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    • 9. 发明授权
    • Use of liquefied natural gas (LNG) coupled with a cold expander to
produce liquid nitrogen
    • 使用与冷膨胀器相连的液化天然气(LNG)产生液氮
    • US5141543A
    • 1992-08-25
    • US691773
    • 1991-04-26
    • Rakesh AgrawalThomas E. Cormier, Sr.
    • Rakesh AgrawalThomas E. Cormier, Sr.
    • F25J3/04F17C9/04F25J1/02
    • F25J3/04351F17C9/04F25J1/0015F25J1/0037F25J1/004F25J1/0042F25J1/0224F25J1/0234F25J1/0292F25J3/0406F25J3/0409F25J3/04224F25J3/04266F25J3/04387F17C2221/033F17C2223/0161F17C2223/033F17C2225/0123F17C2227/0309F17C2265/05F25J2210/50F25J2210/62F25J2230/08F25J2230/42F25J2240/12F25J2245/42F25J2245/90
    • The present invention relates to a process for the liquefaction of a nitrogen stream produced by separating air components, by using the combination of cryogenic distillation with improved refrigeration. Very cold liquefied natural gas (LNG) is employed as refrigerant, with the LNG currently being revaporized for transportation.Multi-stage component compression is used, with the component feed to each compression stage being precooled using sequential refrigeration from the LNG. Expander means for the coldest air component product stream provides supplemental refrigeration at the cold end beyond that which is available from the refrigerant LNG.In a preferred embodiment, the feed nitrogen stream(s) are compressed to at least 300 psi in a multi-stage compressor with interstage cooling provided by heat exchange against vaporizing LNG; the resulting compressed stream is directed into first and second nitrogen substreams, followed by further cooling of the first substream by heat exchange against vaporizing LNG and then expanding the cooled first substream to produce an expanded nitrogen substream. Condensing of the second compressed substream against both vaporizing LNG and the expanded nitrogen substream is carried out. Reducing the pressure of the condensed second nitrogen substream produces a two phase nitrogen stream. Phase separation yields a recyclable nitrogen vapor stream and a liquid nitrogen stream as product.
    • 本发明涉及通过使用低温蒸馏与改进的制冷的组合分离空气组分而产生的氮气流的液化方法。 使用非常冷的液化天然气(LNG)作为制冷剂,目前LNG正在进行再蒸发运输。 使用多级部件压缩,使用来自LNG的顺序制冷将每个压缩级的分量进料预冷却。 用于最冷空气组分产物流的膨胀器意味着在冷端超过可从制冷剂LNG获得的冷却的补充制冷。 在一个优选的实施方案中,在多级压缩机中将进料氮气流压缩至至少300psi,其中通过与蒸发的LNG进行热交换而提供级间冷却; 将所得压缩流引导到第一和第二氮气流中,随后通过与汽化LNG的热交换进一步冷却第一子流,然后使冷却的第一子流扩展以产生膨胀的氮气流。 执行第二压缩子流对蒸发LNG和膨胀氮气流的冷凝。 减少浓缩的第二氮气流的压力产生两相氮气流。 相分离产生可回收的氮蒸汽流和液氮流作为产物。