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1. 发明申请

WO2011011036A1 COATED ARTICLE WITH SPUTTER-DEPOSITED TRANSPARENT CONDUCTIVE COATING FOR REFRIGERATION/FREEZER UNITS, AND METHOD OF MAKING THE SAME 审中-公开
标题翻译：用于制冷/冷冻单元的具有溅射沉积透明导电涂层的涂覆制品及其制备方法
公开(公告)号：WO2011011036A1
公开(公告)日：2011-01-27
申请号：PCT/US2010001793
申请日：2010-06-22
申请人： GUADIAN IND CORP , THOMSEN SCOTT V , LAO JINGYU , O'CONNOR KEVIN
发明人： THOMSEN SCOTT V , LAO JINGYU , O'CONNOR KEVIN
IPC分类号： C03C23/00 , C03C17/36 , F25D23/02
CPC分类号： C03C17/36 , C03C17/3626 , C03C17/3644 , C03C17/3652 , C03C17/3655 , C03C2217/78 , F24C15/04 , F25D21/04 , F25D21/08 , Y10T428/12549
摘要： Certain example embodiments relate to sputter-deposited transparent conductive coatings (TCCs) for use in, for example, refrigeration and/or freezer units (e.g., as doors, windows, etc.). The TCC may include a silver-based conductive layer, at least partially protected by a zirconium oxide overcoat. Such TCCs may be provided in connection with monolithic or multi-substrate arrangements in different example embodiments. Certain example embodiments may involve "active" modes, where a silver-based layer in the TCC may receive a voltage, e.g., to reduce the likelihood of frosting, freezing, fogging, condensation, and/or the like, on the glass substrate that supports the TCC.
摘要翻译：某些示例实施例涉及用于例如制冷和/或冷冻单元（例如门，窗等）中的溅射沉积的透明导电涂层（TCC）。 TCC可以包括至少部分地被氧化锆外涂层保护的银基导电层。在不同示例实施例中可以结合单片或多基片布置提供这种TCC。某些示例性实施例可以涉及“有源”模式，其中TCC中的银基层可以接收电压以例如在玻璃基板上降低结霜，冻结，雾化，凝聚等的可能性，支持TCC。

2. 发明申请

WO2010045041A2 METHOD OF MAKING FRONT ELECTRODE OF PHOTOVOLTAIC DEVICE HAVING ETCHED SURFACE AND CORRESPONDING PHOTOVOLTAIC DEVICE 审中-公开
标题翻译：具有蚀刻表面和相应光伏器件的光电器件的正面电极的制造方法
公开(公告)号：WO2010045041A2
公开(公告)日：2010-04-22
申请号：PCT/US2009059478
申请日：2009-10-05
申请人： GUARDIAN INDUSTRIES , KRASNOV ALEXEY , LU YIWEI , THOMSEN SCOTT V
发明人： KRASNOV ALEXEY , LU YIWEI , THOMSEN SCOTT V
IPC分类号： H01L31/18 , H01L31/0224 , H01L31/0236
CPC分类号： H01L31/1884 , H01L31/022466 , H01L31/0236 , Y02E10/50
摘要： Certain example embodiments of this invention relate to a photovoltaic (PV) device including an electrode such as a front electrode/contact, and a method of making the same. In certain example embodiments, the front electrode has a textured (e.g., etched) surface that faces the photovoltaic semiconductor film of the PV device. The front electrode has a transparent conductive oxide (TCO) film having first and second layers (continuous or discontinuous) of the same material (e.g., zinc oxide, zinc aluminum oxide, indium-tin-oxide, or tin oxide), where the first TCO layer is sputter-deposited using a ceramic sputtering target(s) and the second TCO layer of the same material is sputter-deposited using a metallic or substantially metallic sputtering target(s). This allows the better quality TCO of the film, deposited more slowly via the ceramic target(s), to be formed using the ceramic target and the lesser quality TCO of the film to be deposited more quickly and cost effectively via the metallic target(s). After the etching, most or all of the better quality ceramic-deposited TCO remains whereas much of the lesser quality metallic-deposited TCO of the film was removed during the etching process.
摘要翻译：本发明的某些示例性实施例涉及包括诸如前电极/触点的电极的光伏（PV）装置及其制造方法。在某些示例性实施例中，前电极具有面向PV器件的光电半导体膜的有纹理（例如蚀刻）的表面。前电极具有透明导电氧化物（TCO）膜，其具有相同材料（例如氧化锌，氧化锌铝，氧化铟锡或氧化锡）的第一和第二层（连续或不连续），其中第一使用陶瓷溅射靶溅射沉积TCO层，并且使用金属或基本上金属的溅射靶溅射沉积相同材料的第二TCO层。这允许通过使用陶瓷靶材形成的通过陶瓷靶材更缓慢地沉积的膜的更好的质量TCO，并且通过金属靶材更快速且成本有效地沉积的膜的质量较差的TCO（s ）。在蚀刻之后，大部分或全部较好质量的陶瓷沉积的TCO保留，而在蚀刻过程中除去较薄质量的金属沉积的TCO。

3. 发明申请

WO2009051625A1 METHOD OF MAKING AN ANTIREFLECTIVE SILICA COATING, RESULTING PRODUCT, AND PHOTOVOLTAIC DEVICE COMPRISING SAME 审中-公开
标题翻译：制备抗反射性二氧化硅涂层，结果产品和包含其的光伏器件的方法
公开(公告)号：WO2009051625A1
公开(公告)日：2009-04-23
申请号：PCT/US2008/010071
申请日：2008-08-26
申请人： GUARDIAN INDUSTRIES CORP. , SHARMA, Pramod, K. , MELLOTT, Nathan, P. , VARAPRASAD, Desaraju, V. , LU, Yiwei , THOMSEN, Scott, V.
发明人： SHARMA, Pramod, K. , MELLOTT, Nathan, P. , VARAPRASAD, Desaraju, V. , LU, Yiwei , THOMSEN, Scott, V.
IPC分类号： C03C17/00 , G02B1/11 , H01L31/0216
CPC分类号： C03C17/3417 , C03C17/23 , C03C17/3458 , C03C2217/213 , C03C2217/734 , C03C2218/113 , C03C2218/365 , G02B1/113 , H01L31/02168 , H01L31/0392 , Y02E10/50 , Y10T428/31612
摘要： A low-index silica coating may be made by forming silica sol including a silane and/or a colloidal silica. The silica precursor may be deposited on a substrate (e.g., glass substrate) to form a coating layer. The coating layer may then be cured and/or fired using temperature(s) of from about 550 to 700°C. A barrier undercoating including a metal oxide, such as, silica, alumina, titania, zirconia, and/or an oxynitride of silica may be deposited between the coating layer and substrate. Preferably, the barrier undercoating does not substantially affect the percent transmission or reflection of the low-index silica coating. The low-index silica based coating may be used as an antireflective (AR) film on a front glass substrate of a photovoltaic device (e.g., solar cell) or any other suitable application in certain example instances.
摘要翻译：可以通过形成包括硅烷和/或胶体二氧化硅的二氧化硅溶胶来制备低折射率二氧化硅涂层。可以将二氧化硅前体沉积在基底（例如玻璃基底）上以形成涂层。然后可以使用约550-700℃的温度来固化和/或烧制涂层。可以在涂层和基材之间沉积包括二氧化硅，氧化铝，二氧化钛，氧化锆和/或氧化硅的金属氧化物的屏障底涂层。优选地，阻挡层底涂层基本上不影响低折射率二氧化硅涂层的透射率或反射率。低折射率二氧化硅基涂层可以在某些示例情况下用作光伏器件（例如，太阳能电池）的前玻璃基板上的抗反射（AR）膜或任何其它合适的应用。

4. 发明申请

WO2006057829A3 SCRATCH RESISTANT COATED ARTICLE AND METHOD OF MAKING 审中-公开
标题翻译：防刮涂层制品及其制造方法
公开(公告)号：WO2006057829A3
公开(公告)日：2007-11-22
申请号：PCT/US2005040974
申请日：2005-11-14
申请人： GUARDIAN INDUSTRIES , THOMSEN SCOTT V , PETRMICHL RUDOLPH HUGO , MURPHY NESTOR P , VEERASAMY VIJAYEN S
发明人： THOMSEN SCOTT V , PETRMICHL RUDOLPH HUGO , MURPHY NESTOR P , VEERASAMY VIJAYEN S
IPC分类号： C23C16/40 , B05D3/00 , B32B9/00 , C03C17/22 , C03C17/23 , C03C17/34 , C08J7/18 , C23C14/00 , C23C14/02 , C23C14/08 , C23C14/32 , C23C14/58 , C23C16/00 , C23C16/26 , G21H5/00 , H01L21/4763
CPC分类号： C23C14/06 , C03C17/22 , C03C17/225 , C03C17/23 , C03C17/245 , C03C17/2453 , C03C17/3417 , C03C17/3435 , C03C17/3441 , C03C17/3452 , C03C2217/215 , C03C2217/218 , C03C2217/228 , C03C2217/281 , C03C2217/282 , C03C2217/285 , C03C2218/15 , C03C2218/154 , C23C14/024 , C23C14/0635 , C23C14/08 , C23C14/086 , C23C14/58 , Y10T428/265 , Y10T428/30 , Y10T428/31612
摘要： A scratch resistant coated article is provided which is also resistant to attacks by at least some fluoride-based etchant(s) for at least a period of time. In certain example embodiments, an anti-etch layer(s) is provided on a glass substrate in order to protect the glass substrate from attacks by fluoride-based etchant(s), and an underlayer(s) deposited by flame pyrolysis may be provided under at least the anti-etch layer(s).
摘要翻译：提供了耐刮擦涂层制品，其还耐受至少一些基于氟化物的蚀刻剂至少一段时间的攻击。在某些示例性实施例中，在玻璃基板上提供防蚀刻层，以便保护玻璃基板免受基于氟化物的蚀刻剂的攻击，并且可以提供通过火焰热解沉积的底层在至少一个或多个抗蚀刻层之下。

5. 发明申请

WO2007106223A1 LOW IRON HIGH TRANSMISSION FLOAT GLASS FOR SOLAR CELL APPLICATIONS AND METHOD OF MAKING SAME 审中-公开
标题翻译：用于太阳能电池应用的低铁高透射率玻璃及其制造方法
公开(公告)号：WO2007106223A1
公开(公告)日：2007-09-20
申请号：PCT/US2007/001565
申请日：2007-01-22
申请人： GUARDIAN INDUSTRIES CORP. , THOMSEN, Scott, V. , HULME, Richard , LANDA, Leonid, M.
发明人： THOMSEN, Scott, V. , HULME, Richard , LANDA, Leonid, M.
IPC分类号： C03C3/087 , C03C4/10 , H01L25/04
CPC分类号： C03C3/087 , C03C4/0092 , C03C4/10 , C03C17/36 , C03C17/3678 , C03C2217/944 , H01L31/02366 , H01L31/03921 , Y02E10/50
摘要： Certain example embodiments of this invention relate to a high transmission low iron glass, which is highly oxidized and made using the float process, for use in photovoltaic devices such as solar cells or the like. In certain example embodiments, the glass composition used for the glass is made via the float process using an extremely high and positive batch redox in order to reduce %FeO to a low level and permit the glass to consistently realize a combination of high visible transmission (Lta or T vis ), high infrared (IR) transmission, and high total solar (TS) transmission. The glass substrate may be patterned or not patterned in different example embodiments of this invention.
摘要翻译：本发明的某些示例性实施例涉及高透度低铁玻璃，其被高度氧化并使用浮法工艺制造，用于光伏器件如太阳能电池等。在某些示例性实施方案中，用于玻璃的玻璃组合物通过使用非常高和正批式氧化还原的浮法进行制备，以便将FeO％降低至低水平并允许玻璃始终实现高可见透射（高分辨率红外（IR）传输和高总太阳能（TS）传输。可以在本发明的不同示例性实施例中对玻璃基板进行图案化或未图案化。

6. 发明申请

WO2006060242A2 COATED ARTICLE WITH LOW-E COATING INCLUDING IR REFLECTING LAYER(S) AND CORRESPONDING METHOD 审中-公开
标题翻译：带低反射涂层的涂层物品，包括反射层（S）及相应的方法
公开(公告)号：WO2006060242A2
公开(公告)日：2006-06-08
申请号：PCT/US2005/042325
申请日：2005-11-22
申请人： GUARDIAN INDUSTRIES CORP. , CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A. (C.R.V.C) , FERREIRA, Jose , LEMMER, Jean-marc , MULLER, Jens-Peter , THOMSEN, Scott, V.
发明人： FERREIRA, Jose , LEMMER, Jean-marc , MULLER, Jens-Peter , THOMSEN, Scott, V.
IPC分类号： B32B3/02 , B32B17/06 , B32B15/04 , B32B9/00 , B32B19/00
CPC分类号： C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681 , C03C2218/154 , Y10T428/23
摘要： A coated article is provided with a low-emissivity (low-E) layer stack for use in a window unit or the like. The layer stack, or coating, may permit the coated article to achieve one or more of a fairly low solar factor (SF) value, a high selectivity (T vis /SF) value, substantially neutral color at normal and/or off-axis viewing angles, and/or low emissivity. When high selectivity values are achieved, there is provided a high ratio of visible transmission to SF, which is a desirable feature in certain example instances. In certain example embodiments, a sub-oxide layer (e.g., NiCrO X ) may be used as a contact layer under an infrared (IR) reflecting layer in order to permit low SF values, high selectivity, and good coloration to be achieved.
摘要翻译：涂覆制品具有用于窗户单元等的低发射率（低-E）层堆叠。层堆叠或涂层可允许涂布制品实现以下一项或多项：相当低的太阳因子（SF）值，高选择性（T vis / SF）值，在正常和/或离轴观看角度，和/或低发射率。当达到高选择性值时，提供了可见传输与SF的高比率，这在某些示例情况下是期望的特征。在某些示例性实施例中，为了允许低的SF值，高选择性和低的反射率，可以在红外（IR）反射层之下使用低氧化物层（例如，NiCrO↓↓）作为接触层要达到好的着色效果。

7. 发明申请

WO2006057829A2 SCRATCH RESISTANT COATED GLASS ARTICLE INCLUDING LAYER(S) RESISTANT TO FLUORIDE-BASED ETCHANT(S), AND METHOD OF MAKING ARTICLE USING COMBUSTION CVD 审中-公开
标题翻译：耐刮涂玻璃制品，包括耐氟化物基质的层（S），以及使用燃烧CVD制备物品的方法
公开(公告)号：WO2006057829A2
公开(公告)日：2006-06-01
申请号：PCT/US2005/040974
申请日：2005-11-14
申请人： GUARDIAN INDUSTRIES CORP. , THOMSEN, Scott, V. , PETRMICHL, Rudolph, Hugo , MURPHY, Nestor, P. , VEERASAMY, Vijayen, S.
发明人： THOMSEN, Scott, V. , PETRMICHL, Rudolph, Hugo , MURPHY, Nestor, P. , VEERASAMY, Vijayen, S.
IPC分类号： C23C14/00 , B32B9/00 , C23C14/32 , C23C16/00 , H01L21/4763 , G21H5/00 , B05D3/00 , C08J7/18
CPC分类号： C23C14/06 , C03C17/22 , C03C17/225 , C03C17/23 , C03C17/245 , C03C17/2453 , C03C17/3417 , C03C17/3435 , C03C17/3441 , C03C17/3452 , C03C2217/215 , C03C2217/218 , C03C2217/228 , C03C2217/281 , C03C2217/282 , C03C2217/285 , C03C2218/15 , C03C2218/154 , C23C14/024 , C23C14/0635 , C23C14/08 , C23C14/086 , C23C14/58 , Y10T428/265 , Y10T428/30 , Y10T428/31612
摘要： A scratch resistant coated article is provided which is also resistant to attacks by at least some fluoride-based etchant(s) for at least a period of time. In certain example embodiments, an anti-etch layer(s) is provided on a glass substrate in order to protect the glass substrate from attacks by fluoride-based etchant(s), and an underlayer(s) deposited by flame pyrolysis may be provided under at least the antietch layer(s).
摘要翻译：提供了耐刮擦涂层制品，其还耐受至少一些基于氟化物的蚀刻剂至少一段时间的攻击。在某些示例性实施例中，在玻璃基板上提供防蚀刻层，以便保护玻璃基板免受基于氟化物的蚀刻剂的攻击，并且可以提供通过火焰热解沉积的底层在至少防反射层之下。

8. 发明申请

WO2005082799A3 CLEAR GLASS COMPOSITION 审中-公开
标题翻译：清洁玻璃组合物
公开(公告)号：WO2005082799A3
公开(公告)日：2006-05-26
申请号：PCT/US2005002692
申请日：2005-01-28
申请人： GUARDIAN INDUSTRIES , LANDA LEONID , LANDA KSENIA A , THOMSEN SCOTT V , HULME RICHARD
发明人： LANDA LEONID , LANDA KSENIA A , THOMSEN SCOTT V , HULME RICHARD
IPC分类号： C03C3/095
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: total iron (expressed as Fe 2 0 3 ): 0.01 to 0.30 %, erbium oxide (e.g., Er 2 0 3 ): 0.01 to 0.30 %.
摘要翻译：提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。在某些示例性实施方案中，玻璃可以包括基础玻璃（例如，钠钙二氧化硅基底玻璃），另外，按重量百分比计：总铁（表示为Fe 2 O 3， / 0.01）：0.01〜0.30％，0.01〜0.30％的氧化铒（例如，Er 2 O 3 3）。

9. 发明申请

WO2006028629A3 COATED ARTICLE WITH LOW-E COATING INCLUDING IR REFLECTING LAYER(S) AND CORRESPONDING METHOD 审中-公开
标题翻译：带低反射涂层的涂层物品，包括反射层（S）及相应的方法
公开(公告)号：WO2006028629A3
公开(公告)日：2006-04-27
申请号：PCT/US2005028093
申请日：2005-08-08
申请人： CERAMIQUE S A C R V C CT LUXEM , GUARDIAN INDUSTRIES , FERREIRA JOSE , LEMMER JEAN-MARC , MULLER JEAN-PETER , THOMSEN SCOTT V
发明人： FERREIRA JOSE , LEMMER JEAN-MARC , MULLER JEAN-PETER , THOMSEN SCOTT V
IPC分类号： B32B17/06
CPC分类号： C03C17/36 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C17/3681
摘要： A coated article is provided with a low-emissivity (low-E) layer stack for use in a window unit or the like. The layer stack, or coating, may permit the coated article to achieve one or more of a low solar factor (SF) value, a high selectivity (T vis /SF) value, substantially neutral color at normal and/off-axis viewing angles, and/or low emissivity. When high selectivity values are achieved, there is provided a high ratio of visible transmission to SF, which is a desirable feature in certain example instances. In certain example embodiments , a sub-oxide layer (e.g., NiCrO x ) may be used as a contact layer under an infrared (IR) reflecting layer in order to permit low SF values, high selectivity , and good coloration to be achieved.
摘要翻译：涂层制品具有用于窗户单元等的低发射率（低-E）层堆叠。层堆叠或涂层可以允许涂覆的制品在通常情况下实现低太阳因子（SF）值，高选择性（T / vis / SF）值，基本上中性的颜色中的一种或多种和/或离轴观看角度，和/或低发射率。当达到高选择性值时，提供了可见传输与SF的高比率，这在某些示例情况下是期望的特征。在某些示例性实施例中，为了允许低的SF值，高的选择性和低的反射率，可以在红外（IR）反射层下使用低氧化物层（例如，NiCrO _{x ）作为接触层要实现良好的着色。}

10. 发明申请

WO2004081251A2 COATED ARTICLE INCLUDING TITANIUM OXYCARBIDE AND METHOD OF MAKING SAME 审中-公开
标题翻译：包含氧化钛的涂层制品及其制备方法
公开(公告)号：WO2004081251A2
公开(公告)日：2004-09-23
申请号：PCT/US2004007054
申请日：2004-03-09
申请人： GUARDIAN INDUSTRIES , VEERASAMY VIJAYEN S , THOMSEN SCOTT V , PETRMICHL RUDOLPH HUGO
发明人： VEERASAMY VIJAYEN S , THOMSEN SCOTT V , PETRMICHL RUDOLPH HUGO
IPC分类号： C03C17/22 , C03C17/245 , C23C14/06 , C23C14/08 , C23C14/48 , C23C14/58 , C23C
CPC分类号： C23C14/5833 , C03C17/22 , C03C17/2456 , C03C2217/212 , C03C2217/282 , C03C2218/154 , C03C2218/32 , C23C14/06 , C23C14/083 , C23C14/48 , Y10T428/30 , Y10T428/31
摘要： A coated article is provided which includes a layer including titanium oxycarbide. In order to form the coated article, a layer of titanium oxide is deposited on a substrate by sputtering or the like. After sputtering of the layer including titanium oxide, an ion beam source(s) is used to implant at least carbon ions into the titanium oxide. When implanting, the carbon ions have sufficient ion energy so as to knock off oxygen (0) from TiOX molecules so as to enable a substantially continuous layer comprising titanium oxycarbide to form near a surface of the previously sputtered layer.
摘要翻译：提供了包括包含碳氧化钛的层的涂覆制品。为了形成被覆制品，通过溅射等将氧化钛层沉积在基板上。在溅射包括氧化钛的层之后，使用离子束源至少将碳离子注入到氧化钛中。当注入时，碳离子具有足够的离子能量，从而从TiOX分子中除去氧（0），从而使包含碳氧化钛的基本上连续的层能够形成在先前溅射层的表面附近。

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