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1. 发明授权

US08734568B2 Asymmetric hollow fiber gas separation membrane 有权
标题翻译：不对称中空纤维气体分离膜
公开(公告)号：US08734568B2
公开(公告)日：2014-05-27
申请号：US13638087
申请日：2011-03-30
申请人： Hiroki Hisamori , Tatsuya Hayashi , Seiji Morihashi , Tomonori Kanougi
发明人： Hiroki Hisamori , Tatsuya Hayashi , Seiji Morihashi , Tomonori Kanougi
IPC分类号： B01D53/22
CPC分类号： C01B13/0255 , B01D53/228 , B01D69/02 , B01D69/08 , B01D71/64 , B01D2256/12 , B01D2257/102 , B01D2325/022
摘要： The present invention relates to an asymmetric hollow fiber membrane for gas separation made of a soluble aromatic polyimide, wherein an orientation index is 1.3 or less, a separation coefficient α(P′O2/P′N2) as a permeation rate ratio of oxygen gas/nitrogen gas at 40° C. is 5.3 or more, and a tensile fracture elongation is 15% or more.
摘要翻译：本发明涉及一种由可溶性芳族聚酰亚胺制成的气体分离用不对称中空纤维膜，其中取向指数为1.3以下，作为氧气的透过率的分离系数α（P'O2 / P'N2） /氮气在40℃时为5.3以上，拉伸断裂伸长率为15％以上。

2. 发明申请

US20110048229A1 SOLVENT-RESISTANT ASYMMETRIC HOLLOW FIBER GAS SEPARATION MEMBRANE, AND METHOD FOR PRODUCTION THEREOF 失效
标题翻译：耐溶剂不对称中空纤维气体分离膜及其生产方法
公开(公告)号：US20110048229A1
公开(公告)日：2011-03-03
申请号：US12863125
申请日：2009-01-19
申请人： Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Yoji Kase , Kenji Fukunaga
发明人： Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Yoji Kase , Kenji Fukunaga
IPC分类号： B01D53/22 , C08J9/00
CPC分类号： B01D69/08 , B01D53/228 , B01D71/40 , B01D71/80 , B01D2323/08 , B01D2325/24 , B01D2325/30 , C08G73/1039 , C08G73/1042 , C08G73/1064 , C08G73/1067 , D01F6/74
摘要： An asymmetric hollow fiber gas separation membrane obtained by subjecting an asymmetric hollow fiber polyimide membrane to a heat treatment having a maximum temperature of from 350 to 450° C., wherein the asymmetric hollow fiber polyimide membrane is formed with a polyimide essentially having a repeating unit represented by a general formula (1); is excellent in a solvent resistance and a thermal stability, and as well has such a mechanical strength that a tensile elongation at break is not less than 10% as a hollow fiber membrane. In the general formula (1), 20 to 80 mol % of A is a tetravalent unit based on a biphenyl structure represented by formula (2), 20 to 80 mol % of A is a tetravalent unit based on a diphenylhexafluoropropane structure represented by formula (3), and 0 to 30 mol % of A is a tetravalent unit based on a phenyl structure represented by formula (4); and in the general formula (1), 30 to 70 mol % of R is a divalent unit represented by formula (5) and/or formula (6), and 30 to 70 mol % of R is a divalent unit having one or two other aromatic rings than formula (5) or (6), wherein, R1 and R2 are a hydrogen atom or an organic group, and n is 0, 1 or 2, wherein, R1 and R2 are a hydrogen atom or an organic group, X is —CH2— or —CO—, and n is 0, 1 or 2.
摘要翻译：通过使不对称中空纤维聚酰亚胺膜进行350〜450℃的最高温度的热处理而得到的不对称中空纤维气体分离膜，其中，所述不对称中空纤维聚酰亚胺膜形成有基本上具有重复单元的聚酰亚胺由通式（1）表示; 耐溶剂性和热稳定性优异，作为中空纤维膜，具有拉伸断裂伸长率为10％以上的机械强度。在通式（1）中，A为20〜80摩尔％，为基于式（2）所示的联苯结构的四价单元，A为20〜80摩尔％，基于式（2）表示的二苯基六氟丙烷结构的四价单元（3）表示，0〜30摩尔％的A为基于式（4）表示的苯基结构的四价单元。在通式（1）中，R为作为式（5）和/或式（6）所示的二价单元的30〜70摩尔％，R为30〜70摩尔％，为1或2个（5）或（6）中的其它芳环，其中R1和R2是氢原子或有机基团，n是0,1或2，其中R1和R2是氢原子或有机基团， X是-CH 2 - 或-CO-，n是0,1或2。

3. 发明授权

US09248408B2 Hollow-fiber element for organic-vapor separation 有权
标题翻译：用于有机蒸气分离的中空纤维元件
公开(公告)号：US09248408B2
公开(公告)日：2016-02-02
申请号：US13262158
申请日：2010-03-31
申请人： Tomonori Kanougi , Yuma Irisa , Kenji Fukunaga
发明人： Tomonori Kanougi , Yuma Irisa , Kenji Fukunaga
IPC分类号： B01D63/02
CPC分类号： B01D63/02 , B01D63/022 , B01D63/023 , B01D2313/08
摘要： In a hollow fiber element constituting a separation membrane module for separating an organic vapor, at least one end part of a fiber bundle consisting of multiple hollow fiber membranes having a selective permeability is fixed and bound with a tube sheet formed by a cured material, in which an epoxy composition (A) has been cured by using a hardener (B). A glass transition temperature of said cured material is not less than 160° C., a minimum elongation at break thereof is not less than 7.0%, and an elution ratio thereof is less than 5%. For this reason, the hollow fiber element has enough endurance to retain a gas-tightness of an internal space of the hollow fiber membrane and an external space of the hollow fiber membrane even in use under organic vapor with an elevated temperature and high pressure.
摘要翻译：在构成用于分离有机蒸气的分离膜组件的中空纤维元件中，由具有选择性渗透性的多个中空纤维膜组成的纤维束的至少一个端部固定并与由固化材料形成的管板结合，其中环氧组合物（A）已经通过使用硬化剂（B）固化。所述固化材料的玻璃化转变温度不低于160℃，最小断裂伸长率不小于7.0％，洗脱比小于5％。因此，中空纤维元件具有足够的耐久性，即使在高温高压下在有机蒸气下使用也能够保持中空纤维膜的内部空间的气密性和中空纤维膜的外部空间。

4. 发明授权

US08388733B2 Hollow-fiber element for organic-vapor separation 失效
标题翻译：用于有机蒸气分离的中空纤维元件
公开(公告)号：US08388733B2
公开(公告)日：2013-03-05
申请号：US12679883
申请日：2008-09-29
申请人： Shoichi Yamaoka , Shigekazu Okamura , Masao Kikuchi , Tomonori Kanougi , Yuma Irisa
发明人： Shoichi Yamaoka , Shigekazu Okamura , Masao Kikuchi , Tomonori Kanougi , Yuma Irisa
IPC分类号： B01D53/22
CPC分类号： B01D63/023 , B01D53/22 , B01D61/36 , B01D63/022 , B01D2257/708 , C08K5/18 , C08L63/00
摘要： A hollow fiber element constituting a separation membrane module for separating an organic vapor is disclosed. At least one end part of a fiber bundle consisting of multiple hollow fiber membranes having a selective permeability is fixed and bound with a tube sheet formed by a cured material of an epoxy resin composition. Herein, a resin component of the epoxy resin composition contains an epoxy compound (A) represented by the following formula (1), an epoxy compound (B) represented by the following formula (2) and an aromatic amine compound (C), and wherein the epoxy compound (A) and the epoxy compound (B) are blended at a proportion in a range from 90:10 to 60:40 by weight; wherein R denotes alkyl group having 1 to 3 carbon atoms or hydrogen atom. The tube sheet has enough endurance to retain a gas-tightness of an internal space of the hollow fiber membrane and an external space of the hollow fiber membrane even in use under organic vapor with an elevated temperature and high pressure, and is suitably moldable in a stationary state as well.
摘要翻译：公开了构成用于分离有机蒸气的分离膜组件的中空纤维元件。由具有选择性渗透性的多个中空纤维膜组成的纤维束的至少一个端部与由环氧树脂组合物的固化材料形成的管板固定并结合。这里，环氧树脂组合物的树脂成分含有下述式（1）表示的环氧化合物（A），下述式（2）表示的环氧化合物（B）和芳香族胺化合物（C），以及其中环氧化合物（A）和环氧化合物（B）以90:10至60:40的比例混合; 其中R表示具有1至3个碳原子的烷基或氢原子。管板具有足够的耐久性，即使在高温高压下在有机蒸汽下使用也能够保持中空纤维膜的内部空间的气密性和中空纤维膜的外部空间，并且可适当地模制在固定状态也是如此。

5. 发明授权

US08409325B2 Asymmetric gas separation membrane and process for gas separation 失效
标题翻译：不对称气体分离膜和气体分离过程
公开(公告)号：US08409325B2
公开(公告)日：2013-04-02
申请号：US13121840
申请日：2009-09-30
申请人： Toshimune Yoshinaga , Makoto Nakamura , Tomonori Kanougi , Yoji Kase , Kenji Fukunaga
发明人： Toshimune Yoshinaga , Makoto Nakamura , Tomonori Kanougi , Yoji Kase , Kenji Fukunaga
IPC分类号： B01D53/22
CPC分类号： C08G73/1039 , B01D53/228 , B01D63/021 , B01D69/087 , B01D71/64 , B01D2257/104 , B01D2257/108 , B01D2257/11 , B01D2257/504 , B01D2257/7022 , B01D2325/24 , C08G73/1042 , C08G73/1046 , C08G73/105 , C08G73/1064 , C08G73/1067 , C08G73/1071 , C08L79/08 , Y02C10/10 , Y02P20/152
摘要： There is disclosed an asymmetric gas separation membrane exhibiting both improved gas separation performance and improved mechanical properties, which is made of a soluble aromatic polyimide comprised of a repeating unit represented by general formula (1): wherein B in general formula (1) B comprises 10 to 70 mol % of tetravalent unit B1 represented by general formula (B1) and 90 to 30 mol % of tetravalent unit B2 represented by general formula (B2), and A in general formula (1) comprises 10 to 50 mol % of bivalent unit A1 represented by general formula (A1a) or the like and 90 to 30 mol % of bivalent unit A2 represented by general formula (A2a) or the like.
摘要翻译：公开了一种表现出改善的气体分离性能和改善的机械性能的不对称气体分离膜，其由由通式（1）表示的重复单元组成的可溶性芳族聚酰亚胺制成：其中通式（1）B中的B包含 10〜70摩尔％的通式（B1）表示的四价单元B1和通式（B2）表示的90〜30摩尔％的四价单元B2，通式（1）中的A为10〜50摩尔％由通式（A1a）等表示的单元A1和由通式（A2a）表示的二价单元A2的90〜30摩尔％等。

6. 发明授权

US07285688B2 Proton type β zeolite, preparation method thereof and process for preparing phenol compound using the same 失效
标题翻译：质子型β沸石，其制备方法和使用其制备酚化合物的方法
公开(公告)号：US07285688B2
公开(公告)日：2007-10-23
申请号：US10856886
申请日：2004-05-27
申请人： Tomonori Kanougi , Takashi Atoguchi , Shigeru Yao
发明人： Tomonori Kanougi , Takashi Atoguchi , Shigeru Yao
IPC分类号： C07C27/10
CPC分类号： B01J29/7007 , B01J2229/16 , C01B39/026 , C07C37/60 , C07C41/26 , Y02P20/52 , C07C39/08 , C07C39/07 , C07C43/23
摘要： Disclosed are a proton type β zeolite in which an acid site showing a desorption peak with a range of ±100° C. with a center of 330° C. exists in a spectrum measured by the ammonia temperature programmed desorption method (NH3-TPD), and an amount of a strong acid site showing a desorption peak of 500° C. or higher is controlled to 2.5 μmol/g or less, a method for preparing the same, and a process for preparing a phenol compound by oxidizing a benzene compound with a peroxide in the presence of the proton type β zeolite.
摘要翻译：公开了一种质子型β沸石，其中在通过氨温度程序解吸法（NH 3）测量的光谱中存在其中具有330℃的±100℃范围内的解吸峰的酸性位点， 3 -TPD），并且显示出500℃以上的解吸峰的强酸性部位的量控制在2.5μmol/ g以下，其制备方法及其制备方法苯酚化合物通过在质子型β沸石的存在下用过氧化物氧化苯化合物。

7. 发明授权

US09211497B2 Asymmetric gas separation membrane and method for separating methanol from mixed organic vapor using the same 有权
标题翻译：不对称气体分离膜及使用其分离甲醇与混合有机蒸气的方法
公开(公告)号：US09211497B2
公开(公告)日：2015-12-15
申请号：US13992600
申请日：2011-12-09
申请人： Ryoichi Takada , Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Kenji Fukunaga
发明人： Ryoichi Takada , Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Kenji Fukunaga
IPC分类号： B01D53/22 , B01D71/64 , B01D53/72 , B01D69/02 , B01D69/08 , C08L79/08
CPC分类号： B01D53/228 , B01D53/22 , B01D53/72 , B01D69/02 , B01D69/08 , B01D71/64 , B01D2257/704 , B01D2325/20 , C08L79/08
摘要： An asymmetric gas separation membrane made of an aromatic polyimide mainly containing repeating units having an ether bond which is heated at a temperature near a softening point (Ts) of the aromatic polyimide, and a method for separating methanol from a methanol-containing mixed organic vapor by allowing methanol to selectively permeate the asymmetric gas separation membrane using the membrane.
摘要翻译：由芳族聚酰亚胺主要含有在芳香族聚酰亚胺的软化点（Ts）附近被加热的醚键的重复单元的芳香族聚酰亚胺构成的不对称气体分离膜和从含甲醇的混合有机蒸气中分离甲醇的方法通过使甲醇选择性地使用膜渗透不对称气体分离膜。

8. 发明申请

US20130319229A1 ASYMMETRIC GAS SEPARATION MEMBRANE AND METHOD FOR SEPARATING METHANOL FROM MIXED ORGANIC VAPOR USING THE SAME 有权
标题翻译：不对称气体分离膜和使用其分离混合有机蒸气的甲醇的方法
公开(公告)号：US20130319229A1
公开(公告)日：2013-12-05
申请号：US13992600
申请日：2011-12-09
申请人： Ryoichi Takada , Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Kenji Fukunaga
发明人： Ryoichi Takada , Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Kenji Fukunaga
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D53/22 , B01D53/72 , B01D69/02 , B01D69/08 , B01D71/64 , B01D2257/704 , B01D2325/20 , C08L79/08
摘要： An asymmetric gas separation membrane made of an aromatic polyimide mainly containing repeating units having an ether bond which is heated at a temperature near a softening point (Ts) of the aromatic polyimide, and a method for separating methanol from a methanol-containing mixed organic vapor by allowing methanol to selectively permeate the asymmetric gas separation membrane using the membrane.
摘要翻译：由芳族聚酰亚胺主要含有在芳香族聚酰亚胺的软化点（Ts）附近被加热的醚键的重复单元的芳香族聚酰亚胺构成的不对称气体分离膜和从含甲醇的混合有机蒸气中分离甲醇的方法通过使甲醇选择性地使用膜渗透不对称气体分离膜。

9. 发明授权

US08580012B2 Solvent-resistant asymmetric hollow fiber gas separation membrane, and method for production thereof 失效
标题翻译：耐溶剂型不对称中空纤维气体分离膜及其制造方法
公开(公告)号：US08580012B2
公开(公告)日：2013-11-12
申请号：US12863125
申请日：2009-01-19
申请人： Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Yoji Kase , Kenji Fukunaga
发明人： Harutoshi Hoshino , Tomonori Kanougi , Toshimune Yoshinaga , Yoji Kase , Kenji Fukunaga
IPC分类号： B01D53/22 , B01D71/64
CPC分类号： B01D69/08 , B01D53/228 , B01D71/40 , B01D71/80 , B01D2323/08 , B01D2325/24 , B01D2325/30 , C08G73/1039 , C08G73/1042 , C08G73/1064 , C08G73/1067 , D01F6/74
摘要： An asymmetric hollow fiber gas separation membrane obtained by subjecting an asymmetric hollow fiber polyimide membrane to a heat treatment having a maximum temperature of from 350 to 450° C., wherein the asymmetric hollow fiber polyimide membrane is formed with a polyimide essentially having a repeating unit represented by a general formula (1); is excellent in a solvent resistance and a thermal stability, and as well has such a mechanical strength that a tensile elongation at break is not less than 10% as a hollow fiber membrane. In the general formula (1), 20 to 80 mol % of A is a tetravalent unit based on a biphenyl structure represented by formula (2), 20 to 80 mol % of A is a tetravalent unit based on a diphenylhexafluoropropane structure represented by formula (3), and 0 to 30 mol % of A is a tetravalent unit based on a phenyl structure represented by formula (4); and in the general formula (1), 30 to 70 mol % of R is a divalent unit represented by formula (5) and/or formula (6), and 30 to 70 mol % of R is a divalent unit having one or two other aromatic rings than formula (5) or (6), wherein, R1 and R2 are a hydrogen atom or an organic group, and n is 0, 1 or 2, wherein, R1 and R2 are a hydrogen atom or an organic group, X is —CH2— or —CO—, and n is 0, 1 or 2.
摘要翻译：通过使不对称中空纤维聚酰亚胺膜进行350〜450℃的最高温度的热处理而得到的不对称中空纤维气体分离膜，其中，所述不对称中空纤维聚酰亚胺膜形成有基本上具有重复单元的聚酰亚胺由通式（1）表示; 耐溶剂性和热稳定性优异，作为中空纤维膜，具有拉伸断裂伸长率为10％以上的机械强度。在通式（1）中，A为20〜80摩尔％，为基于式（2）所示的联苯结构的四价单元，A为20〜80摩尔％，基于式（2）表示的二苯基六氟丙烷结构的四价单元（3）表示，0〜30摩尔％的A为基于式（4）表示的苯基结构的四价单元。在通式（1）中，R为作为式（5）和/或式（6）所示的二价单元的30〜70摩尔％，R为30〜70摩尔％，为1或2个（5）或（6）中的其它芳环，其中R1和R2是氢原子或有机基团，n是0,1或2，其中R1和R2是氢原子或有机基团， X是-CH 2 - 或-CO-，n是0,1或2。

10. 发明申请

US20120031831A1 HOLLOW-FIBER ELEMENT FOR ORGANIC-VAPOR SEPARATION 有权
标题翻译：有机蒸汽分离器的中空元件
公开(公告)号：US20120031831A1
公开(公告)日：2012-02-09
申请号：US13262158
申请日：2010-03-31
申请人： Tomonori Kanougi , Yuma Irisa , Kenji Fukunaga
发明人： Tomonori Kanougi , Yuma Irisa , Kenji Fukunaga
IPC分类号： B01D63/04
CPC分类号： B01D63/02 , B01D63/022 , B01D63/023 , B01D2313/08
摘要： In a hollow fiber element constituting a separation membrane module for separating an organic vapor, at least one end part of a fiber bundle consisting of multiple hollow fiber membranes having a selective permeability is fixed and bound with a tube sheet formed by a cured material, in which an epoxy composition (A) has been cured by using a hardener (B). A glass transition temperature of said cured material is not less than 160° C., a minimum elongation at break thereof is not less than 7.0%, and an elution ratio thereof is less than 5%. For this reason, the hollow fiber element has enough endurance to retain a gas-tightness of an internal space of the hollow fiber membrane and an external space of the hollow fiber membrane even in use under organic vapor with an elevated temperature and high pressure.
摘要翻译：在构成用于分离有机蒸气的分离膜组件的中空纤维元件中，由具有选择性渗透性的多个中空纤维膜组成的纤维束的至少一个端部被固化并与由固化材料形成的管板结合，其中环氧组合物（A）已经通过使用硬化剂（B）固化。所述固化材料的玻璃化转变温度不低于160℃，最小断裂伸长率不小于7.0％，洗脱比小于5％。因此，中空纤维元件具有足够的耐久性，即使在高温高压下在有机蒸气下使用也能够保持中空纤维膜的内部空间的气密性和中空纤维膜的外部空间。

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