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    • 3. 发明申请
    • Solid oxide fuel cell having a supported electrolyte film
    • 具有负极电解质膜的固体氧化物燃料电池
    • US20020048701A1
    • 2002-04-25
    • US09983056
    • 2001-10-23
    • Toho Gas Co. Ltd.
    • Kenji UkaiYasunobu Mizutani
    • H01M008/12H01M004/86
    • C04B35/486H01M8/1231H01M8/1246H01M2300/0094Y02E60/525Y02P70/56
    • The present invention intends to provide a solid oxide fuel cell having a supported electrolyte film, which shows sufficiently high reliability, yields a high output, and exhibits high output power density per unit volume. The present invention is characterized by use of a first cermet comprising catalyst and a second solid electrolyte, which has a bending strength of more than 500 MPa and exhibits oxide ion conductivity, for a fuel electrode substrate in an SOFC having a supported electrolyte film equipped with an electrolyte-electrode assembly that is made by bonding the fuel electrode substrate and an air electrode on both sides of an electrolyte film consisting of the first solid electrolyte capable of exhibiting oxide ion conductivity. As a preferred embodiment, stabilized zirconia containing 2 to 4 mol % yttria or 3 to 6 mol % scandia is preferred for the second solid electrolyte. More particularly, an interlayer comprising the second catalyst and the third solid electrolyte, which shows oxide ion conductivity of more than 0.1 S/cm at 800null C., is preferably interposed between the electrolyte film and the fuel electrode substrate.
    • 本发明提供一种具有负极电解质膜的固体氧化物型燃料电池,其显示出足够高的可靠性,产生高的输出,并表现出高的每单位体积的输出功率密度。 本发明的特征在于,在具有负载电解质膜的SOFC中,使用包含催化剂和第二固体电解质的第一金属陶瓷,所述第一金属陶瓷具有大于500MPa的弯曲强度并具有氧化物离子传导性, 电解质电极组件,其通过将燃料电极基板和由能够显示氧化物离子传导性的第一固体电解质构成的电解质膜的两侧的空气电极接合而制成。 作为优选实施方案,对于第二固体电解质,优选含有2至4mol%氧化钇或3至6mol%Scandia的稳定的氧化锆。 更具体地说,包含第二催化剂和第三固体电解质的中间层优选介于电解质膜和燃料电极基板之间,其在800℃下显示大于0.1S / cm的氧离子电导率。
    • 7. 发明申请
    • Single cell for a solid oxide fuel cell
    • 用于固体氧化物燃料电池的单电池
    • US20040072060A1
    • 2004-04-15
    • US10619315
    • 2003-07-14
    • Toho Gas Co., Ltd.
    • Kenji UkaiKouji Hisada
    • H01M004/90H01M004/86H01M008/12
    • H01M8/1213H01M2300/0068Y02P70/56
    • A single cell for a solid oxide fuel cell and a solid oxide fuel cell using the same practicable and excellent in generation performance and durability, wherein a fuel electrode including a cermet of a catalyst and a second solid electrolyte with oxide ion conductivity at 1000null C. of 0.20 S/cm or more is bonded to one side of a solid electrolyte plate with the conductivity of 0.07 S/cm or more and bending strength of 700 MPa or more, and an air electrode including a compound of perovskite type transition metal oxide with a third solid electrolyte is bonded to the other side. A surface of the fuel electrode is coated with a layer, and an air electrode surface is coated with a layer, and an aqueous solution where a noble metal compound is dissolved in water is impregnated into the air electrode.
    • 用于固体氧化物燃料电池的单电池和固体氧化物燃料电池,其具有可行且优异的发电性能和耐久性的固体氧化物燃料电池,其中包括催化剂金属陶瓷的燃料电极和在1000℃下具有氧化物离子传导性的第二固体电解质 0.20S / cm以上的导电率粘合到固体电解质板的一侧,导电率为0.07S / cm以上,弯曲强度为700MPa以上,空气电极包含钙钛矿型过渡金属氧化物 第三固体电解质结合到另一侧。 燃料电极的表面涂覆有层,空气电极表面涂覆有层,并且将含有贵金属化合物的水溶液浸渍在空气电极中。
    • 8. 发明申请
    • Solid oxide fuel cell
    • 固体氧化物燃料电池
    • US20020076603A1
    • 2002-06-20
    • US09982971
    • 2001-10-22
    • TOHO GAS CO., LTD.
    • Kenji UkaiYasunobu Mizutani
    • H01M004/86H01M008/12
    • C04B35/486H01M8/0625H01M8/1231H01M8/124H01M2300/0094Y02P70/56
    • A solid oxide fuel cell in which the catalytic activity of a fuel electrode is high and in which no poisoning by carbon occurs even when internal reforming is performed under a condition of a low S/C ratio and further in which the time course degradation of the fuel electrode is less when internal reforming is performed. In a solid oxide fuel cell having an oxide ion conductive solid electrolyte, and a fuel electrode and an air electrode connected to both faces thereof, a cermet of a catalyst and of the second solid electrolyte whose oxide ion conductivity is more than or equal to 0.2 S/cm at 1000null C. is used as the fuel electrode. More specifically, it is desirable that the second solid electrolyte is scandia-stabilized zirconia (ScSZ) containing 9 to 12 mol % of scandia. In addition, the second solid electrolyte may further be ScSZ containing yttria or ceria less than or equal to 2 mol %. Furthermore, the second solid electrolyte may be a composite material of ScSZ and alumina less than or equal to 2 wt %.
    • 即使在S / C比低的条件下进行内部重整也可以使燃料电极的催化活性高,即使不产生中毒的固体氧化物型燃料电池, 当进行内部重整时,燃料电极较少。 在具有氧化物离子传导性固体电解质的固体氧化物型燃料电池和与其两面连接的燃料电极和空气电极中,氧化物离子传导率为0.2以上的催化剂和第二固态电解质的金属陶瓷 在1000℃下使用S / cm作为燃料电极。 更具体地说,希望第二固体电解质是含有9〜12摩尔%的猩红的氧化钪稳定的氧化锆(ScSZ)。 此外,第二固体电解质还可以是含有少于或等于2摩尔%的氧化钇或二氧化铈的ScSZ。 此外,第二固体电解质可以是ScSZ和氧化铝的复合材料小于或等于2重量%。