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1. 发明授权

US08456066B2 Piezoelectric / electrostrictive material, piezoelectric / electrostrictive ceramic composition, piezoelectric / electrostrictive element, and piezoelectric motor 有权
标题翻译：压电/电致伸缩材料，压电/电致伸缩陶瓷组合物，压电/电致伸缩元件和压电电机
公开(公告)号：US08456066B2
公开(公告)日：2013-06-04
申请号：US12792860
申请日：2010-06-03
申请人： Toshikatsu Kashiwaya , Yuya Kikuta , Tomohiko Hibino
发明人： Toshikatsu Kashiwaya , Yuya Kikuta , Tomohiko Hibino
IPC分类号： H01L41/187
CPC分类号： C04B35/493 , C04B35/62685 , C04B2235/3251 , C04B2235/3258 , C04B2235/3262 , C04B2235/3281 , C04B2235/3294 , C04B2235/36 , C04B2235/6025 , C04B2235/768 , C04B2235/79 , H01L41/083 , H01L41/0913 , H01L41/1876 , H01L41/273
摘要： There is provided a piezoelectric/electrostrictive element having little decease of Qm even in a high electric field in the case of a piezoelectric element. The piezoelectric/electrostrictive body is characterized in that the rate of Qm in an electric field of 10 V/mm is 30% or more with respect to Qm in an electric field of 1 V/mm.
摘要翻译：在压电元件的情况下，即使在高电场中也提供了几乎不具有Qm的Qm的压电/电致伸缩元件。压电/电致伸缩体的特征在于，在10V / mm的电场中，Qm相对于1m / mm的电场中的Qm为30％以上。

2. 发明授权

US07477004B2 Piezoelectric/electrostrictive porcelain composition, piezoelectric/electrostrictive article, and piezoelectric/electrostrictive film type element 有权
标题翻译：压电/电致伸缩瓷组合物，压电/电致伸缩制品和压电/电致伸缩薄膜型元件
公开(公告)号：US07477004B2
公开(公告)日：2009-01-13
申请号：US11232787
申请日：2005-09-22
申请人： Tsutomu Nanataki , Hirofumi Yamaguchi , Toshikatsu Kashiwaya
发明人： Tsutomu Nanataki , Hirofumi Yamaguchi , Toshikatsu Kashiwaya
IPC分类号： H01L41/187
CPC分类号： C04B35/495 , B41J2/14233 , B41J2202/03 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3215 , C04B2235/3224 , C04B2235/3229 , C04B2235/3236 , C04B2235/3239 , C04B2235/3251 , C04B2235/3255 , C04B2235/326 , C04B2235/3279 , C04B2235/3291 , C04B2235/3294 , H01L41/0973 , H01L41/187 , H01L41/1873
摘要： A piezoelectric/electrostrictive porcelain composition which exhibits superior piezoelectric/electrostrictive characteristics without containing lead (Pb) is provided. A main component of the piezoelectric/electrostrictive composition is a binary solid solution represented by the general formula (1): (1−n)(Ag1−a−b−cLiaNabKc)(Nb1−x−y−zTaxSbyVz)O3+nM1M2O3; wherein 0≦a≦0.2, 0≦b≦0.95, 0≦c≦0.95, 0
摘要翻译：提供了不含铅（Pb）的优异的压电/电致伸缩特性的压电/电致伸缩瓷组合物。压电/电致伸缩组合物的主要成分是由通式（1）表示的二元固溶体：（1-n）（Ag1-a-b-cLiaNabKc）（Nb1-x-y-zTaxSbyVz）O3 + nM1M2O3; 其中0 <= a <= 0.2,0 <= b <= 0.95,0 <= c <= 0.95,0 <（1-ab -c）<=1,0,0≤x≤0.5,0≤y <= 0.2,0 <= z <= 0.2,0 <=（y + z）<= 0.3,0 <= n <= 0.2，其中M1和M2是满足先决条件的金属的组合。

3. 发明申请

US20060158068A1 Piezoelectric device 审中-公开
标题翻译：压电元件
公开(公告)号：US20060158068A1
公开(公告)日：2006-07-20
申请号：US11327859
申请日：2006-01-09
申请人： Hideki Shimizu , Takashi Ebigase , Mutsumi Kitagawa , Toshikatsu Kashiwaya
发明人： Hideki Shimizu , Takashi Ebigase , Mutsumi Kitagawa , Toshikatsu Kashiwaya
IPC分类号： H01L41/187
CPC分类号： C04B35/493 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3227 , C04B2235/3251 , C04B2235/3279 , C04B2235/768 , C04B2235/77 , C04B2235/786 , H01L41/0805 , H01L41/0973 , H01L41/1875
摘要： There is disclosed a piezoelectric device which has a remarkably high piezoelectric characteristic and which is superior in a vibration transmitting property between a substrate and a piezoelectric portion and in which linearity of a flexural displacement with respect to a voltage is high up to a high voltage region and which exhibits a high durability even in a case where the device is used with a large flexural displacement for a long period. The piezoelectric device is provided with: a substrate 2 made of a ceramic; a piezoelectric portion 1 constituted of a piezoelectric porcelain composition containing as a major component a Pb(Mg, Ni)1/3Nb2/3O3—PbZrO3—PbTiO3 ternary solid solution system composition represented by a predetermined formula; and an electrode 3 electrically connected to the piezoelectric portion 1, and the piezoelectric portion 1 is solidly attached onto the substrate 2 directly or via the electrode 3.
摘要翻译：公开了一种具有非常高的压电特性的压电器件，其在衬底和压电部件之间的振动传递性能优异，并且其中相对于电压的弯曲位移的线性度高达高电压区域并且即使在长期使用具有大的弯曲位移的装置的情况下也显示出高的耐久性。压电装置设置有：由陶瓷制成的基板2; 由作为主成分的Pb（Mg，Ni）1/3 Nb 3/3/3 O 3的压电陶瓷组合物构成的压电体1，由预定公式表示的三元固体溶液体系组合物; 以及电连接到压电部分1的电极3，并且压电部分1直接或经由电极3牢固地附接到基板2上。

4. 发明授权

US5668071A Piezoelectric porcelain 失效
标题翻译：压电瓷
公开(公告)号：US5668071A
公开(公告)日：1997-09-16
申请号：US604712
申请日：1996-02-21
申请人： Toshikatsu Kashiwaya , Hirofumi Yamaguchi , Tadashi Otagiri
发明人： Toshikatsu Kashiwaya , Hirofumi Yamaguchi , Tadashi Otagiri
IPC分类号： C04B35/493 , H01L41/187 , C04B35/472 , C04B35/499
CPC分类号： C04B35/493 , H01L41/187
摘要： The present invention includes the following three types of piezoelectric porcelains. (1) In a piezoelectric porcelain having a composition of aPb[Mg.sub.1-X Ni.sub.X).sub.1/3 (Nb.sub.1-Y Ta.sub.Y).sub.2/3 ]O.sub.3 -bPbTiO.sub.3 -cPbZrO.sub.3, the coefficients a, b and c (mol %) and the substitution rate X satisfy all the following conditions; 15.ltoreq.a.ltoreq.45, 32.ltoreq.b.ltoreq.45, 10.ltoreq.c.ltoreq.50 and 0.1.ltoreq.X.ltoreq.0.9. (2) In a piezoelectric porcelain having a composition of aPb[Mg.sub.1-X Ni.sub.X).sub.1/3 (Nb.sub.1-Y Ta.sub.Y).sub.2/3 ]O.sub.3 -bPbTiO.sub.3 -cPbZrO.sub.3, the coefficients a, b and c (mol %) and the substitution rates X and Y satisfy all the following conditions; 15.ltoreq.a.ltoreq.45, 32.ltoreq.b.ltoreq.45, 10.ltoreq.c.ltoreq.50, 0.1.ltoreq.X.ltoreq.0.9, 0.1.ltoreq.Y.ltoreq.0.9 and Y-X.gtoreq.0.05. (3) In a piezoelectric porcelain having a composition of aPb[Mg.sub.1-X Ni.sub.X).sub.1/3 (Nb.sub.1-Y Ta.sub.Y).sub.2/3 ]O.sub.3 -bPbTiO.sub.3 -cPbZrO.sub.3, the coefficients a, b and c (mol %) and the substitution rates X and Y satisfy all the following conditions; 15.ltoreq.a.ltoreq.45, 32.ltoreq.b.ltoreq.45, 10.ltoreq.c.ltoreq.50, 0.2.ltoreq.X.ltoreq.0.9, 0.2.ltoreq.Y.ltoreq.0.9 and X-Y.gtoreq.0.05.
摘要翻译：本发明包括以下三种类型的压电陶瓷。（1）在具有组成为Pb [Mg1-XNiX] + E，fra1 / 3 + EE（Nb1-YTaY）+ E，fra2 / 3 + EE] O3-bPbTiO3-cPbZrO3的压电陶瓷中，系数a ，b和c（mol％），取代率X满足以下所有条件; 15 = = 0.05。（3）在具有Pb [Mg1-XNiX] + E，fra1 / 3 + EE（Nb1-YTaY）+ E，fra2 / 3 + EE] O3-bPbTiO3-cPbZrO3组成的压电陶瓷中，系数a ，b和c（mol％），取代率X和Y满足以下所有条件; 15 / = 0.05。

5. 发明授权

US08080923B2 Piezoelectric/electrostrictive membrane element 有权
标题翻译：压电/电致伸缩膜元件
公开(公告)号：US08080923B2
公开(公告)日：2011-12-20
申请号：US12316079
申请日：2008-12-09
申请人： Takaaki Koizumi , Toshikatsu Kashiwaya
发明人： Takaaki Koizumi , Toshikatsu Kashiwaya
IPC分类号： H01L41/187
CPC分类号： C04B35/493 , C04B35/6262 , C04B2235/3206 , C04B2235/3251 , C04B2235/3279 , C04B2235/5445 , C04B2235/6562 , C04B2235/6565 , C04B2235/75 , C04B2235/76 , C04B2235/761 , C04B2235/762 , C04B2235/765 , C04B2235/768 , H01L41/0973 , H01L41/1876 , H01L41/314 , H01L41/43
摘要： A piezoelectric/electrostrictive membrane element is provided, including a ceramic substrate, a membranous piezoelectric/electrostrictive portion including a piezoelectric/electrostrictive body made of a large number of crystal particles having a lead zirconate titanate based piezoelectric/electrostrictive ceramic composition, and membranous electrodes electrically connected to the piezoelectric/electrostrictive portion. The crystal particles include crystal main body portions, and surface layer portions arranged in at least a part of the outer periphery of crystal main body portions and having a crystal structure which is different from that of the crystal main body portions. The piezoelectric/electrostrictive portion is bonded in a solid state to the substrate directly or via electrodes.
摘要翻译：提供一种压电/电致伸缩膜元件，包括陶瓷基板，膜压电/电致伸缩部分，其包括由具有锆钛酸铅基压电/电致伸缩陶瓷组合物的大量晶体颗粒制成的压电/电致伸缩体，以及电极连接到压电/电致伸缩部分。晶体颗粒包括晶体主体部分和布置在晶体主体部分的外周的至少一部分上并具有与晶体主体部分不同的晶体结构的表面层部分。压电/电致伸缩部分以固态直接或通过电极接合到衬底上。

6. 发明授权

US07901729B2 Method of manufacturing a piezoelectric/electrostrictive device 有权
标题翻译：制造压电/电致伸缩器件的方法
公开(公告)号：US07901729B2
公开(公告)日：2011-03-08
申请号：US12047501
申请日：2008-03-13
申请人： Tsutomu Nanataki , Hirofumi Yamaguchi , Toshikatsu Kashiwaya , Yuya Kikuta
发明人： Tsutomu Nanataki , Hirofumi Yamaguchi , Toshikatsu Kashiwaya , Yuya Kikuta
IPC分类号： B05D5/12 , H01L41/22
CPC分类号： C04B35/493 , C01G23/003 , C01G25/006 , C01P2006/10 , C01P2006/40 , C04B35/62675 , C04B35/62805 , C04B2235/3206 , C04B2235/3213 , C04B2235/3215 , C04B2235/3227 , C04B2235/3229 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3267 , C04B2235/3279 , C04B2235/3287 , C04B2235/3298 , C04B2235/3418 , C04B2235/5445 , C04B2235/656 , C04B2235/768 , C04B2235/77 , H01L41/0805 , H01L41/083 , H01L41/0973 , H01L41/1875 , H01L41/43 , Y10T29/42
摘要： There is disclosed a piezoelectric/electrostrictive porcelain composition capable of manufacturing, at a comparatively low sintering temperature, a piezoelectric/electrostrictive body which is dense and superior in crystallinity and which has satisfactory piezoelectric/electrostrictive characteristics so that deviation of the composition is not easily generated. The piezoelectric/electrostrictive porcelain composition contains as a major component a piezoelectric/electrostrictive porcelain composition component including a PbMg1/3Nb2/3O3—PbZrO3—PbTiO3 ternary solid solution system composition and NiO or including a Pb(Mg, Ni)1/3Nb2/3O3—PbZrO3—PbTiO3 ternary solid solution system composition, and further contains lead germanate.
摘要翻译：公开了一种压电/电致伸缩瓷组合物，其能够在比较低的烧结温度下制造致密且结晶性优异并且具有令人满意的压电/电致伸缩特性的压电/电致伸缩体，因此不容易产生组成的偏差。压电/电致伸缩瓷组合物包含作为主要成分的包括PbMg1 / 3Nb2 / 3O3-PbZrO3-PbTiO3三元固溶体系组成的压电/电致伸缩瓷组合物组分和NiO或包含Pb（Mg，Ni）1 / 3Nb2 / 3O3 -PbZrO3-PbTiO3三元固溶体系组成，并含有锗酸铅。

7. 发明授权

US07737611B2 Piezoelectric/electrostrictive ceramics and piezoelectric/electrostrictive device 失效
标题翻译：压电/电致伸缩陶瓷和压电/电致伸缩器件
公开(公告)号：US07737611B2
公开(公告)日：2010-06-15
申请号：US12492409
申请日：2009-06-26
申请人： Toshikatsu Kashiwaya , Takashi Ebigase
发明人： Toshikatsu Kashiwaya , Takashi Ebigase
IPC分类号： H01L41/187
CPC分类号： H01L41/1875 , C04B35/493 , C04B2235/3217 , C04B2235/3255 , C04B2235/3279 , H01L41/081 , H01L41/083 , H01L41/0973 , H01L41/273
摘要： The piezoelectric/electrostrictive properties and mechanical durability of a piezoelectric/electrostrictive ceramic can be improved. A piezoelectric/electrostrictive device has a laminated structure in which an electrode film, a piezoelectric/electrostrictive film, an electrode film, an piezoelectric/electrostrictive film, and an electrode film are laminated in the order mentioned on a thin portion of a substrate. The piezoelectric/electrostrictive films are ceramic films with a matrix of perovskite oxide that contains lead (Pb) as an A-site component and nickel (Ni), aluminum (Al), niobium (Nb), zirconium (Zr), and titanium (Ti) as B-site components. The piezoelectric/electrostrictive films are formed by firing as a unit the substrate that contains aluminum oxide and an intermediate coating film of perovskite oxide that contains components other than aluminum so that aluminum oxide is diffused from the substrate to the intermediate coating film.
摘要翻译：可以提高压电/电致伸缩陶瓷的压电/电致伸缩性能和机械耐久性。压电/电致伸缩器件具有层压结构，其中电极膜，压电/电致伸缩膜，电极膜，压电/电致伸缩膜和电极膜以按照衬底薄部分的顺序层压。压电/电致伸缩膜是具有钙钛矿氧化物基质的陶瓷膜，其包含铅（Pb）作为A位组分，镍（Ni），铝（Al），铌（Nb），锆（Zr）和钛（ Ti）作为B位组分。压电/电致伸缩膜通过以包含氧化铝的基板和包含除了铝以外的成分的钙钛矿氧化物的中间涂层作为单元进行烧结而形成，使得氧化铝从基板扩散到中间涂膜。

8. 发明授权

US07484278B2 Method of manufacturing a multi-layered piezoelectric 失效
标题翻译：制造多层压电陶瓷的方法
公开(公告)号：US07484278B2
公开(公告)日：2009-02-03
申请号：US11033785
申请日：2005-01-12
申请人： Toshikatsu Kashiwaya , Mutsumi Kitagawa
发明人： Toshikatsu Kashiwaya , Mutsumi Kitagawa
IPC分类号： H01L41/22 , H01L41/00
CPC分类号： H01L41/0805 , H01L41/0831 , H01L41/0973 , H01L41/1875 , Y10T29/42 , Y10T29/435 , Y10T29/49128 , Y10T29/4913 , Y10T29/49131 , Y10T29/49151
摘要： A multi-layered piezoelectric device includes a plurality of piezoelectric portions and a plurality of electrodes electrically connected to the piezoelectric portions that are formed in layers on a ceramic substrate. A first piezoelectric portion is made of a piezoelectric ceramic composition containing Ni in an amount of 0.08 to 0.31% by mass (in terms of NiO), and second and upper piezoelectric portions are made of a piezoelectric ceramic composition of higher Ni content than in the first piezoelectric portion. An electrode is provided at least between the first piezoelectric portion and the second piezoelectric portion.
摘要翻译：多层压电装置包括多个压电部分和与陶瓷基板上的层压形成的压电部分电连接的多个电极。第一压电部分由含有0.08-0.31质量％（以NiO计）的Ni的压电陶瓷组合物制成，第二和上压电部分由Ni含量高的压电陶瓷组合物制成第一压电部。至少在第一压电部分和第二压电部分之间提供电极。

9. 发明授权

US07176155B2 Piezoelectric/electrostrictive ceramic composition, piezoelectric/electrosrictive material, and piezoelectric/electrostrictive film device 失效
标题翻译：压电/电致伸缩陶瓷组合物，压电/电绝缘材料和压电/电致伸缩膜装置
公开(公告)号：US07176155B2
公开(公告)日：2007-02-13
申请号：US11001952
申请日：2004-12-02
申请人： Toshikatsu Kashiwaya , Hideki Shimizu , Takashi Ebigase
发明人： Toshikatsu Kashiwaya , Hideki Shimizu , Takashi Ebigase
IPC分类号： H01L41/04 , C04B35/493
CPC分类号： C01G33/006 , C01P2002/52 , C01P2002/54 , C01P2006/40 , C04B35/493 , C04B35/499 , C04B2235/3206 , C04B2235/3234 , C04B2235/3249 , C04B2235/3255 , C04B2235/3279 , C04B2235/3418 , C04B2235/77 , C04B2235/785 , C04B2235/786 , C04B2235/79 , H01L41/0973 , H01L41/098 , H01L41/1875
摘要： A piezoelectric/electrostrictive ceramic composition containing, as a major component, a Pb(Mg1/3Nb2/3)O3—PbTiO3—PbZrO3 ternary solid solution system composition and further containing Ni in an amount of 0.05 to 3.0% by mass in terms of NiO and Si in an amount of 0.003 to 0.01% by mass in terms of SiO2. The piezoelectric/electrostrictive ceramic composition can constitute a piezoelectric/electrostrictive body or a piezoelectric/electrostrictive portion both having an excellent piezoelectric/electrostrictive property and durability even under high-temperature and highly humid conditions.
摘要翻译：一种压电/电致伸缩陶瓷组合物，其包含作为主要成分的Pb（Mg 1/3 N 2 Nb 3/3）O 3 -PbTiO 三元固溶体系组合物，还含有以NiO和Si计为0.05-3.0质量％的量为0.003至0.01的Ni 质量％SiO 2。压电/电致伸缩陶瓷组合物可以构成即使在高温高湿条件下也具有优异的压电/电致伸缩性能和耐久性的压电/电致伸缩体或压电/电致伸缩部分。

10. 发明申请

US20060066176A1 Piezoelectric/electrostrictive film type device and method of manufacturing the same 有权
标题翻译：压电/电致伸缩薄膜型器件及其制造方法
公开(公告)号：US20060066176A1
公开(公告)日：2006-03-30
申请号：US11233391
申请日：2005-09-22
申请人： Tsutomu Nanataki , Hirofumi Yamaguchi , Toshikatsu Kashiwaya , Takaaki Koizumi
发明人： Tsutomu Nanataki , Hirofumi Yamaguchi , Toshikatsu Kashiwaya , Takaaki Koizumi
IPC分类号： H01L41/18
CPC分类号： C04B35/495 , C04B2235/3201 , C04B2235/3203 , C04B2235/3251 , C04B2235/3291 , C04B2235/3294 , C04B2235/656 , C04B2235/6567 , C04B2235/785 , C04B2235/786 , H01L41/0973 , H01L41/1873 , H01L41/314 , Y10T29/42
摘要： There is disclosed a piezoelectric/electrostrictive film type device 1 provided with: a thin substrate 2 made of a ceramic; and a piezoelectric/electrostrictive operating portion 5 disposed on the substrate 2 and constituted by successively laminating a lower electrode film 3a, a piezoelectric/electrostrictive film 4 containing a large number of crystal particles constituted of a piezoelectric/electrostrictive composition, and an upper electrode film 3b. The piezoelectric/electrostrictive composition contains one or more alkali metal elements selected from the group consisting of lithium (Li), potassium (K), and sodium (Na), and one or more metal elements selected from the group consisting of niobium (Nb), tantalum (Ta), antimony (Sb), and silver (Ag) (however, surely containing niobium (Nb), and circle equivalent diameters of 90% or more of the large number of crystal particles are in a range of 0.3 to 50 μm. It is possible to exhibit a superior piezoelectric/electrostrictive characteristic without containing lead (Pb) and obtain an especially large displacement.
摘要翻译：公开了一种压电/电致伸缩膜型器件1，其设置有：由陶瓷制成的薄基片2; 以及压电/电致伸缩操作部分5，其设置在基板2上，并且通过连续地层叠下电极膜3a，包含大量由压电/电致伸缩组合物构成的晶体颗粒和上电极的压电/电致伸缩膜4 电影3 b。压电/电致伸缩组合物含有一种或多种选自锂（Li），钾（K）和钠（Na）的碱金属元素，以及一种或多种选自铌（Nb），钽（Ta），锑（Sb）和银（Ag）（然而，确实含有铌（Nb），圆当量直径为90％以上的大量结晶粒子的范围为0.3〜50 可以显示出优异的压电/电致伸缩特性，而不含铅（Pb），并获得特别大的位移。

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