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    • 1. 发明申请
    • PRODUCTION METHOD OF ALLYL ALCOHOL COPOLYMER
    • 烯醇共聚物的生产方法
    • WO2011013844A3
    • 2011-04-14
    • PCT/JP2010063133
    • 2010-07-28
    • SHOWA DENKO KKKIBINO NOBUYUKIHETSUGI YUKIHARUTAJIMA TSUNEO
    • KIBINO NOBUYUKIHETSUGI YUKIHARUTAJIMA TSUNEO
    • C08F216/08
    • C08F216/08C08F8/14C08F232/08C08F218/02
    • The present invention relates to a method for producing an allyl alcohol copolymer comprising structures represented by formulae (3) and (2) as monomer units (in the formulae, R2 represents an aliphatic hydrocarbon group having 2 to 20 carbon atoms), comprising subjecting a copolymer comprising structures represented by formulae (1) and (2) as monomer units (in the formulae, R1 represents an aliphatic hydrocarbon group having 1 to 10 carbon atoms, which may be branched or include a cyclic structure; and R2 has the same meaning as mentioned above) to transesterification reaction with alcohol in the presence of a catalyst. The allyl alcohol copolymer obtained by the present invention is excellent in compatibility with various resins, electric insulating property, low water absorption, thermal stability and surface activity effect; and therefore is useful as a resin improver, components in coating agent, ink, adhesive agent and primer, high-performance wax, compatibilizer, surfactant, additive for grease, polyurethane material and polyester material.
    • (3)和(2)表示的结构作为单体单元(式中,R 2表示碳原子数为2〜20的脂肪族烃基)的烯丙醇共聚物的制造方法,其特征在于, (1)和(2)表示的结构作为单体单元的共聚物(式中,R 1表示碳原子数1〜10的脂肪族烃基,其可以为支链状或具有环状结构; R 2具有相同的含义 如上所述)在催化剂存在下与醇发生酯基转移反应。 本发明获得的烯丙醇共聚物与各种树脂的相容性,电绝缘性,低吸水性,热稳定性和表面活性效果优异; 因此可用作树脂改进剂,涂料剂中的组分,油墨,粘合剂和底漆,高性能蜡,增容剂,表面活性剂,润滑脂添加剂,聚氨酯材料和聚酯材料。
    • 7. 发明申请
    • PRODUCTION METHOD OF ALLYL ALCOHOL COPOLYMER
    • 乙醇共聚物的生产方法
    • WO2011013844A2
    • 2011-02-03
    • PCT/JP2010/063133
    • 2010-07-28
    • SHOWA DENKO K.K.KIBINO NobuyukiHETSUGI YukiharuTAJIMA Tsuneo
    • KIBINO NobuyukiHETSUGI YukiharuTAJIMA Tsuneo
    • C08F216/08
    • C08F216/08C08F8/14C08F232/08C08F218/02
    • The present invention relates to a method for producing an allyl alcohol copolymer comprising structures represented by formulae (3) and (2) as monomer units (in the formulae, R 2 represents an aliphatic hydrocarbon group having 2 to 20 carbon atoms), comprising subjecting a copolymer comprising structures represented by formulae (1) and (2) as monomer units (in the formulae, R 1 represents an aliphatic hydrocarbon group having 1 to 10 carbon atoms, which may be branched or include a cyclic structure; and R 2 has the same meaning as mentioned above) to transesterification reaction with alcohol in the presence of a catalyst. The allyl alcohol copolymer obtained by the present invention is excellent in compatibility with various resins, electric insulating property, low water absorption, thermal stability and surface activity effect; and therefore is useful as a resin improver, components in coating agent, ink, adhesive agent and primer, high-performance wax, compatibilizer, surfactant, additive for grease, polyurethane material and polyester material.
    • 本发明涉及一种烯丙醇共聚物的制造方法,其包含由式(3)和(2)表示的结构作为单体单元(式中,R2表示碳原子数2〜20的脂肪族烃基),其中, 包含由式(1)和(2)表示的结构的共聚物作为单体单元(在该式中,R1表示可以是支链或包含环状结构的具有1-10个碳原子的脂族烃基;并且R 2具有相同的含义 如上所述)与催化剂存在下与醇进行酯交换反应。 通过本发明获得的烯丙醇共聚物与各种树脂的相容性优异,电绝缘性,低吸水性,热稳定性和表面活性效果优异; 因此可用作树脂改良剂,涂料剂,油墨,粘合剂和底漆中的组分,高性能蜡,增容剂,表面活性剂,油脂添加剂,聚氨酯材料和聚酯材料。