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    • 4. 发明授权
    • Process for producing optical glass product
    • 光学玻璃制品生产工艺
    • US4528010A
    • 1985-07-09
    • US584968
    • 1984-02-29
    • Takao EdahiroNobuo InagakiShiro Kurosaki
    • Takao EdahiroNobuo InagakiShiro Kurosaki
    • C01B33/187C03B8/02C03B37/016C03C3/04C03C3/06C03C23/00G02B6/00C03B19/06
    • C03C23/008C03B37/016C03C3/06C03B2201/30C03B2201/50C03C2201/50C03C2203/24C03C2203/36Y10S65/901
    • A process for producing an optical glass product having a predetermined distribution of refractive index in the interior of the product is disclosed. The process comprises the steps of:(a) preparing an aqueous silicate solution containing from about 0.1 to about 0.6 mol/liter of Si (as SiO.sub.2) comprising silicic acid and at least one element selected from the group consisting of rubidium, thallium and cesium;(b) mixing the silicate solution with an acidic aqueous solution, and letting the two solutions react with each other for a period of time sufficient for polymerization to produce a porous gelled product wherein the silica particles are agglomerated;(c) leaching the gelled product with a liquid selected from the group consisting of water, a weakly acidic aqueous solution, an aqueous solution having an alkali metal salt dissolved therein and an aqueous solution of organic matter capable of dissolving Rb.sub.2 O, Cs.sub.2 O, or Tl.sub.2 O, unitl the center of the product starts to dissolve; and(d) drying the leached product in a predetermined atmosphere, and further heating the partially leached gelled product at a temperature sufficiently high to eliminate the particulate material but lower than the melting point of the silica.
    • 公开了一种在产品内部具有预定折射率分布的光学玻璃制品的制造方法。 该方法包括以下步骤:(a)制备含有约0.1至约0.6mol /升包含硅酸的Si(作为SiO 2)和选自铷,铊和铯中的至少一种元素的硅酸盐水溶液 ; (b)将硅酸盐溶液与酸性水溶液混合,并使两种溶液彼此反应一段足以聚合的时间以产生多孔凝胶产物,其中二氧化硅颗粒凝聚; (c)用选自水,弱酸性水溶液,溶解有碱金属盐的水溶液和能够溶解Rb 2 O,Cs 2 O或T 1/2的有机物水溶液的液体浸出凝胶状产品 ,产品中心开始溶解; 和(d)在预定的气氛中干燥浸出的产品,并且在足够高的温度下进一步加热部分浸出的凝胶产品以消除颗粒材料但低于二氧化硅的熔点。
    • 5. 发明授权
    • Single-polarization single-mode optical fiber
    • 单极化单模光纤
    • US4480897A
    • 1984-11-06
    • US388543
    • 1982-06-15
    • Katsunari OkamotoToshihito HosakaYutaka SasakiJuichi NodaTakao Edahiro
    • Katsunari OkamotoToshihito HosakaYutaka SasakiJuichi NodaTakao Edahiro
    • H01P3/16C03B37/012G02B6/024G02B6/10G02B5/172
    • G02B6/105G01L1/242
    • A single-polarization single mode optical fiber of the type comprising an elliptical core, a pair of stress applying parts on both sides of the minor radius of the elliptical core for applying asymmetrical stress thereto and a clad embedding therein the core and the stress applying parts, the stress applying parts being made of B.sub.2 O.sub.3 wherein a relative refractive index difference .DELTA. between the core and the clad satisfies a relation 0.004.ltoreq..DELTA..ltoreq.0.05, an ellipticity .epsilon. satisfies a relation 0.01.ltoreq..epsilon..ltoreq.0.9, the B.sub.2 O.sub.3 has a molar concentration of 1 to 25 mole %, ratio of thickness of the stress applying parts and the core is 5 to 15, a modal birefringence B expressed by an equation B=(.beta..sub.x -.beta..sub.y)/k satisfies a relation B=1.times.10.sup.-6 where (.beta..sub.x -.beta..sub.y) represents a propagation constant difference between HE.sub.11.sup.x and HE.sub.11.sup.y modes, and k a wave number in vacuum, whereby a polarization mode dispersion, that is a delay time difference between the HE.sub.11.sup.x and HE.sub.11.sup.y modes which are orthogonal with each other is zero.
    • 一种单偏振单模光纤,其包括椭圆形芯,用于对其施加不对称应力的椭圆形芯的小半径两侧的一对应力施加部分,以及在其中嵌入芯的包层和应力施加部 应力施加部分由B 2 O 3制成,其中芯和包层之间的相对折射率差ΔTATA满足关系0.004≤ΔTA≤0.05,椭圆度ε满足关系式0.01 =ε= 0.9 ,B2O3的摩尔浓度为1〜25摩尔%,应力施加部和芯的厚度比为5〜15,由式B =(βx-βy)/ k表示的模态双折射B满足 关系B = 1×10 -6其中(βx-βy)表示HE11x和HE11y模式之间的传播常数差异,以及真空中的ka波数,由此偏振模色散是HE11x和HE11y之间的延迟时间差 模式whic h彼此正交为零。
    • 6. 发明授权
    • Core torch for fabricating single-mode optical fiber preforms
    • 用于制造单模光纤预制棒的核心手电筒
    • US4406684A
    • 1983-09-27
    • US386752
    • 1982-06-09
    • Masao KawachiSatoru TomaruTakao EdahiroShoichi Suto
    • Masao KawachiSatoru TomaruTakao EdahiroShoichi Suto
    • C03B37/014C03B19/06
    • C03B37/0144C03B37/014C03B2203/22C03B2203/24C03B2207/04C03B2207/06C03B2207/10C03B2207/16C03B2207/18C03B2207/20C03B2207/42C03B2207/50C03B2207/60C03B2207/64Y02P40/57Y10S65/90
    • A core torch for fabricating a single-mode optical fiber preform wherein fine glass particles are produced eccentrically with respect to the center area of a flame stream, the core torch being so arranged as to blow the flame stream at an angle inclined to a seed rod. The porous glass body forming the core is grown on one end of the rod and in the direction of the axis of the rod. A cladding layer is formed on the periphery of the porous glass core body by at least one torch for forming the cladding. The obtained porous glass body is heated and vitrified into a transparent glass body, which is sealed in a silica tube for jacketting to form a single-mode optical fiber preform. At least one exhaust port is disposed within a distance of 1 mm to 50 mm from the periphery of the porous glass body and in the vicinity of the growing surface of the glass body to exhaust residual glass fine particles and undesired gases. A porous glass body having a diameter of 20 mm or less is easily formed. Single-mode optical fiber having a cladding-to-core-diameter ratio of 3 or more is fabricated by the VAD method. Accordingly, a long-length and low-loss single-mode optical fiber is mass-produced.
    • 一种用于制造单模光纤预制件的核心手电筒,其中相对于火焰流的中心区域产生偏心的细玻璃颗粒,所述芯焊炬布置成以与种子杆倾斜的角度吹动火焰流 。 形成芯的多孔玻璃体在棒的一端和棒的轴线方向上生长。 通过用于形成包层的至少一个焊炬在多孔玻璃芯体的周边上形成包覆层。 将得到的多孔玻璃体加热并玻璃化成透明玻璃体,将其密封在用于夹套的石英管中,形成单模光纤预制棒。 至少一个排气口设置在与多孔玻璃体的周边1mm至50mm的距离内,并且在玻璃体的生长表面附近,以排出残余的玻璃微粒和不期望的气体。 容易形成直径为20mm以下的多孔玻璃体。 通过VAD法制造包芯到芯直径比为3以上的单模光纤。 因此,大批量生产长长度和低损耗的单模光纤。
    • 9. 发明授权
    • Fabrication method of single-mode optical fiber preforms
    • 单模光纤预制棒的制作方法
    • US4345928A
    • 1982-08-24
    • US188914
    • 1980-09-19
    • Masao KawachiSatoru TomaruTakao EdahiroShoichi Suto
    • Masao KawachiSatoru TomaruTakao EdahiroShoichi Suto
    • C03B37/014C03B19/06
    • C03B37/0144C03B37/014C03B2203/22C03B2203/24C03B2207/04C03B2207/06C03B2207/10C03B2207/16C03B2207/18C03B2207/20C03B2207/42C03B2207/50C03B2207/60C03B2207/64Y02P40/57Y10S65/90
    • A method of fabricating a single-mode optical fiber preform wherein a core torch produces fine glass particles eccentrically with respect to the center area of a flame stream, the core torch being so arranged as to blow the flame stream at an angle inclined to a seed rod. The porous glass body forming the core is grown on one end of the rod and in the direction of the axis of the rod. A cladding layer is formed on the periphery of the porous glass core body by at least one torch for forming the cladding. The obtained porous glass body is heated and vitrified into a transparent glass body, which is sealed in a silica tube for jacketting to form a single-mode optical fiber preform. At least one exhaust port is disposed within a distance of 1 mm to 50 mm from the periphery of the porous glass body and in the vicinity of the growing surface of the glass body to exhaust residual glass fine particles and undesired gases. A porous glass body having a diameter of 20 mm or less is easily formed. Single-mode optical fiber having a cladding-to-core-diameter ratio of 3 or more is fabricated by the VAD method. Accordingly, a long-length and low-loss single-mode optical fiber is mass-produced.
    • 一种制造单模光纤预成型件的方法,其中芯焊炬相对于火焰流的中心区域偏心地产生细微的玻璃颗粒,所述芯炬被布置成以与种子倾斜的角度吹动火焰流 竿。 形成芯的多孔玻璃体在棒的一端和棒的轴线方向上生长。 通过用于形成包层的至少一个焊炬在多孔玻璃芯体的周边上形成包覆层。 将得到的多孔玻璃体加热并玻璃化成透明玻璃体,将其密封在用于夹套的石英管中,形成单模光纤预制棒。 至少一个排气口设置在与多孔玻璃体的周边1mm至50mm的距离内,并且在玻璃体的生长表面附近,以排出残余的玻璃微粒和不期望的气体。 容易形成直径为20mm以下的多孔玻璃体。 通过VAD法制造包芯到芯直径比为3以上的单模光纤。 因此,大批量生产长长度和低损耗的单模光纤。