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    • 1. 发明申请
    • USE OF LIQUID HYDROGEN CHLORIDE AS REFRIGERANT IN PROCESSES FOR PREPARING CHLORINE
    • 氯化氢作为制冷剂在制备氯化物的工艺中的应用
    • US20120213693A1
    • 2012-08-23
    • US13371910
    • 2012-02-13
    • Hans-Jürgen PALLASCHHeiner SCHELLINGPeter VAN DEN ABEELTill EINIG
    • Hans-Jürgen PALLASCHHeiner SCHELLINGPeter VAN DEN ABEELTill EINIG
    • C01B7/04
    • C01B7/04
    • This invention relates to a process for preparing chlorine from HCl and a method of using liquid HCl to cool and optionally liquefy chlorine in the process. The process involves introducing at least one HCl-containing stream and an oxygen-containing stream into an oxidation zone and catalytically oxidizing the HCl to chlorine, contacting the chlorine with aqueous HCl with partial separation of water and HCl to yield a gas stream, drying the gas stream to yield an essentially water-free gas stream, which is compressed and cooled to give an at least partially liquefied stream, and separating the liquefied stream into a gas stream and a liquid stream which is separated into a chlorine stream, such that cooling and partial liquefaction of the gas stream is effected by indirect heat exchange with a liquid HCl stream, resulting in some of the liquid HCl stream vaporizing to form a gaseous HCl stream.
    • 本发明涉及一种从HCl制备氯的方法,以及使用液体HCl冷却和任选地在该过程中液化氯的方法。 该方法包括将至少一种含HCl流和含氧物流引入氧化区并将HCl催化氧化成氯,将氯与HCl水溶液接触,部分分离出水和HCl,产生气流,干燥 气流以产生基本上无水的气流,其被压缩和冷却以产生至少部分液化的流,并将液化物流分离成气流和液态物流,其被分离成氯气流,使得冷却 并且通过与液体HCl流的间接热交换来实现气流的部分液化,导致一些液体HCl流汽化以形成气态HCl流。