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2. 发明授权

US4065598A Process for polymeric modification of a fiber 失效
标题翻译：聚合物改性纤维的方法
公开(公告)号：US4065598A
公开(公告)日：1977-12-27
申请号：US777655
申请日：1977-03-15
申请人： Kooji Takahashi , Tatsuji Kojima , Teruo Ishikawa , Kimio Nakamura , Shizuyoshi Ikenaga
发明人： Kooji Takahashi , Tatsuji Kojima , Teruo Ishikawa , Kimio Nakamura , Shizuyoshi Ikenaga
IPC分类号： D06M15/263 , B32B27/00 , D02G3/00
CPC分类号： D06M15/263 , Y10T428/2967 , Y10T428/2969 , Y10T442/2295 , Y10T442/2434 , Y10T442/2492
摘要： A process for imparting antistatic, soil release and water-absorbing properties to a synthetic fiber structure which comprises adhering the following agent (A) or (B): to the fiber structureA. a compound selected from the group consisting of diacrylate, dimethacrylate, triacrylate and trimethacrylate compound having a polyalkylene oxide segment which has a molecular weight of from 400 to 10,000 and which includes an alkylene substituent selected from the group consisting of ethylene groups, propylene groups and a mixture of ethylene groups and propylene groupsB. a mixture ofA. a compound selected from the class consisting of propylene glycol methacrylate, methoxy polyethylene glycol acrylate, methoxy polyethylene glycol methacrylate, ethoxy polyethylene glycol acrylate, ethoxy polyethylene glycol methacrylate, chlorinated polyethylene glycol methacrylate, polypropylene glycol methacrylate, methoxy polypropylene glycol acrylate, polypropylene glycol acrylate, methyl sulfide polyethylene glycol methacrylate and compounds having a vinyl group as a side chain as follows: ##STR1## wherein R.sub.1 and R.sub.2 represent hydrogen, methyl or ethyl, and wherein n & m are integer from 5 - 500, the molecular weight of whose polyalkylene oxide segment is 400 - 10,000; withB. a compound selected from the group of a diacrylate, dimethacrylate, triacrylate or trimethacrylate compound having a polyalkylene oxide segment which has a molecular weight of from about 400 - 10,000 and which includes alkylene groups, propylene groups and mixtures thereof.The mix ratio of the compound (b) being about 3.0 - 50.0% by weight based on the solid portion of the compound (a),And heat-treating the adhered fiber structure in the presence of moisture, whereby polymerization is carried out as a film on the fiber, and the surface of the fiber is covered with a polymer film of said compound, the film having a thickness of about 0.01 - 10.mu..
摘要翻译：一种赋予合成纤维结构抗静电，去污和吸水性能的方法，其包括将以下试剂（A）或（B）：粘合到纤维结构体A上。选自二丙烯酸酯，二甲基丙烯酸酯，三丙烯酸酯和三甲基丙烯酸酯化合物，其具有分子量为400至10,000的聚环氧烷链段，并且其包括选自亚乙基，亚丙基和亚乙基和丙烯基的混合物的亚烷基取代基B.将 A. SELECTED从类甲基丙烯酸丙二醇酯，甲氧基聚乙二醇丙烯酸酯，甲氧基聚乙二醇甲基丙烯酸酯，乙氧基聚乙二醇丙烯酸酯，乙氧基聚乙二醇甲基丙烯酸酯，氯化聚乙烯乙二醇甲基丙烯酸酯，聚丙二醇甲基丙烯酸酯，甲氧基聚乙二醇丙烯酸酯，聚丙二醇组成的复合丙烯酸酯，甲基磺酰基聚乙二醇 ENE甘油甲基丙烯酸酯和具有作为侧链的乙烯基团的化合物如下：＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;其中R1和R2表示氢，甲基或乙基，并且其中n＆m是5-500的整数，分子量其聚环氧烷链段为400〜10,000; B.由二丙烯酸酯，二甲基丙烯酸酯，三丙烯酸酯或三甲基丙烯酸酯化合物组成的化合物，其具有约400-10,000的分子量的聚亚烷基氧化物部分，并且包括亚烷基组，丙烯基团和其混合物。

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