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    • 3. 发明申请
    • PHENYL AND FLUORENYL SUBSTITUTED PHENYL-PYRAZOLE COMPLEXES OF Ir
    • 苯并噻唑取代的苯并噻唑复合物
    • WO2004085450A2
    • 2004-10-07
    • PCT/US2004/009228
    • 2004-03-24
    • THE UNIVERSITY OF SOUTHERN CALIFORNIATHOMPSON, Mark, E.TAMAYO, ArnoldDJUROVICH, Peter
    • THOMPSON, Mark, E.TAMAYO, ArnoldDJUROVICH, Peter
    • C07F17/00
    • H01L51/0085C07D231/12C07F15/0033C07F15/0046C09K11/06C09K2211/1029C09K2211/1044C09K2211/185H01L51/5016H01L2251/55H05B33/14Y10S428/917
    • An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer may further include a compound with the following structure (I) wherein M is a metal having an atomic weight greater than 40; (C-N) is a substituted or unsubstituted cyclometallated ligand, and (C-N) is different from at least one other ligand attached to the metal; each R is independently selected from hydrogen, alkyl, alkenyl, alkynyl, alkylaryl, CN, CF 3 , C0 2 R, C(O)R, NR 2 , N0 2 , OR, halo, aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a heterocyclic group; additionally or alternatively, any two adjacent substituted positions together form, independently, a fused 4- to 7-member cyclic group, wherein said cyclic group is cycloalkyl, cycloheteroalkyl, aryl, or heteroaryl, and wherein the 4- to 7-member cyclic group may be optionally substituted with substituent R; m may have a value of at least 1; n has a value of at least 1; and where n is 3, R is not a cyano group; m + n is the maximum number of ligands that may be attached to the metal. The emissive layer may further include a compound comprising a metal bonded to at least a first ligand and a second ligand, in which the first ligand has a triplet energy corresponding to a wavelength that is at least 80 nm greater than the wavelength corresponding to the triplet energy of other ligands. The compound may have only one first ligand bound to the metal. Each ligand may be organometallic. The emissive material may have enhanced electroluminescent efficiency and improved lifetime when incorporated into a light emitting device.
    • 提供有机发光装置。 该装置具有阳极,阴极和布置在阳极和阴极之间并电连接到阳极和阴极的发射层。 发光层还可以包括具有以下结构(I)的化合物,其中M是原子量大于40的金属; (C-N)是取代或未取代的环金属配体,(C-N)不同于至少一个与金属连接的其它配体; 每个R独立地选自氢,烷基,烯基,炔基,烷基芳基,CN,CF 3,CO 2 R,C(O)R,NR 2,NO 2,OR,卤素,芳基,杂芳基,取代的芳基,取代的杂芳基或杂环基 ; 另外或替代地,任何两个相邻的取代位置一起独立地形成稠合的4-至7-成员的环状基团,其中所述环状基团是环烷基,环杂烷基,芳基或杂芳基,并且其中所述4-至7-成员的环状基团 可以任选被取代基R取代; m可以具有至少1的值; n的值至少为1; 并且其中n是3,R不是氰基; m + n是可以连接到金属的配体的最大数目。 发射层还可以包括包含键合到至少第一配体和第二配体的金属的化合物,其中第一配体具有对应于比对应于三重态的波长大至少80nm的波长的三线态能量 其他配体的能量。 化合物可以仅具有与金属结合的一个第一配体。 每个配体可以是有机金属的。 发光材料可以具有增强的电致发光效率并且在结合到发光器件中时具有改善的寿命。
    • 6. 发明申请
    • PHENYL-PYRAZOLE COMPLEXES OF IR
    • IR的苯基 - 吡唑复合物
    • WO2004085450A3
    • 2004-11-25
    • PCT/US2004009228
    • 2004-03-24
    • UNIV SOUTHERN CALIFORNIATHOMPSON MARK ETAMAYO ARNOLDDJUROVICH PETER
    • THOMPSON MARK ETAMAYO ARNOLDDJUROVICH PETER
    • C07F15/00C09K11/06H01L51/00H01L51/50H05B33/14
    • H01L51/0085C07D231/12C07F15/0033C07F15/0046C09K11/06C09K2211/1029C09K2211/1044C09K2211/185H01L51/5016H01L2251/55H05B33/14Y10S428/917
    • An organic light emitting device is provided. The device has an anode, a cathode, and an emissive layer disposed between and electrically connected to the anode and the cathode. The emissive layer may further include a compound with the following structure (I) wherein M is a metal having an atomic weight greater than 40; (C-N) is a substituted or unsubstituted cyclometallated ligand, and (C-N) is different from at least one other ligand attached to the metal; each R is independently selected from hydrogen, alkyl, alkenyl, alkynyl, alkylaryl, CN, CF3, CO2R, C(O)R, NR2, NO2, OR, halo, aryl, heteroaryl, substituted aryl, substituted heteroaryl, or a heterocyclic group; additionally or alternatively, any two adjacent substituted positions together form, independently, a fused 4- to 7-member cyclic group, wherein said cyclic group is cycloalkyl, cycloheteroalkyl, aryl, or heteroaryl, and wherein the 4- to 7-member cyclic group may be optionally substituted with substituent R; m may have a value of at least 1; n has a value of at least 1; and where n is 3, R is not a cyano group; m + n is the maximum number of ligands that may be attached to the metal. The emissive layer may further include a compound comprising a metal bonded to at least a first ligand and a second ligand, in which the first ligand has a triplet energy corresponding to a wavelength that is at least 80 nm greater than the wavelength corresponding to the triplet energy of other ligands. The compound may have only one first ligand bound to the metal. Each ligand may be organometallic. The emissive material may have enhanced electroluminescent efficiency and improved lifetime when incorporated into a light emitting device.
    • 提供有机发光装置。 该装置具有阳极,阴极和布置在阳极和阴极之间并电连接到阳极和阴极的发射层。 发光层还可以包括具有以下结构(I)的化合物,其中M是原子量大于40的金属; (C-N)是取代或未取代的环金属配体,(C-N)不同于至少一个与金属连接的其它配体; 每个R独立地选自氢,烷基,烯基,炔基,烷基芳基,CN,CF 3,CO 2 R,C(O)R,NR 2,NO 2,OR,卤素,芳基,杂芳基,取代的芳基,取代的杂芳基或杂环基 ; 另外或替代地,任何两个相邻的取代位置一起独立地形成稠合的4-至7-成员的环状基团,其中所述环状基团是环烷基,环杂烷基,芳基或杂芳基,并且其中所述4-至7-成员的环状基团 可以任选被取代基R取代; m可以具有至少1的值; n的值至少为1; 并且其中n是3,R不是氰基; m + n是可以连接到金属的配体的最大数目。 发射层还可以包括包含键合到至少第一配体和第二配体的金属的化合物,其中第一配体具有对应于比对应于三重态的波长大至少80nm的波长的三线态能量 其他配体的能量。 化合物可以仅具有与金属结合的一个第一配体。 每个配体可以是有机金属的。 发光材料可以具有增强的电致发光效率并且在结合到发光器件中时具有改善的寿命。