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    • 1. 发明申请
    • PROCESS OF HYDROCRACKING HEAVY OIL
    • 加氢重油工艺
    • US20080156693A1
    • 2008-07-03
    • US11964349
    • 2007-12-26
    • Toshiaki OKUIMasaaki TamuraKazuyuki EikawaWladmir Ferraz de Souza
    • Toshiaki OKUIMasaaki TamuraKazuyuki EikawaWladmir Ferraz de Souza
    • C10G47/02
    • C10G47/26C10G7/06C10G47/02
    • To provide a process of hydrocracking heavy oil capable of obtaining cracked light oil with higher yields and/or milder reaction conditions than the conventionally proposed hydrocracking process in a suspended bed method using an iron-based catalyst when hydrocracking heavy oil containing heavy metal components produced in a refining process of crude oil into lighter oil.There are provided (1) a process of hydrocracking heavy oil containing heavy metal components produced in a refining process of crude oil, comprising a vacuum distillation step to obtain the heavy oil as distillation residue by vacuum distillation; and a reaction step to hydrocrack the heavy oil in the presence of an iron-based catalyst in a suspended bed reactor, wherein the distillation is conducted at 350° C. or less in the vacuum distillation step, (2) in the preceding process, reaction conditions in the reaction step are a reaction pressure of 60-160 kg/cm2; a reaction temperature of 430-455° C.; and a reaction time of 30-180 minutes.
    • 提供一种加氢裂化重油的方法,其能够以比常规提出的加氢裂化方法更高的产率和/或更温和的反应条件获得裂解轻油,该方法在使用铁基催化剂的悬浮床方法中加氢裂化重质金属组分 将原油精炼成轻油。 提供(1)在原油精制过程中生成的含重金属成分的重油加氢裂化方法,包括真空蒸馏步骤,通过真空蒸馏得到重油作为蒸馏残渣; 以及在悬浮床反应器中在铁基催化剂存在下加氢裂解重油的反应步骤,其中在真空蒸馏步骤中,在350℃或更低温度下进行蒸馏,(2)在前述方法中, 反应步骤中的反应条件是反应压力为60-160kg / cm 2; 反应温度为430-455℃。 反应时间为30-180分钟。
    • 2. 发明授权
    • Method of liquefying brown coal
    • 液化褐煤的方法
    • US4565622A
    • 1986-01-21
    • US550122
    • 1983-11-09
    • Yukio NakakoTetsuo MatsumuraToshio OzawaKaizaburo SaitoShin-ichi KatsushimaShin-ichi OyaToshiaki OkuiYutaka MitoOsamu OkumaTomoji Takahashi
    • Yukio NakakoTetsuo MatsumuraToshio OzawaKaizaburo SaitoShin-ichi KatsushimaShin-ichi OyaToshiaki OkuiYutaka MitoOsamu OkumaTomoji Takahashi
    • C10G1/06C10G1/00C10G1/08
    • C10G1/002C10G1/083
    • A method for the liquefaction of brown coal which comprises effecting primary hydrogenation at a temperature and pressure sufficient to promote the efficient hydrogenation of a slurry prepared by adding an iron-based catalyst and a slurrying solvent to brown coal; distilling all or a portion of the primary hydrogenation product, whereby a naphtha fraction, a middle distillate oil fraction, a heavy distillate oil fraction and a distillation residue are produced; recycling a portion of said middle distillate oil, said heavy distillate oil fraction and said distillation residue to said primary hydrogenation step as the slurrying solvent; removing ash from the remaining portion of the distillation residue, thereby separating the same into an insoluble fraction containing ash, insoluble organic matter or a mixture thereof, and a soluble fraction as a solution in said solvent; and feeding said soluble fraction and said middle and heavy distillate fractions, to a fixed-bed column reactor packed with a molybdenum-based catalyst for secondary hydrogenation at a temperature and pressure sufficient to promote the efficient hydrogenation thereof; and separating the naphtha fraction from the secondary hydrogenation product and recycling all or a portion of the remainder to said primary hydrogenation step as the slurrying solvent therefor.
    • 一种用于液化褐煤的方法,其包括在足以促进通过向褐煤中加入铁基催化剂和浆化溶剂制备的浆料的有效氢化的温度和压力下进行初级氢化; 蒸馏全部或一部分初级氢化产物,由此制备石脑油馏分,中间馏分油馏分,重馏分油馏分和蒸馏残余物; 将所述中间馏分油,所述重馏分油馏分和所述蒸馏残余物的一部分循环到所述初级氢化步骤作为浆化溶剂; 从蒸馏残余物的剩余部分除去灰分,从而将其分离成含有灰分,不溶性有机物或其混合物的不溶性级分,以及作为所述溶剂中的溶液的可溶性级分; 并将所述可溶部分和所述中重馏分部分加入到填充有钼基催化剂的固定床反应器中,以在足以促进其有效氢化的温度和压力下进行二次氢化; 并将所述石脑油馏分与二次氢化产物分离,并将其余部分的全部或一部分循环到所述初级氢化步骤作为其制浆溶剂。