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    • 1. 发明申请
    • FLAME RETARDANT COMPOSITIONS AND THEIR USE
    • 阻燃组合物及其用途
    • WO2006019414A1
    • 2006-02-23
    • PCT/US2005/006558
    • 2005-03-01
    • ALBEMARLE CORPORATIONTHOMAS, Samuel, G., Jr.DESOTO, Troy, E.
    • THOMAS, Samuel, G., Jr.DESOTO, Troy, E.
    • C08L55/02C08L51/04C08L23/06C08K5/00
    • C08L55/02C08K5/0066C08K5/03C08L23/02C08L23/06C08L25/06C08L25/18C08L51/04C08L25/00C08L2666/04C08L2666/06
    • This invention provides a flame retardant additive composition which comprises a blend of (a) brominated anionic styrenic polymer, and (b) at least one polybrominated organic flame retardant. The polybrominated organic flame retardant (b) is selected from the following: A) (1) at least one polybrominated 1,1,3-trimethyl-3-phenylindane having three or more bromine atoms per molecule, or (2) at least one polybrominated 1­methyl-3-phenylindane having three or more bromine atoms per molecule, or (3) both of (1) and (2) hereof; B) at least one polybrominated epoxy oligomer having a bromine content of at least about 30 wt %; C) at least one brominated diphenyloxide having at least 6 bromine atoms per molecule, or if a mixture, an average of at least 6 bromine atoms per molecule; D) at least one brominated phenoxytriazine having two or three brominated phenoxy groups bonded to a triazine ring, with the total number of bromine atoms on the two or three phenoxy groups being at least 6, or if a mixture of brominated phenoxytriazine compounds, an average of at least 6 bromine atoms per molecule; E) at least one brominated diphenoxybenzene having at least 9 bromine atoms per molecule or if a mixture, an average of at least 9 bromine atoms per molecule; F) at least one ring-brominated alkylenebisphthalimide having at least 6 bromine atoms per molecule or if a mixture, an average of at least 6 bromine atoms per molecule; and G) (I) at least one ring-brominated bisphenol A having an average of at least about 3 bromine atoms per molecule, or (ii) at least one ring-brominated bisphenol sulfone having an average of at least about 3 bromine atoms per molecule, or (iii) at least one ring-brominated bisphenol A bis(brominated alkylether) having an average of at least about 3 bromine atoms per molecule, or (iv) at least one ring-brominated bisphenol sulfone bis(brominated alkylether) having an average of at least about 3 bromine atoms per molecule, or a mixture of any two or more of (i)-(iv).
    • 本发明提供一种阻燃添加剂组合物,其包含(a)溴化阴离子苯乙烯聚合物和(b)至少一种多溴有机阻燃剂的共混物。 多溴有机阻燃剂(b)选自以下:A)(1)至少一种每分子具有三个或更多个溴原子的多溴化1,1,3,3-三甲基-3-苯基二氢茚基,或(2)至少一个 每分子具有三个或更多个溴原子的多溴化1-甲基-3-苯基二氢茚基,或(3)本文的(1)和(2)两者; B)至少一种溴含量为至少约30重量%的多溴环氧低聚物; C)至少一种每分子具有至少6个溴原子的溴化二苯醚,或者如果混合物,每分子平均至少6个溴原子; D)至少一种具有两个或三个与三嗪环结合的溴化苯氧基的溴化苯氧基三嗪,两个或三个苯氧基的溴原子总数至少为6,或者如果是溴化苯并三嗪化合物的混合物, 每分子至少6个溴原子; E)每分子具有至少9个溴原子的至少一个溴化二苯氧基,或者如果混合物,每分子平均至少9个溴原子; F)每分子具有至少6个溴原子的至少一个环溴化亚烷基双对苯二甲酰亚胺或如果混合物,每分子平均至少6个溴原子; 和G)(I)每分子平均具有至少约3个溴原子的至少一个环溴化双酚A,或(ii)至少一个平均具有至少约3个溴原子的环溴代双酚砜 分子,或(iii)每分子平均具有至少约3个溴原子的至少一个环溴化双酚A双(溴化烷基醚),或(iv)至少一个环溴代双酚砜双(溴化烷基醚),其具有 每个分子平均至少约3个溴原子,或(i) - (iv)中任意两个或多个的混合物。