的一部分，可以在混合或捏合过程中使沥青的细颗粒均匀分散。所得到的含碳耐火材料具有优异的耐腐蚀性。同时，在保持强度的同时，还可以抑制杨氏模量的增加，即使碳含量比低，耐散热性优异。

5. 发明授权

US08450228B2 Refractory, method for manufacturing refractory, and refractory raw material 有权
$Refractory, method for manufacturing refractory, and refractory raw material$
标题翻译：耐火材料，耐火材料制造方法和耐火原料
公开(公告)号：US08450228B2
公开(公告)日：2013-05-28
申请号：US11887744
申请日：2006-04-19
申请人： Katsumi Morikawa , Koichi Haren , Joki Yoshitomi , Toshiyuki Hokii , Keisuke Asano
发明人： Katsumi Morikawa , Koichi Haren , Joki Yoshitomi , Toshiyuki Hokii , Keisuke Asano
IPC分类号： C04B35/80 , C04B35/81 , C04B35/52
CPC分类号： C04B35/013 , B82Y30/00 , C04B35/103 , C04B35/63 , C04B35/66 , C04B2235/3217 , C04B2235/3241 , C04B2235/3244 , C04B2235/3272 , C04B2235/3275 , C04B2235/3289 , C04B2235/402 , C04B2235/404 , C04B2235/405 , C04B2235/424 , C04B2235/425 , C04B2235/428 , C04B2235/441 , C04B2235/444 , C04B2235/48 , C04B2235/5248 , C04B2235/5288 , C04B2235/5436 , C04B2235/5445 , C04B2235/96 , C04B2235/9607 , C04B2235/9669
摘要： In a carbon-containing refractory composed of a refractory aggregate, a carbon based raw material, and a carbon bond connecting between the refractory aggregate or the carbon based raw material, transition metal-containing nanoparticles having particle diameters of 1,000 nm or less and containing a transition metal are contained in the above-described carbon bond while being dispersed. When the carbon-containing refractory is heat-treated, flexible structures of carbon fiber-shaped textures having diameters of 50 nm or less are formed in the inside of a carbon bond and, thereby, an increase in strength, a reduction in modulus of elasticity, and a reduction in thermal expansion coefficient are facilitated. Therefore, a carbon-containing refractory exhibiting high thermal shock resistance, high abrasion resistance, and high corrosion resistance are provided.
摘要翻译：在由耐火骨料，碳基原料和连接耐火骨料或碳基原料的碳键构成的含碳耐火材料中，含有粒径为1000nm以下的含过渡金属的纳米粒子，过渡金属分散在上述碳键中。当对含碳耐火材料进行热处理时，在碳质内部形成直径为50nm以下的碳纤维状织构的柔性结构，强度提高，弹性模量降低，并且促进了热膨胀系数的降低。因此，提供了具有高耐热冲击性，高耐磨性和高耐腐蚀性的含碳耐火材料。

6. 发明申请

US20050200057A1 Nozzle for continuous casting of aluminum killed steel and continuous casting method 审中-公开
标题翻译：用于铝连铸铝喷枪和连铸法
公开(公告)号：US20050200057A1
公开(公告)日：2005-09-15
申请号：US10513186
申请日：2003-04-30
申请人： Koji Ogata , Koichi Shimizu , Keisuke Asano , Toshiyuki Hokii , Joki Yoshitomi
发明人： Koji Ogata , Koichi Shimizu , Keisuke Asano , Toshiyuki Hokii , Joki Yoshitomi
IPC分类号： B22D11/10 , B22D11/00 , B22D41/50 , B22D41/54 , C04B35/03 , C21B7/14
CPC分类号： B22D41/54
摘要： The present invention provides a technique of applying a CaO-containing material to a nozzle unit for casting of aluminum-killed steel, in such a manner that the amount of large-size alumina inclusions in slabs can be reduced irrespective of nozzle type, such as single-part type or multi-part type. The amount of large-size alumina inclusions in slabs obtained using a single-part type or multi-part type nozzle unit, which has an inner hole to be used for pouring molten steel from a tundish to a mold therethrough and CaO-containing refractories applied to a surface of the inner hole, has a strong correlation with the entire surface area of the inner hole of the nozzle unit and the amount of CaO contained in the employed refractories. According to the present invention, 50% or more of the entire surface area of the inner hole of the nozzle unit is formed of refractories containing 20 mass % or more of CaO to allow the amount of large-size alumina inclusions to be reduced.
摘要翻译：本发明提供了一种将含CaO材料施加到用于铸造铝镇静钢的喷嘴单元的技术，其方法是可以减少板坯中的大尺寸氧化铝夹杂物的数量，而不管喷嘴类型如单件式或多件式。使用单件式或多型式喷嘴单元获得的大型氧化铝夹杂物的量，其具有用于将钢水从中间包浇铸到模具中的内孔和用于其的含CaO耐火材料与内孔的表面具有与喷嘴单元的内孔的整个表面积和所使用的耐火材料中含有的CaO的量的强相关性。根据本发明，喷嘴单元的内孔的整个表面积的50％以上由含有20质量％以上的CaO的耐火材料形成，能够减少大尺寸的氧化铝夹杂物的量。

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