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1. 发明授权

US5770301A Barrier composite films and a method for producing the same 失效
标题翻译：阻隔复合膜及其制造方法
公开(公告)号：US5770301A
公开(公告)日：1998-06-23
申请号：US732226
申请日：1996-10-25
申请人： Takaaki Murai , Ryuta Miyake
发明人： Takaaki Murai , Ryuta Miyake
IPC分类号： B32B27/08 , B32B27/16 , C08J7/04 , B32B27/32 , B32B27/34 , B32B27/36
CPC分类号： C08J7/045 , B32B27/08 , B32B27/16 , Y10T428/2495 , Y10T428/24967 , Y10T428/24975 , Y10T428/31663 , Y10T428/31667
摘要： At least one side of a polyester or other base film is successively covered with an inorganic layer composed of a silicon oxide or the like and a coating layer comprising a silane coupling agent and a barrier resin (e.g. vinylidene chloride-based copolymer, ethylene-vinyl alcohol copolymer) to provide a barrier composite film. The amount of the silane coupling agent is about 0.05 to 10 parts by weight relative to 100 parts by weight of the barrier resin. A heat-sealing layer is optionally formed on the surface of the barrier resin coating layer or on the other side of the base film. Such barrier composite film has excellent transparency and retains high barrier properties and adhesive properties of covering layer despite its thin covering layer.
摘要翻译： PCT No.PCT / JP96 / 00614 Sec。 371日期1996年10月25日第 102（e）日期1996年10月25日PCT 1996年3月13日PCT公布。出版物WO96 / 28299 日期1996年9月19日聚酯或其他基膜的至少一面依次被由氧化硅等构成的无机层和包含硅烷偶联剂和阻隔树脂（例如偏二氯乙烯基共聚物，乙烯 - 乙烯醇共聚物）以提供阻隔复合膜。相对于100重量份的阻隔树脂，硅烷偶联剂的量为约0.05至10重量份。可选地，在隔离树脂涂层的表面或基膜的另一侧上形成热封层。这种阻隔复合膜具有优异的透明性，并且尽管其覆盖层薄，但仍具有高覆盖层的阻隔性和粘合性。

2. 发明授权

US4841017A Polyether compounds, epoxy resins and processes for production thereof 失效
标题翻译：聚醚化合物，环氧树脂及其生产方法
公开(公告)号：US4841017A
公开(公告)日：1989-06-20
申请号：US167680
申请日：1988-03-11
申请人： Takaaki Murai , Katsuhisa Sakai
发明人： Takaaki Murai , Katsuhisa Sakai
IPC分类号： C08G59/02 , C08G59/34 , C08G65/14
CPC分类号： C08G59/027 , C08G59/02 , C08G65/14
摘要： Disclosed as a polyether compound having ether groups and vinyl double bonds represented by formula (I) ##STR1## and an epoxy resin represented by formula (II) ##STR2## wherein R.sup.1 represents a residue group of an organic compound having l active hydrogen atoms, n1 through nl each represents 0 or an integer of from 1 to 100, the sum of integers represented by n1 through nl is from 1 to 100, and l represents an integer of from 1 to 100, and A represents from 1 to 100, and A represents ##STR3## or a mixture of ##STR4## wherein R.sup.2 represents a residue group of mono epoxy compound, and B represents ##STR5## or a mixture of ##STR6## wherein X represents a ##STR7## group, wherein R.sup.3 represents a hydrogen atom, an alkyl group, an alkyl carbonyl group, or an arylcarbonyl group, provided that the epoxy resin represented by formula (II) contains at least one ##STR8## group: In a further aspect, the invention relates to processes for production thereof.

3. 发明授权

US5510428A Compositions, epoxized compositions, a heat curable resin composition, an epoxy resin composition, radically polymerized compositions, a curable resin composition and a polymer having epoxy groups 失效
标题翻译：组合物，环氧化合物，热固性树脂组合物，环氧树脂组合物，自由基聚合组合物，固化性树脂组合物和具有环氧基的聚合物
公开(公告)号：US5510428A
公开(公告)日：1996-04-23
申请号：US342633
申请日：1994-11-21
申请人： Yoshiyuki Harano , Sozo Namai , Katsuyuki Maeda , Takaaki Murai
发明人： Yoshiyuki Harano , Sozo Namai , Katsuyuki Maeda , Takaaki Murai
IPC分类号： C08G59/34 , C08G59/68 , C08G63/58 , C08G63/91 , C08G65/14 , C08G65/26 , C09D163/00 , C09D167/00 , C08F20/00 , C07D301/14
CPC分类号： C08G59/027 , C08G59/68 , C08G63/58 , C08G63/918 , C08G65/14 , C08G65/2615 , C09D163/00 , C09D167/00 , Y10S525/922
摘要： Compositions (I), (II) and (III) comprising compounds having vinyl groups as side chains and epoxidized compositions (XI), (XII) and (XIII) thereof, which can be prepared by the various reaction combinations of (a) with (b) or (b)+(c), and or (d), where(a) is at least one compound having at least one vinyl group and one epoxy group in the molecule; (b) is at least one of a polybasic compound, an anhydride thereof, a polymer having carboxylic groups at terminals and a polymer having carboxylic groups as side chains; (c) is at least one organic compound having at least one active hydrogen atom; and (d) is at east one of an unsaturated monocarboxylic compound or an unsaturated monocarboxylic ester having a hydroxyl group.
摘要翻译：包含具有乙烯基作为侧链和环氧化组合物（XI），（XII）和（XIII））的化合物（I），（II）和（III）），其可以通过（a）与（b）或（b）+（c）和（d），其中（a）是至少一种在分子中具有至少一个乙烯基和一个环氧基的化合物; （b）是多元化合物，其酸酐，末端具有羧基的聚合物和具有羧基作为侧链的聚合物中的至少一种; （c）是至少一种具有至少一个活性氢原子的有机化合物; 和（d）在不饱和单羧酸化合物或具有羟基的不饱和单羧酸酯的东侧。

4. 发明授权

US4663429A Process for producing lactone polymer and an anti-shrinking thermosetting resin composition having formulated therein said lactone polymer as an anti-shrinking agent 失效
标题翻译：制备内酯聚合物的方法和其中配制有所述内酯聚合物作为抗收缩剂的抗收缩热固性树脂组合物
公开(公告)号：US4663429A
公开(公告)日：1987-05-05
申请号：US760782
申请日：1985-07-31
申请人： Takaaki Murai , Shoji Watanabe , Kimio Inoue , Tomohisa Isobe , Naoki Nakashima , Takuya Miho , Yoshiyuki Ikemoto
发明人： Takaaki Murai , Shoji Watanabe , Kimio Inoue , Tomohisa Isobe , Naoki Nakashima , Takuya Miho , Yoshiyuki Ikemoto
IPC分类号： C08G63/60 , C08L67/06 , C08G63/10
CPC分类号： C08G63/60 , C08L67/06
摘要： A process for producing a lactone polymer which comprises reacting an ester compound synthesized from an alcohol and an acid or acid anhydride thereof with a lactone and a ring-opening polymerization initiator without being accompanied by condensation. The thus produced lactone polymer is effective for preventing shrinkage of thermosetting resins, particularly unsaturated polyester resins.
摘要翻译：一种内酯聚合物的制备方法，其包括使由醇和其酸或酸酐合成的酯化合物与内酯和开环聚合引发剂反应而不伴随冷凝。由此制得的内酯聚合物对于防止热固性树脂，特别是不饱和聚酯树脂的收缩是有效的。

5. 发明授权

US5942320A Barrier composite films and a method for producing the same 失效
标题翻译：阻隔复合膜及其制造方法
公开(公告)号：US5942320A
公开(公告)日：1999-08-24
申请号：US917345
申请日：1997-08-26
申请人： Ryuta Miyake , Takaaki Murai
发明人： Ryuta Miyake , Takaaki Murai
IPC分类号： B65D81/34 , B05D7/04 , B05D7/24 , B29D7/01 , B32B9/00 , B32B27/30 , B65D65/40 , C08J7/04 , C08J7/06 , B32B27/32 , B32B27/34 , B32B27/36
CPC分类号： C08J7/045 , Y10T428/2495 , Y10T428/24967 , Y10T428/24975 , Y10T428/265 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31598 , Y10T428/31667
摘要： A barrier composite film comprises a base film, an anchor coat layer, an inorganic layer such as a silicon oxide layer, and a coating layer containing a silane coupling agent and a barrier resin (e.g. a vinylidene chloride-series copolymer, an ethylene-vinyl alcohol copolymer), the layers being formed on at least one side of the base film in the order of reference. The anchor coat layer can be made of (A) a chlorine-containing resin such as a vinyl chloride-vinyl acetate copolymer, (B) a polyisocyanate compound, and (C) a saturated polyester resin having a glass transition temperature of -10.degree. C. to 20.degree. C. and being substantially unreactive to the component (B). A heat-sealing layer may be formed on the surface of the coating layer or the other side of the base film. This composite film provided with the inorganic layer can avoid a loss of its adhesive properties and barrier properties even under severe conditions such as retort treatment.
摘要翻译：阻挡复合膜包括基膜，锚涂层，无机层如氧化硅层，以及包含硅烷偶联剂和阻隔树脂的涂层（例如偏二氯乙烯系共聚物，乙烯 - 乙烯基醇共聚物），所述层在基膜的至少一侧上以参考顺序形成。锚固涂层可以由（A）氯乙烯 - 乙酸乙烯酯共聚物等含氯树脂，（B）多异氰酸酯化合物，（C）玻璃化转变温度为-10℃的饱和聚酯树脂 C至20℃，并且对组分（B）基本上不反应。可以在涂层的表面或基膜的另一侧上形成热封层。具有无机层的复合膜即使在诸如蒸馏处理的苛刻条件下也可以避免其粘合性能和阻隔性能的损失。

6. 发明授权

US5853862A Barrier composite films and method of producing the same 失效
标题翻译：阻隔复合膜及其制备方法
公开(公告)号：US5853862A
公开(公告)日：1998-12-29
申请号：US737557
申请日：1996-11-12
申请人： Takaaki Murai , Ryuta Miyake
发明人： Takaaki Murai , Ryuta Miyake
IPC分类号： B32B27/06 , B32B27/08 , C08J7/04 , C23C14/02 , B32B15/08
CPC分类号： C08J7/045 , B32B27/06 , B32B27/08 , C08J7/047 , C23C14/024 , C08J2427/00 , Y10T428/24967 , Y10T428/24975 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31667 , Y10T428/31681
摘要： At least one side of a base film is successively covered with an anchor coat layer comprising (A) a chlorine-containing resin e.g. a vinyl chloride-vinyl acetate copolymer, (B) a polyisocyanate compound and (C) a saturated polyester resin having glass transition temperature of -10.degree. C. to 20.degree. C. and being substantially unreactive to the polyisocyanate compound, and an inorganic layer such as a silicon oxide. The component (C) includes a noncrystalline saturated polyesters each having a hydroxyl value of 0 to 15 mg KOH/g or acid value of 0 to 10 mg KOH/g. The anchor coat layer may comprise about 10 to 500 parts by weight of the component (B) and 1 to 50 parts by weight of the component (C) relative to 100 parts by weight of the component (A). Such composite film inhibits deterioration of the adhesive properties and barrier properties even when exposed to severe conditions such as retort treatment.
摘要翻译： PCT No.PCT / JP96 / 00990 Sec。 371日期：1996年11月12日 102（e）日期1996年11月12日PCT 1996年4月11日PCT PCT。出版物WO96 / 32253 日期1996年10月17日基底膜的至少一面依次被覆盖着包覆层（A）含氯树脂，例如，氯乙烯 - 乙酸乙烯酯共聚物，（B）多异氰酸酯化合物和（C）具有玻璃化转变温度为-10℃至20℃并且对多异氰酸酯化合物基本上不反应的饱和聚酯树脂，以及无机层例如氧化硅。组分（C）包括各自具有0至15mg KOH / g的羟值或0至10mg KOH / g的酸值的非结晶饱和聚酯。相对于100重量份的组分（A），锚涂层可以包含约10至500重量份的组分（B）和1至50重量份的组分（C）。这种复合膜即使在苛刻条件如蒸煮处理时也能抑制粘合性能和阻隔性能的劣化。

7. 发明授权

US4835213A Process for producing lactone polymer and an anti-shrinking thermosetting resin composition having formulated therein said lactone polymer as an anti-shrinking agent 失效
标题翻译：制备内酯聚合物的方法和其中配制有所述内酯聚合物作为抗收缩剂的抗收缩热固性树脂组合物
公开(公告)号：US4835213A
公开(公告)日：1989-05-30
申请号：US19166
申请日：1987-02-26
申请人： Takaaki Murai , Shoji Watanabe , Kimio Inoue , Tomohisa Isobe , Naoki Nakashima , Takuya Miho , Yoshiyuki Ikemoto
发明人： Takaaki Murai , Shoji Watanabe , Kimio Inoue , Tomohisa Isobe , Naoki Nakashima , Takuya Miho , Yoshiyuki Ikemoto
IPC分类号： C08G63/60 , C08L67/06
CPC分类号： C08G63/60 , C08L67/06
摘要： A process for producing a lactone polymer which comprises reacting an ester compound synthesized from an alcohol and an acid or acid anhydride thereof with a lactone and a ring-opening polymerization initiator without being accompanied by condensation. The thus produced lactone polymer is effective for preventing shrinkage of thermosetting resins, particularly unsaturated polyester resins.
摘要翻译：一种内酯聚合物的制备方法，其包括使由醇和其酸或酸酐合成的酯化合物与内酯和开环聚合引发剂反应而不伴随冷凝。由此制得的内酯聚合物对于防止热固性树脂，特别是不饱和聚酯树脂的收缩是有效的。

8. 发明授权

US4565859A Polyether compounds, epoxy resins, epoxy resin compositions, and processes for production thereof 失效
标题翻译：聚醚化合物，环氧树脂，环氧树脂组合物及其生产方法
公开(公告)号：US4565859A
公开(公告)日：1986-01-21
申请号：US696239
申请日：1985-01-29
申请人： Takaaki Murai , Shoji Watanabe , Kimio Inoue , Toyokazu Yagii
发明人： Takaaki Murai , Shoji Watanabe , Kimio Inoue , Toyokazu Yagii
IPC分类号： C08G59/02 , C08G59/34 , C08G65/14 , C08G65/26 , C08G65/332 , C08G59/42
CPC分类号： C08G59/027 , C08G59/02 , C08G65/14 , C08G65/26 , C08G65/3322
摘要： A polyether compound having ether groups and vinyl double bonds represented by formula (I) ##STR1## wherein R.sub.1 represents a residue of an organic compound having l active hydrogen atoms, n.sub.1 through n.sub.l each represents 0 or an integer of from 1 to 100, the sum of the integers represented by n.sub.1 through n.sub.l is from 1 to 100, andl represents an integer of from 1 to 100, and A represents ##STR2## and a process for production thereof; an epoxy resin represented by formula (II) ##STR3## wherein R.sub.1 and n.sub.1 through n.sub.l are defined above, and B is an oxycyclohexane unit having a substituent and is represented by formula (III) ##STR4## wherein X represents a ##STR5## --CH.dbd.CH.sub.2, or ##STR6## groups, wherein R.sub.2 represents an alkyl group, an alkylcarbonyl group, or an arylcarbonyl group, provided that the epoxy resin represented by formula (II) contains at least one ##STR7## group, and a process for production thereof; and an epoxy resin comprising an epoxy resin as in formula (II), are disclosed.
摘要翻译：具有由式（I）表示的醚基和乙烯基双键的聚醚化合物其中R 1表示具有1个活性氢原子的有机化合物的残基，n1至n1各自表示0或1〜 100，由n1〜n1表示的整数的和为1〜100，l表示1〜100的整数，A表示其生成方法。（II）表示的环氧树脂其中R1和n1至n1如上定义，B是具有取代基的氧代环己烷单元，由式（III）表示。其中X 表示式（II）表示的环氧树脂包含至少一个“IMA”> -CH = CH 2或基团，其中R 2表示烷基，烷基羰基或芳基羰基，组及其生产方法; 和包含式（II）中的环氧树脂的环氧树脂。

9. 发明授权

US4475998A Modified epoxy (meth) acrylate resin and hardenable resin composition containing the same 失效
标题翻译：改性环氧（甲基）丙烯酸酯树脂和含有它的可硬化树脂组合物
公开(公告)号：US4475998A
公开(公告)日：1984-10-09
申请号：US534863
申请日：1983-09-22
申请人： Kiyoshi Okitsu , Takaaki Murai
发明人： Kiyoshi Okitsu , Takaaki Murai
IPC分类号： C08F299/02 , C08G59/14 , C08G59/62 , C08G63/08 , C08F8/00 , C08G59/40
CPC分类号： C08F299/026 , C08G59/1494 , C08G59/625 , C08G59/626
摘要： A lactone-modified epoxy (meth)acrylate resin is disclosed as is a hardenable resin composition which includes the lactone-modified epoxy resin. The lactone-modified epoxy (meth)acrylate resin is obtained by addition polymerizing 3 to 95 parts by weight of a lactone to 97 to 5 parts by weight of an epoxy (meth)acrylate resin at the whole or a part of the secondary hydroxy groups thereof. The hardenable resin composition comprises (A) 5 to 95 parts by weight of the above referred to lactone-modified epoxy (meth)acrylate resin, (B) 95 to 5 parts by weight of a vinyl compound having an ethylenically unsaturated bond, and (C) 0 to 10 parts by weight of a photosensitizer.
摘要翻译：公开了内酯改性的环氧（甲基）丙烯酸酯树脂作为包含内酯改性环氧树脂的可硬化树脂组合物。内酯改性的环氧（甲基）丙烯酸酯树脂通过将3〜95重量份的内酯加成聚合至全部或部分仲羟基的97〜5重量份的环氧（甲基）丙烯酸酯树脂而得到其中。可硬化树脂组合物包含（A）5-95重量份上述内酯改性的环氧（甲基）丙烯酸酯树脂，（B）95-5重量份具有烯属不饱和键的乙烯基化合物和（ C）0至10重量份的光敏剂。

10. 发明授权

US5143997A Polycarbonate-polyol composition and polycarbonate(meth) acrylate compositions and urethane(meth) acrylate compositions prepared therefrom 失效
标题翻译：聚碳酸酯 - 多元醇组合物和聚碳酸酯（甲基）丙烯酸酯组合物和URETHANE（METH）丙烯酸酯组合物
公开(公告)号：US5143997A
公开(公告)日：1992-09-01
申请号：US595423
申请日：1990-10-11
申请人： Toshio Endo , Takaaki Murai , Tatsumi Fujii
发明人： Toshio Endo , Takaaki Murai , Tatsumi Fujii
IPC分类号： C08F299/02 , C08G18/44 , C08G18/81 , C08G64/02
CPC分类号： C08G64/0291 , C08F299/024 , C08G18/44 , C08G18/8175 , C08G64/0216
摘要： A polycarbonate polyol composition which can be used to prepare polycarbonate(meth)acrylate and urethane(meth)acrylate compositions is obtained by the ester interchange reaction of a polycarbonate diol composition with a triol and/or tetraol. The (meth)acrylate compositions have excellent photo and electron beam curability and the cured layers prepared therefrom have excellent heat resistance under moisture conditions.

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