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1. 发明授权

US08722011B2 Method of producing hydrogen from ammonia 失效
标题翻译：从氨生产氢气的方法
公开(公告)号：US08722011B2
公开(公告)日：2014-05-13
申请号：US13822041
申请日：2011-07-06
申请人： Susumu Hikazudani , Takuma Mori , Sadao Araki
发明人： Susumu Hikazudani , Takuma Mori , Sadao Araki
IPC分类号： H01M8/06 , B01J7/00 , C01B3/04 , F02B43/10
CPC分类号： C01B3/06 , C01B3/047 , C01B21/26 , Y02E60/364 , Y02P20/129
摘要： In a method by which hydrogen supplied as a combustion aid to an ammonia combustion engine is produced from ammonia, the filling amount of a decomposition catalyst in an ammonia decomposition apparatus is reduced. The method includes an ammonia decomposition apparatus that produces hydrogen as a combustion aid and an ammonia oxidation apparatus that allows a part of introduced ammonia to react with oxygen for combustion by action of an oxidation catalyst in order to supply the heat needed for the ammonia decomposition reaction, wherein the amount of ammonia and the amount of air introduced into the oxidation apparatus are controlled in accordance with the entrance temperature of an ammonia oxidation catalyst layer, so as to set the ammonia decomposition ratio in the ammonia decomposition apparatus to be 40 to 60% at all times.
摘要翻译：在由氨制造作为燃烧助燃剂的氢气供给的氢的方法中，氨分解装置中的分解催化剂的填充量减少。该方法包括产生作为燃烧助剂的氢的氨分解装置和氨氧化装置，其允许一部分引入的氨与氧气反应以通过氧化催化剂的作用进行燃烧以提供氨分解反应所需的热量其中，根据氨氧化催化剂层的入口温度来控制氨的量和引入氧化装置的空气量，以将氨分解装置中的氨分解比设定为40〜60％每时每刻。

2. 发明申请

US20130266506A1 METHOD OF PRODUCING HYDROGEN FROM AMMONIA 失效
标题翻译：从氨生产氢的方法
公开(公告)号：US20130266506A1
公开(公告)日：2013-10-10
申请号：US13822041
申请日：2011-07-06
申请人： Susumu Hikazudani , Takuma Mori , Sadao Araki
发明人： Susumu Hikazudani , Takuma Mori , Sadao Araki
IPC分类号： C01B3/06
CPC分类号： C01B3/06 , C01B3/047 , C01B21/26 , Y02E60/364 , Y02P20/129
摘要： In a method by which hydrogen supplied as a combustion aid to an ammonia combustion engine is produced from ammonia, the filling amount of a decomposition catalyst in an ammonia decomposition apparatus is reduced. The method includes an ammonia decomposition apparatus that produces hydrogen as a combustion aid and an ammonia oxidation apparatus that allows a part of introduced ammonia to react with oxygen for combustion by action of an oxidation catalyst in order to supply the heat needed for the ammonia decomposition reaction, wherein the amount of ammonia and the amount of air introduced into the oxidation apparatus are controlled in accordance with the entrance temperature of an ammonia oxidation catalyst layer, so as to set the ammonia decomposition ratio in the ammonia decomposition apparatus to be 40 to 60% at all times.
摘要翻译：在由氨制造作为燃烧助燃剂的氢气供给的氢的方法中，氨分解装置中的分解催化剂的填充量减少。该方法包括产生作为燃烧助剂的氢的氨分解装置和氨氧化装置，其允许一部分引入的氨与氧气反应以通过氧化催化剂的作用进行燃烧以提供氨分解反应所需的热量其中，根据氨氧化催化剂层的入口温度来控制氨的量和引入氧化装置的空气量，以将氨分解装置中的氨分解比设定为40〜60％每时每刻。

3. 发明申请

US20120149910A1 Pesticidal Carboxamides 有权
标题翻译：杀虫剂
公开(公告)号：US20120149910A1
公开(公告)日：2012-06-14
申请号：US13390302
申请日：2010-08-03
申请人： Jun Mihara , Koichi Araki , Takuma Mori , Tetsuya Murata , Yasushi Yoneta , Yukiyoshi Watanabe , Eiichi Shimojo , Teruyuki Ichihara , Masashi Ataka , Katsuhiko Shibuya , Ulrich Gorgens
发明人： Jun Mihara , Koichi Araki , Takuma Mori , Tetsuya Murata , Yasushi Yoneta , Yukiyoshi Watanabe , Eiichi Shimojo , Teruyuki Ichihara , Masashi Ataka , Katsuhiko Shibuya , Ulrich Gorgens
IPC分类号： C07C237/42 , C07D231/12 , C07D207/327 , C07D233/61 , C07C255/60 , C07D249/18 , C07C237/40 , C07D213/82 , C07C233/64 , C07D249/08 , C07D257/04
CPC分类号： C07C233/66 , A01N37/42 , A01N37/44 , A01N37/48 , A01N37/50 , A01N43/40 , A01N43/56 , C07C235/84 , C07C237/40 , C07C237/42 , C07C237/48 , C07C251/44 , C07C251/48 , C07C255/19 , C07C255/57 , C07C271/22 , C07C275/24 , C07C309/66 , C07C311/06 , C07C323/60 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/10 , C07C2601/14 , C07C2602/08 , C07C2602/10 , C07D209/48 , C07D213/61 , C07D213/81 , C07D213/82 , C07D213/84 , C07D213/85 , C07D231/12 , C07D231/16 , C07D249/08 , C07D249/18 , C07D249/20 , C07D257/04 , C07D295/155 , C07D401/12
摘要： The object of the present invention is to provide novel carboxamides which exhibit an excellent pesticidal activity as pesticides. Disclosed are the carboxamides represented by the following Formula (I): wherein each substituent is as defined in the specification, and use thereof as pesticides and animal parasite controlling agents.
摘要翻译：本发明的目的是提供一种作为农药具有优良杀虫活性的新型甲酰胺。公开了由下式（I）表示的羧酰胺：其中每个取代基如说明书中所定义，以及其作为农药和动物寄生虫控制剂的用途。

4. 发明申请

US20110306489A1 AMMONIA DECOMPOSITION CATALYST 审中-公开
标题翻译：氨基酸分解催化剂
公开(公告)号：US20110306489A1
公开(公告)日：2011-12-15
申请号：US13203376
申请日：2010-02-18
申请人： Susumu Hikazudani , Takuma Mori , Chikashi Inazumi , Haruyuki Nakanishi , Hidekazu Arikawa , Hironobu Kumagai
发明人： Susumu Hikazudani , Takuma Mori , Chikashi Inazumi , Haruyuki Nakanishi , Hidekazu Arikawa , Hironobu Kumagai
IPC分类号： B01J21/18
CPC分类号： C01B3/047 , B01J21/18 , B01J21/185 , B01J23/462 , B01J23/745 , B01J35/0046 , B01J35/0053 , B01J37/0201 , B01J37/08 , B01J37/086 , B01J37/18 , B82Y30/00 , C08G14/06 , C08L61/04 , Y02E60/364
摘要： Disclosed is an ammonia decomposition catalyst which is obtained by heat-treating a complex at a temperature of 360° C. to 900° C. in a reducing atmosphere, wherein the complex containing a polymer having a molecular weight of 1,000 to 500,000 represented by the formula [I], a transition metal coordinated with the polymer, and an activated carbon or a carbon nanotube added thereto. In a case of using the carbon nanotube, an alkali metal compound or an alkaline earth metal compound is added to the heat-treated complex. R1 represents H or hydrocarbon having 1 to 10 carbon atoms, R2 and R3 each represent H, halogen, nitro, acyl, ester, carboxyl, formyl, nitrile, sulfone, aryl, or alkyl group having 1 to 15 carbon atoms, X and Y each represent H or OH, Z represents CH or N, R4 and R5 each represent H, OH, ether, amino, aryl, or alkyl group having 1 to 15 carbon atoms, x represents a real number of 1 to 2, y represents a real number of 1 to 3, and n represents a real number of 2 to 120. The amount of the transition metal deposited on the catalyst can be increased without deteriorating the dispersion of the metal, so that the amount of the catalyst required to obtain a desired activity can be reduced.
摘要翻译：公开了一种氨还原催化剂，其通过在还原气氛中在360℃至900℃的温度下热处理络合物获得，其中所述络合物含有分子量为1,000至500,000的聚合物，其由式[I]，与聚合物配位的过渡金属，和加入其中的活性炭或碳纳米管。在使用碳纳米管的情况下，向热处理复合体中添加碱金属化合物或碱土金属化合物。 R1表示H或碳原子数1〜10的烃，R2和R3各自表示H，卤素，硝基，酰基，酯，羧基，甲酰基，腈，砜，芳基或碳原子数1〜15的烷基，X和Y 各自表示H或OH，Z表示CH或N，R 4和R 5各自表示H，OH，醚，氨基，芳基或具有1至15个碳原子的烷基，x表示1至2的实数，y表示实数1〜3，n表示2〜120的实数。可以提高沉积在催化剂上的过渡金属的量，而不会使金属的分散性恶化，从而获得所需催化剂的量可以减少所需的活动。

5. 发明申请

US20130288890A1 AMMONIA OXIDATION/DECOMPOSITION CATALYST 审中-公开
标题翻译：氨基氧化/分解催化剂
公开(公告)号：US20130288890A1
公开(公告)日：2013-10-31
申请号：US13883302
申请日：2011-11-09
申请人： Susumu Hikazudani , Takuma Mori , Sadao Araki
发明人： Susumu Hikazudani , Takuma Mori , Sadao Araki
IPC分类号： B01J23/83 , B01J23/34 , B01J23/28 , B01J23/63
CPC分类号： C01B3/047 , B01J23/28 , B01J23/34 , B01J23/63 , B01J23/83 , B01J35/04 , B01J37/0009 , B01J37/0201 , B01J37/038 , B01J37/18 , H01M8/0606 , H01M8/222 , Y02E60/364
摘要： Provided is an ammonia oxidation/decomposition catalyst which can decrease the reduction temperature of a support, which is required for the catalyst to have a property of being activated at room temperature, and also can render a property of being activated at a temperature lower than room temperature. The ammonia oxidation/decomposition catalyst of the present invention is an ammonia oxidation/decomposition catalyst, comprising: a catalyst support composed of a composite oxide of cerium oxide and zirconium oxide; and at least one metal selected from the group consisting of metals of group 6A, group 7A, group 8, and group 1B as a catalytically active metal deposited thereon, characterized in that the molar concentration of zirconium oxide in the catalyst support is from 10 to 90%.
摘要翻译：提供了能够降低载体的还原温度的氨氧化/分解催化剂，催化剂具有在室温下被活化的性质，并且还可以使其在低于室温的温度下活化温度。本发明的氨氧化/分解催化剂是氨氧化/分解催化剂，包括：由氧化铈和氧化锆的复合氧化物构成的催化剂载体; 和选自6A，7A，8族和1B族金属中的至少一种金属作为沉积在其上的催化活性金属，其特征在于催化剂载体中氧化锆的摩尔浓度为10〜 90％。

6. 发明授权

US08822691B2 Pesticidal carboxamides 有权
标题翻译：杀虫甲酰胺
公开(公告)号：US08822691B2
公开(公告)日：2014-09-02
申请号：US13386598
申请日：2010-07-10
申请人： Jun Mihara , Koichi Araki , Takuma Mori , Tetsuya Murata , Yasushi Yoneta , Eiichi Shimojo , Teruyuki Ichihara , Masashi Ataka , Katsuhiko Shibuya , Ulrich Görgens
发明人： Jun Mihara , Koichi Araki , Takuma Mori , Tetsuya Murata , Yasushi Yoneta , Eiichi Shimojo , Teruyuki Ichihara , Masashi Ataka , Katsuhiko Shibuya , Ulrich Görgens
IPC分类号： A01N37/34 , A01N43/42 , C07D215/48 , C07D215/60 , C07D277/68
CPC分类号： C07D215/48 , A01N37/34 , A01N43/42 , A01N43/78 , A01N43/82 , C07C211/52 , C07C217/84 , C07C233/66 , C07C237/48 , C07C255/57 , C07C2601/14 , C07D215/60 , C07D277/68
摘要： To provide novel carboxamides which exhibit an excellent pesticidal activity as pesticides. Carboxamides represented by the following Formula (I) and use thereof as pesticides and an animal parasite control agent: wherein each substituent is as defined in the specification.
摘要翻译：提供作为农药具有优良杀虫活性的新型甲酰胺。由下式（I）表示的羧酰胺及其作为农药的用途和动物寄生虫控制剂：其中每个取代基如说明书中所定义。

7. 发明申请

US20130156687A1 AMMONIA OXIDATION/DECOMPOSITION CATALYST 有权
标题翻译：氨基氧化/分解催化剂
公开(公告)号：US20130156687A1
公开(公告)日：2013-06-20
申请号：US13819070
申请日：2010-08-31
申请人： Sadao Araki , Susumu Hikazudani , Takuma Mori , Akira Taniguchi
发明人： Sadao Araki , Susumu Hikazudani , Takuma Mori , Akira Taniguchi
IPC分类号： C01B3/04
CPC分类号： C01B3/047 , B01J23/002 , B01J23/10 , B01J23/14 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/63 , B01J23/66 , B01J23/83 , B01J37/0201 , B01J37/031 , B01J2523/00 , Y02E60/364 , B01J2523/31 , B01J2523/3712 , B01J2523/48 , B01J2523/41 , B01J2523/47 , B01J2523/22
摘要： The present invention provides an ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon. By bringing the ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon into contact with ammonia and air at ordinary temperature, the support in a reduced state reacts with oxygen to generate oxidation heat, and the temperature of the catalyst layer is increased in a moment. Once the temperature of the catalyst layer is increased to a temperature at which ammonia and oxygen react with each other, the ammonia oxidation reaction proceeds autonomously after that. The heat generated in this exothermic reaction is used in the course of decomposing ammonia in the presence of the catalytically active metal, thereby producing hydrogen.
摘要翻译：本发明提供一种氨氧化/分解催化剂，其包含由可氧化还原性金属氧化物和负载在其上的催化活性金属构成的载体。通过将包含由可氧化还原性金属氧化物构成的载体和负载有催化活性金属的氨氧化/分解催化剂在常温下与氨和空气接触，还原态的载体与氧气反应产生氧化热，并且催化剂层的温度暂时增加。一旦催化剂层的温度升高到氨和氧彼此反应的温度，氨氧化反应就自动进行。在该放热反应中产生的热在催化活性金属存在下分解氨的过程中使用，从而产生氢。

8. 发明申请

US20110201603A1 Novel Acylaminobenzamide Derivatives 审中-公开
标题翻译：新型酰氨基苯甲酰胺衍生物
公开(公告)号：US20110201603A1
公开(公告)日：2011-08-18
申请号：US13057934
申请日：2009-07-30
申请人： Jun Mihara , Tetsuya Murata , Kei Domon , Yukiyoshi Watanabe , Yasushi Yoneta , Takuma Mori , Eiichi Shimojo , Katsuhiko Shibuya , Teruyuki Ichihara , Masashi Ataka , Ulrich Görgens
发明人： Jun Mihara , Tetsuya Murata , Kei Domon , Yukiyoshi Watanabe , Yasushi Yoneta , Takuma Mori , Eiichi Shimojo , Katsuhiko Shibuya , Teruyuki Ichihara , Masashi Ataka , Ulrich Görgens
IPC分类号： A01N43/84 , C07D401/12 , C07C237/42 , C07D213/56 , C07D241/24 , C07D285/06 , C07D413/12 , C07D417/12 , A01N43/48 , A01N37/24 , A01N43/40 , A01N43/60 , A01N43/828 , A01N43/58 , A01P7/00
CPC分类号： C07C237/42 , A01N37/18 , A01N43/40 , A01N43/50 , A01N43/52 , A01N43/56 , A01N43/647 , A01N43/653 , A01N43/713 , A01N43/78 , A01N43/84 , A01N55/00 , C07D213/82 , C07D241/24 , C07D285/06 , C07D401/12
摘要： The present invention relates to novel Acylaminobenzamide derivatives represented by the following formula (I) and use thereof as pesticides: wherein V represents an aromatic ring group of V1 to V5 described in the detailed description, Q represents an aromatic ring group of Q1 to Q7 described in the detailed description, G1 and G2 represent O or S, R1 represents hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, phenyl or a heterocyclic group and R2 and R3 represent hydrogen, alkyl, haloalkyl, alkylcarbonyl, haloalkylcarbonyl, alkoxycarbonyl or haloalkoxycarbonyl.
摘要翻译：本发明涉及由下式（I）表示的新型酰氨基苯甲酰胺衍生物及其作为农药的用途：其中V表示详细描述中描述的V1至V5的芳环基团，Q表示所述的Q1至Q7的芳族环基团在详细描述中，G1和G2表示O或S，R1表示氢，烷基，卤代烷基，烷氧基，卤代烷氧基，苯基或杂环基，R2和R3表示氢，烷基，卤代烷基，烷基羰基，卤代烷基羰基，烷氧基羰基或卤代烷氧基羰基。

9. 发明授权

US09580309B2 Ammonia oxidation/decomposition catalyst 有权
标题翻译：氨氧化/分解催化剂
公开(公告)号：US09580309B2
公开(公告)日：2017-02-28
申请号：US13819070
申请日：2010-08-31
申请人： Sadao Araki , Susumu Hikazudani , Takuma Mori , Akira Taniguchi
发明人： Sadao Araki , Susumu Hikazudani , Takuma Mori , Akira Taniguchi
IPC分类号： C01B3/50 , C01B3/04 , B01J23/00 , B01J23/10 , B01J23/14 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/63 , B01J23/66 , B01J23/83 , B01J37/02 , B01J37/03
CPC分类号： C01B3/047 , B01J23/002 , B01J23/10 , B01J23/14 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/63 , B01J23/66 , B01J23/83 , B01J37/0201 , B01J37/031 , B01J2523/00 , Y02E60/364 , B01J2523/31 , B01J2523/3712 , B01J2523/48 , B01J2523/41 , B01J2523/47 , B01J2523/22
摘要： The present invention provides an ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon. By bringing the ammonia oxidation/decomposition catalyst including a support composed of an oxidizable and reducible metal oxide and a catalytically active metal supported thereon into contact with ammonia and air at room temperature, the support in a reduced state reacts with oxygen to generate oxidation heat, and the temperature of the catalyst layer is increased in a moment. Once the temperature of the catalyst layer is increased to a temperature at which ammonia and oxygen react with each other, the ammonia oxidation reaction proceeds autonomously after that. The heat generated in this exothermic reaction is used in the course of decomposing ammonia in the presence of the catalytically active metal, thereby producing hydrogen.
摘要翻译：本发明提供一种氨氧化/分解催化剂，其包含由可氧化还原性金属氧化物和负载在其上的催化活性金属构成的载体。通过将包含由可氧化和可还原的金属氧化物构成的载体和负载在其上的催化活性金属的氨氧化/分解催化剂在室温下与氨和空气接触，还原态的载体与氧反应产生氧化热，并且催化剂层的温度暂时增加。一旦催化剂层的温度升高到氨和氧彼此反应的温度，氨氧化反应就自动进行。在该放热反应中产生的热在催化活性金属存在下分解氨的过程中使用，从而产生氢。

10. 发明授权

US08932773B2 Hydrogen generating apparatus and hydrogen generating method 有权
标题翻译：氢发生装置和氢气生成方法
公开(公告)号：US08932773B2
公开(公告)日：2015-01-13
申请号：US13255381
申请日：2010-03-11
申请人： Haruyuki Nakanishi , Hidekazu Arikawa , Susumu Hikazudani , Chikashi Inazumi , Sadao Araki , Takuma Mori
发明人： Haruyuki Nakanishi , Hidekazu Arikawa , Susumu Hikazudani , Chikashi Inazumi , Sadao Araki , Takuma Mori
IPC分类号： H01M8/06 , C01B3/04 , B01J8/02 , B01J8/04 , B01J21/04 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/745 , B01J23/755 , B01J35/02
CPC分类号： C01B3/047 , B01J8/0221 , B01J8/0438 , B01J21/04 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/745 , B01J23/755 , B01J35/023 , B01J2208/00061 , B01J2208/00274 , B01J2208/025 , C01B2203/06 , C01B2203/066 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , Y02E60/364
摘要： A hydrogen generating apparatus for effectively generating hydrogen from ammonia and relates to the hydrogen generating apparatus for generating hydrogen from ammonia. The apparatus comprises an ammonia oxidation part having ammonia oxidation catalysts which oxidizes ammonia, and an ammonia decomposition part having an ammonia decomposition catalyst which decomposes ammonia to generate nitrogen and hydrogen. The decomposition part is located downstream of the oxidation part in a direction of feed gas flow. The oxidation catalyst contains both a noble metal catalyst and a base metal catalyst, and a loading concentration of the noble metal catalyst in an upstream portion of the oxidation part is higher than a loading concentration of the noble metal catalyst in a downstream portion of the oxidation part, and/or the decomposition catalyst contains both a noble metal catalyst and a base metal catalyst, and a loading concentration of the noble metal catalyst in a downstream portion of the decomposition part is higher than a loading concentration of the noble metal catalyst in an upstream portion of the decomposition part.
摘要翻译：一种用于从氨有效地产生氢的氢产生装置，涉及用于从氨产生氢的氢生成装置。该装置包括具有氧化氨的氨氧化催化剂的氨氧化部分和具有分解氨以产生氮和氢的氨分解催化剂的氨分解部分。分解部分沿着进料气流的方向位于氧化部分的下游。氧化催化剂含有贵金属催化剂和贱金属催化剂，氧化部分上游部分的贵金属催化剂的负载浓度高于贵金属催化剂在氧化部分的下游部分的负载浓度部分和/或分解催化剂含有贵金属催化剂和贱金属催化剂，并且贵金属催化剂在分解部分的下游部分的负载浓度高于贵金属催化剂在负载浓度分解部分的上游部分。

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