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    • 4. 发明授权
    • Method for producing cyclopropanecarboxylates
    • 制备环丙烷羧酸酯的方法
    • US06706910B2
    • 2004-03-16
    • US09984894
    • 2001-10-31
    • Kazunori IwakuraHiroshi SoudaTohei TakagakiYoshimi Yamada
    • Kazunori IwakuraHiroshi SoudaTohei TakagakiYoshimi Yamada
    • C07C6974
    • C07C67/03C07C69/743
    • There is provided a method for producing a cyclopropanecarboxylate of formula (1): which comprises contacting a cyclopropanecarboxylate of formula (2): with a monohydroxy compound of formula (3): R7OH  (3) in the presence of a lithium compound of formula (4): R8OLi  (4), wherein R1, R2, R3, R4 and R5 each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, or a substituted or unsubstituted aryl group; R6 represents an alkyl group having 1 to 10 carbon atoms or a substituted or unsubstituted phenyl group; R7 and R8 do not simultaneously represent the same and each independently represent a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group.
    • 提供了制备式(1)的环丙烷羧酸酯的方法:其包括使式(2)的环丙烷羧酸酯与式(3)的单羟基化合物在式(4)的锂化合物存在下接触:其中R R 1,R 3,R 3,R 4和R 5各自独立地表示氢原子,卤素原子,取代或未取代的烷基,取代或未取代的烯基,或取代或未取代的 未取代的芳基; R 6表示具有1〜10个碳原子的烷基或取代或未取代的苯基; R 7和R 8不同时表示相同且各自独立地表示取代或未取代的烷基, 或取代或未取代的芳基。