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    • 1. 发明授权
    • Beta-alumina solid electrolyte
    • β-氧化铝固体电解质
    • US5612154A
    • 1997-03-18
    • US397756
    • 1995-03-02
    • Masaharu KajitaTakehiro KajiharaTakao Totoki
    • Masaharu KajitaTakehiro KajiharaTakao Totoki
    • C04B35/113H01M10/39H01M6/18
    • H01M10/3918C04B35/113
    • A beta-alumina solid electrolyte for use in a sodium-sulfur battery is composed of beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and an aspect ratio of 4.0 or less. The beta-alumina solid electrolyte is composed of the beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and has such a particle diameter distribution that the average particle diameter is 3 .mu.m or less, the proportion of the particles having a particle diameter of 5 .mu.m or less is 90% or more, and the maximum particle diameter is 300 .mu.m or less. A process for producing a beta-alumina solid electrolyte using an alumina source material, a magnesium source material and a sodium source material, uses a magnesium-aluminum spinel as the magnesium source material and subjects all materials to mixing, granulation, molding and firing to obtain a beta-alumina solid electrolyte without subjecting the materials to calcination. The beta-alumina solid electrolyte has a low electrical resistance and a large strength to internal water pressure and exhibits excellent properties when used as a diaphragm for a sodium-sulfur battery.
    • 用于钠硫电池的β-氧化铝固体电解质由具有朝向其C轴的取向程度为0.2-0.4,宽高比为4.0以下的β-氧化铝晶体组成。 β-氧化铝固体电解质由具有C轴取向度的β-氧化铝晶体构成,为0.2〜0.4,具有平均粒径为3μm以下的粒径分布,比例 的粒径为5μm以下的粒子为90%以上,最大粒径为300μm以下。 使用氧化铝源材料,镁源材料和钠源材料制造β-氧化铝固体电解质的方法使用镁 - 铝尖晶石作为镁源材料,并将所有材料进行混合,造粒,模塑和烧制 获得β-氧化铝固体电解质,而不对材料进行煅烧。 β-氧化铝固体电解质具有低电阻和较大的内部水压强度,并且在用作钠硫电池的隔膜时表现出优异的性能。
    • 5. 发明授权
    • Beta-alumina solid electrolyte and process for production thereof
    • β-氧化铝固体电解质及其生产方法
    • US5691082A
    • 1997-11-25
    • US707293
    • 1996-09-03
    • Masaharu KajitaTakehiro KajiharaTakao Totoki
    • Masaharu KajitaTakehiro KajiharaTakao Totoki
    • C04B35/113H01M10/39H01M6/18C01F7/00
    • H01M10/3918C04B35/113
    • A beta-alumina solid electrolyte for use in a sodium-sulfur battery is composed of beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and an aspect ratio of 4.0 or less. The beta-alumina solid electrolyte is composed of the beta-alumina crystals having a degree of orientation toward the C axis thereof, of 0.2-0.4 and has such a particle diameter distribution that the average particle diameter is 3 .mu.m or less, the proportion of the particles having a particle diameter of 5 .mu.m or less is 90% or more, and the maximum particle diameter is 300 .mu.m or less. A process for producing a beta-alumina solid electrolyte using an alumina source material, a magnesium source material and a sodium source material, uses a magnesium-aluminum spinel as the magnesium source material and subjects all materials to mixing, granulation, molding and firing to obtain a beta-alumina solid electrolyte without subjecting the materials to calcination. The beta-alumina solid electrolyte has a low electrical resistance and a large strength to internal water pressure and exhibits excellent properties when used as a diaphragm for a sodium-sulfur battery.
    • 用于钠硫电池的β-氧化铝固体电解质由具有朝向其C轴的取向程度为0.2-0.4,宽高比为4.0以下的β-氧化铝晶体组成。 β-氧化铝固体电解质由具有C轴取向度的β-氧化铝晶体构成,为0.2〜0.4,具有平均粒径为3μm以下的粒径分布,比例 的粒径为5μm以下的粒子为90%以上,最大粒径为300μm以下。 使用氧化铝源材料,镁源材料和钠源材料制造β-氧化铝固体电解质的方法使用镁 - 铝尖晶石作为镁源材料,并将所有材料进行混合,造粒,模塑和烧制 获得β-氧化铝固体电解质,而不对材料进行煅烧。 β-氧化铝固体电解质具有低电阻和较大的内部水压强度,并且在用作钠硫电池的隔膜时表现出优异的性能。