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1. 发明申请

WO2010110994A2 POLYMER MEMBRANES PREPARED FROM AROMATIC POLYIMIDE MEMBRANES BY THERMAL TREATING AND UV CROSSLINKING 审中-公开
标题翻译：通过热处理和紫外线交联从芳族聚酰亚胺膜制备的聚合物膜
公开(公告)号：WO2010110994A2
公开(公告)日：2010-09-30
申请号：PCT/US2010/025820
申请日：2010-03-02
申请人： UOP LLC , LIU, Chunqing , COUGHLIN, Peter K. , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
发明人： LIU, Chunqing , COUGHLIN, Peter K. , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
IPC分类号： B01D71/64
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译：本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。

2. 发明申请

WO2010110986A2 POLYBENZOXAZOLE POLYMER-BASED MIXED MATRIX MEMBRANES 审中-公开
标题翻译：聚苯并唑基聚合物混合基质膜
公开(公告)号：WO2010110986A2
公开(公告)日：2010-09-30
申请号：PCT/US2010/025391
申请日：2010-02-25
申请人： UOP LLC , LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
发明人： LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
IPC分类号： B01D71/00 , B01D69/00 , B01D67/00
CPC分类号： B01D71/62 , B01D67/0079 , B01D69/147
摘要： The present invention discloses new types of polybenzoxazole-based mixed matrix membranes and methods for making and using these membranes. The polybenzoxazole-based mixed matrix membranes are prepared by fabricating a polyimide-based mixed matrix membrane by dispersing molecular sieve particles in a continuous aromatic polyimide matrix with pendent hydroxyl groups ortho to the heterocyclic imide nitrogen; and then converting the polyimide-based mixed matrix membrane to a polybenzoxazole-based mixed matrix membrane by heating between 200 and 600C under inert atmosphere or vacuum. The polybenzoxazole-based mixed matrix membranes of the present invention can be fabricated into any convenient geometry such as flat sheet (or spiral wound), tube, hollow fiber, or thin film composite. These polybenzoxazole-based mixed matrix membranes exhibit high thermal stability, significantly higher selectivity than the neat polybenzoxazole polymer membranes, and much higher permeability than traditional mixed matrix membranes.
摘要翻译：本发明公开了新型的基于苯并恶唑的混合基质膜，以及制造和使用这些膜的方法。基于聚苯并恶唑的混合基质膜通过将分子筛颗粒分散在具有与杂环酰亚胺氮原子相邻的侧羟基的连续芳族聚酰亚胺基体中制备聚酰亚胺基混合基质膜来制备; 然后通过在惰性气氛或真空下在200℃至600℃之间加热将聚酰亚胺基混合基质膜转变成聚苯并恶唑类混合基质膜。本发明的基于聚苯并恶唑的混合基质膜可以制成任何方便的几何形状，例如平板（或螺旋缠绕），管，中空纤维或薄膜复合材料。这些基于聚苯并恶唑的混合基质膜具有高的热稳定性，比纯聚苯并恶唑聚合物膜显着更高的选择性，并且比传统的混合基质膜具有更高的渗透性。

3. 发明申请

WO2009137245A2 FLUOROPOLYMER COATED MEMBRANES 审中-公开
标题翻译：含氟聚合物涂膜
公开(公告)号：WO2009137245A2
公开(公告)日：2009-11-12
申请号：PCT/US2009040648
申请日：2009-04-15
申请人： UOP LLC , LIU CHUNQING , TANG MAN-WING
发明人： LIU CHUNQING , TANG MAN-WING
IPC分类号： B01D71/32 , B01D69/02
CPC分类号： B01D61/025 , B01D61/362 , B01D67/0011 , B01D67/0079 , B01D67/0088 , B01D69/10 , B01D69/12 , B01D69/141 , B01D71/028 , B01D71/10 , B01D71/32 , B01D2325/022 , B01D2325/24 , C10K1/20 , Y02A20/131
摘要： The present invention discloses fluoropolymer coated membranes and methods for making and using these membranes. The fluoropolymer coated membranes are prepared by coating a porous asymmetric membrane layer with a thin layer of fluoropolymer coating. The porous asymmetric membrane layer comprises an asymmetric cellulosic membrane, an asymmetric polymer membrane, or an asymmetric molecular sieve/polymer mixed matrix membrane with a low selectivity and high permeance. The fluoropolymer coating improves the selectivity of the porous asymmetric membrane layer and maintains the membrane performance with time. The fluoropolymer coated membranes are suitable for a variety of liquid, gas, and vapor separations such as desalination of water by reverse osmosis, non-aqueous liquid separation such as deep desulfurization of gasoline and diesel fuels, ethanol/water separations, pervaporation dehydration of aqueous/organic mixtures, CO2/CH4, CO2/N2, H2/CH4, O2/N2, olefin/paraffin, iso/normal paraffins separations, and other light gas mixture separations.
摘要翻译：本发明公开了含氟聚合物涂覆的膜和用于制造和使用这些膜的方法。含氟聚合物涂覆的膜通过用含氟聚合物涂层的薄层涂覆多孔不对称膜层来制备。多孔非对称膜层包含具有低选择性和高渗透性的不对称纤维素膜，不对称聚合物膜或不对称分子筛/聚合物混合基质膜。含氟聚合物涂层改善了多孔不对称膜层的选择性并随时间维持膜性能。含氟聚合物涂层膜适用于各种液体，气体和蒸汽分离，如通过反渗透脱盐水，非水液体分离如汽油和柴油燃料的深度脱硫，乙醇/水分离，水溶液的渗透汽化脱水 /有机混合物，CO 2 / CH 4，CO 2 / N 2，H 2 / CH 4，O 2 / N 2，烯烃/石蜡，异/正链烷烃分离和其他轻质气体混合物分离。

4. 发明申请

WO2010110975A3 HIGH PERFORMANCE CROSS-LINKED POLYBENZOXAZOLE AND POLYBENZOTHIAZOLE POLYMER MEMBRANES 审中-公开
公开(公告)号：WO2010110975A3
公开(公告)日：2010-09-30
申请号：PCT/US2010/024855
申请日：2010-02-22
申请人： UOP LLC , LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
发明人： LIU, Chunqing , TANG, Man-Wing , SERBAYEVA, Raisa , ZHOU, Lubo
IPC分类号： B01D71/64 , B01D67/00 , C08J5/22 , C08G73/22 , C08G75/32
摘要： In the present invention high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes and methods for making and using these membranes have been developed. The cross-linked polybenzoxazole and polybenzothiazole polymer membranes are prepared by: 1) first synthesizing polyimide polymers comprising pendent functional groups (e.g., -OH or -SH) ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone; 2) fabricating polyimide membranes from these polymers; 3) converting the polyimide membranes to polybenzoxazole or polybenzothiazole membranes by heating under inert atmosphere such as nitrogen or vacuum; and 4) finally converting the membranes to high performance cross-linked polybenzoxazole or polybenzothiazole membranes by a crosslinking treatment, preferably UV radiation. The membranes can be fabricated into any convenient geometry. The high performance cross-linked polybenzoxazole and polybenzothiazole polymer membranes of the present invention are suitable for a variety of liquid, gas, and vapor separations.

5. 发明申请

WO2008076599A1 ASYMMETRIC GAS SEPARATION MEMBRANES WITH SUPERIOR CAPABILITIES FOR GAS SEPARATION 审中-公开
标题翻译：具有气体分离的超级能力的不对称气体分离膜
公开(公告)号：WO2008076599A1
公开(公告)日：2008-06-26
申请号：PCT/US2007/085665
申请日：2007-11-27
申请人： UOP LLC , TANG, Man-wing
发明人： TANG, Man-wing
IPC分类号： B01D71/00
CPC分类号： B29C41/24 , B01D53/228 , B01D67/0011 , B01D67/0083 , B01D67/0088 , B01D71/18 , B01D71/64 , B01D71/68 , B01D2323/283 , B01D2325/022 , B29K2001/00 , B29K2001/12 , B29K2079/08 , B29K2081/06 , C08K5/1565 , C08K5/3415 , Y02P20/132
摘要： This invention relates to a method of making flat sheet asymmetric membranes, including cellulose diacetate /cellulose triacetate blended membranes, polyimide membranes, and polyimide/polyethersulfone blended membranes by formulating the polymer or the blended polymers dopes in a dual solvent mixture containing 1,3 dioxolane and a second solvent, such as N,N'-methylpyrrolidinone (NMP). The dopes are tailored to be closed to the point of phase separation with or without suitable non-solvent additives such as methanol, acetone, decane or a mixture of these non-solvents. The flat sheet asymmetric membranes are cast by the phase inversion processes using water as the coagulation bath and annealing bath. The dried membranes are coated with UV curable silicone rubber. The resulting asymmetric membranes exhibit excellent permeability and selectivity compared to the intrinsic dense film performances.
摘要翻译：本发明涉及通过在含有1,3-二氧戊环的双重溶剂混合物中配制聚合物或共混聚合物涂料来制备平板非对称膜的方法，包括纤维素二乙酸酯/三乙酸纤维素共混膜，聚酰亚胺膜和聚酰亚胺/聚醚砜共混膜和第二溶剂如N，N'-甲基吡咯烷酮（NMP）。使用或不使用合适的非溶剂添加剂例如甲醇，丙酮，癸烷或这些非溶剂的混合物将掺合物定制为封闭到相分离点。通过使用水作为凝固浴和退火浴的相转化法浇铸平板不对称膜。干燥的膜用可UV固化的硅橡胶涂覆。与内在致密膜性能相比，所得到的不对称膜表现出优异的渗透性和选择性。

6. 发明申请

WO2010110995A3 POLYMER MEMBRANES DERIVED FROM AROMATIC POLYIMIDE MEMBRANES 审中-公开
标题翻译：从芳族聚酰亚胺膜衍生的聚合物膜
公开(公告)号：WO2010110995A3
公开(公告)日：2011-01-06
申请号：PCT/US2010025822
申请日：2010-03-02
申请人： UOP LLC , LIU CHUNQING , SERBAYEVA RAISA , TANG MAN-WING , ZHOU LUBO , COUGHLIN PETER K
发明人： LIU CHUNQING , SERBAYEVA RAISA , TANG MAN-WING , ZHOU LUBO , COUGHLIN PETER K
IPC分类号： B01D71/64 , C08J5/22
CPC分类号： B01D71/64 , B01D67/0088 , B01D2323/08 , B01D2323/30
摘要： The present invention discloses a new type of high performance polymer membranes derived from aromatic polyimide membranes and methods for making and using these membranes. The polymer membranes described in the present invention were derived from aromatic polyimide membranes by crosslinking followed by thermal treating. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The high performance polymer membranes showed significantly improved permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The high performance polymer membranes also showed significantly improved selectivity for gas separations compared to the thermal-treated but non-UV-crosslinked aromatic polyimide membranes. The high performance polymer membranes of the present invention are suitable for liquid, gas, and vapor separations, as well as for catalysis and fuel cell applications.
摘要翻译：本发明公开了一种衍生自芳族聚酰亚胺膜的新型高性能聚合物膜以及制造和使用这些膜的方法。本发明中描述的聚合物膜通过交联然后进行热处理从芳族聚酰亚胺膜得到。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，高性能聚合物膜显示出显着改善气体分离的渗透性。与热处理但非UV交联的芳族聚酰亚胺膜相比，高性能聚合物膜还显示出对气体分离的选择性显着提高。本发明的高性能聚合物膜适用于液体，气体和蒸汽分离，以及催化和燃料电池应用。

7. 发明申请

WO2010110994A3 POLYMER MEMBRANES PREPARED FROM AROMATIC POLYIMIDE MEMBRANES BY THERMAL TREATING AND UV CROSSLINKING 审中-公开
标题翻译：通过热处理和紫外线交联从芳族聚酰亚胺膜制备的聚合物膜
公开(公告)号：WO2010110994A3
公开(公告)日：2011-01-06
申请号：PCT/US2010025820
申请日：2010-03-02
申请人： UOP LLC , LIU CHUNQING , COUGHLIN PETER K , TANG MAN-WING , SERBAYEVA RAISA , ZHOU LUBO
发明人： LIU CHUNQING , COUGHLIN PETER K , TANG MAN-WING , SERBAYEVA RAISA , ZHOU LUBO
IPC分类号： B01D71/64
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0093 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1042 , C08G73/1046 , C08G73/1064 , C08G73/16 , C08L79/08 , Y02C20/20
摘要： The present invention discloses a new type of high performance polymer membranes prepared from aromatic polyimide membranes by thermal treating and crosslinking and methods for making and using these membranes. The polymer membranes were prepared from aromatic polyimide membranes by thermal treating under inert atmosphere followed by crosslinking preferably by using a UV radiation source. The aromatic polyimide membranes were made from aromatic polyimide polymers comprising both pendent hydroxy functional groups ortho to the heterocyclic imide nitrogen and cross-linkable functional groups in the polymer backbone. The membranes showed significantly improved selectivity and permeability for gas separations compared to the aromatic polyimide membranes without any treatment. The membranes can be fabricated into any convenient geometry and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used for other applications such as for catalysis and fuel cell applications.
摘要翻译：本发明公开了通过热处理和交联由芳族聚酰亚胺膜制备的新型高性能聚合物膜以及制造和使用这些膜的方法。聚合物膜由芳族聚酰亚胺膜通过在惰性气氛下热处理制备，然后优选通过使用UV辐射源进行交联。芳族聚酰亚胺膜由芳族聚酰亚胺聚合物制成，其中包含杂环酰亚胺氮原子的邻接羟基官能团和聚合物主链中的可交联官能团。与没有任何处理的芳族聚酰亚胺膜相比，膜显示出气体分离的选择性和渗透性显着提高。膜可以制造成任何方便的几何形状，并且不仅适用于各种液体，气体和蒸汽分离，而且还可以用于其它应用，例如用于催化和燃料电池应用。

8. 发明申请

WO2010151451A3 POLYBENZOXAZOLE MEMBRANES PREPARED FROM AROMATIC POLYAMIDE MEMBRANES 审中-公开
公开(公告)号：WO2010151451A3
公开(公告)日：2010-12-29
申请号：PCT/US2010/038574
申请日：2010-06-15
申请人： UOP LLC , LIU, Chunqing , MINKOV, Raisa , FAHEEM, Syed, A. , TANG, Man-Wing , ZHOU, Lubo , BRICKER, Jeffery, C.
发明人： LIU, Chunqing , MINKOV, Raisa , FAHEEM, Syed, A. , TANG, Man-Wing , ZHOU, Lubo , BRICKER, Jeffery, C.
IPC分类号： B01D71/00 , B01D71/64 , B01D69/00 , C08J5/18
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550°C under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. The polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.

9. 发明申请

WO2010151451A2 POLYBENZOXAZOLE MEMBRANES PREPARED FROM AROMATIC POLYAMIDE MEMBRANES 审中-公开
标题翻译：从芳族聚酰胺膜制备的聚苯并噻唑膜
公开(公告)号：WO2010151451A2
公开(公告)日：2010-12-29
申请号：PCT/US2010038574
申请日：2010-06-15
申请人： UOP LLC , LIU CHUNQING , MINKOV RAISA , FAHEEM SYED A , TANG MAN-WING , ZHOU LUBO , BRICKER JEFFERY C
发明人： LIU CHUNQING , MINKOV RAISA , FAHEEM SYED A , TANG MAN-WING , ZHOU LUBO , BRICKER JEFFERY C
IPC分类号： B01D71/00 , B01D69/00 , B01D71/64 , C08J5/18
CPC分类号： B01D71/62 , B01D53/228 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G73/22 , H01M8/1027 , H01M8/103 , H01M2300/0082
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550°C under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. The polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
摘要翻译：本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。聚苯并恶唑膜可以进行另外的交联步骤以提高膜的选择性。与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池。

10. 发明申请

WO2010110968A3 BLEND POLYMER MEMBRANES COMPRISING THERMALLY REARRANGED POLYMERS DERIVED FROM AROMATIC POLYIMIDES CONTAINING ORTHO-POSITIONED FUNCTIONAL GROUPS 审中-公开
标题翻译：包含衍生自含有定位官能团的芳香族聚酰亚胺的热再生聚合物的共混聚合物膜
公开(公告)号：WO2010110968A3
公开(公告)日：2010-11-18
申请号：PCT/US2010024557
申请日：2010-02-18
申请人： UOP LLC , LIU CHUNQING , TANG MAN-WING
发明人： LIU CHUNQING , TANG MAN-WING
IPC分类号： C08J5/22 , B01D53/22 , C01B32/50 , C08L79/04
CPC分类号： C08L79/08 , B01D71/64 , B01D71/82 , B01D2323/08 , B01D2323/30 , B01D2323/345 , C08G73/1039 , C08G73/1046 , C08G73/1064 , C08G73/22 , C08J5/2256 , C08J5/2275 , C08J2379/08 , C08J2481/06 , C08L79/04 , C08L81/06 , C08L2205/02 , C08L81/00 , C08L2666/20
摘要： The present invention discloses blend polymer membranes comprising thermally rearranged polymers derived from aromatic polyimides containing ortho-positioned functional groups and methods for making and using these blend polymer membranes. The blend polymer membranes described in the current invention are prepared by heat treatment of blend polymer membranes comprising aromatic polyimides containing ortho-positioned functional groups such as -OH or -SH groups. In some instances, an additional crosslinking step is performed to improve the selectivity of the membrane. These blend polymer membranes have improved flexibility, reduced cost, improved processability, and enhanced selectivity and/or permeability compared to the comparable polymer membranes that comprise a single polymer.
摘要翻译：本发明公开了包含衍生自含有邻位官能团的芳族聚酰亚胺的热重排聚合物的共混聚合物膜以及制备和使用这些共混聚合物膜的方法。本发明中描述的共混聚合物膜通过热处理包含含有邻位官能团如-OH或-SH基团的芳族聚酰亚胺的共混聚合物膜来制备。在一些情况下，进行额外的交联步骤以提高膜的选择性。与包含单一聚合物的可比较聚合物膜相比，这些共混聚合物膜具有改进的柔韧性，降低的成本，改进的可加工性以及增强的选择性和/或渗透性。

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