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    • 2. 发明授权
    • Amines or salts thereof and methods of preparing same
    • 胺或其盐及其制备方法
    • US06642404B2
    • 2003-11-04
    • US09828962
    • 2001-04-10
    • Hiroshi KobayashiJin NieTakaaki Sonoda
    • Hiroshi KobayashiJin NieTakaaki Sonoda
    • C07C30300
    • C07C303/34C07C307/02
    • The invention relates to a first compound which is a first amine or a first salt thereof, and to a second compound which is a second amine or a second salt thereof. The first compound has a fluorocarbon sulfonic acid ester group and is represented by a general formula of M[Rf1OSO2NSO2ORf2]n wherein Rf1 and Rf2 represent the same or different fluorine-containing monovalent organic groups. The first amine is prepared by reacting bis(chlorosulfonyl)amine with a fluoroalcohol represented by a general formula of Rf3OH wherein Rf3 represents the same of different groups which are identical with Rf1 and Rf2. The second compound has a fluorocarbon sulfonic acid ester group and is represented by a general formula of —[M[N—SO2ORf4OSO2]n]m— wherein Rf4 represents a fluorine-containing bivalent organic group. The second amine is prepared by reacting bis(chlorosulfonyl)amine with a fluorodiol represented by a general formula of HORf5OH wherein Rf5 represents a bivalent organic group which is identical with Rf4. The first and second salts are respectively prepared by reacting the first and second amines with a compound selected from ammonia, quaternary ammonium compounds, hydroxides of, oxides of, carbonates of, halides of, fluorides of, chlorides of, bromides of, iodides of, and acetates of particular elements. The first and second compounds are fully expected to be usable as catalyst and the like, in the synthesis of organic compounds.
    • 本发明涉及第一种化合物,它是第一种胺或其第一种盐,第二种化合物是第二种胺或其第二种盐。 第一种化合物具有氟碳磺酸酯基并由通式M [Rf 1 OSO 2 NO 2 O 2] n表示,其中Rf 1和Rf 2表示相同或不同的含氟一价有机基团 团体 通过使双(氯磺酰基)胺与由通式Rf 3 OH表示的氟代醇反应制备第一种胺,其中Rf 3代表与Rf 1和Rf 2相同的不同基团, 。 第二化合物具有碳氟化合物磺酸酯基,由通式 - [M [N-SO 2 OR f 4 OSO 2] n] m - 表示,其中Rf 4表示含氟二价有机基团。 第二种胺通过双(氯磺酰基)胺与通式为HORf 5 OH表示的氟代二醇反应制备,其中Rf 5表示与Rf 4相同的二价有机基团。 第一和第二盐分别通过使第一和第二胺与选自下列化合物的化合物反应制备:氨,季铵化合物,氟化物的卤化物,氟化物的卤化物,碘化物的碘化物, 和特定元素的醋酸盐。 在有机化合物的合成中,第一种和第二种化合物完全可以用作催化剂等。