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1. 发明申请

WO2011013844A3 PRODUCTION METHOD OF ALLYL ALCOHOL COPOLYMER 审中-公开
标题翻译：烯醇共聚物的生产方法
公开(公告)号：WO2011013844A3
公开(公告)日：2011-04-14
申请号：PCT/JP2010063133
申请日：2010-07-28
申请人： SHOWA DENKO KK , KIBINO NOBUYUKI , HETSUGI YUKIHARU , TAJIMA TSUNEO
发明人： KIBINO NOBUYUKI , HETSUGI YUKIHARU , TAJIMA TSUNEO
IPC分类号： C08F216/08
CPC分类号： C08F216/08 , C08F8/14 , C08F232/08 , C08F218/02
摘要： The present invention relates to a method for producing an allyl alcohol copolymer comprising structures represented by formulae (3) and (2) as monomer units (in the formulae, R2 represents an aliphatic hydrocarbon group having 2 to 20 carbon atoms), comprising subjecting a copolymer comprising structures represented by formulae (1) and (2) as monomer units (in the formulae, R1 represents an aliphatic hydrocarbon group having 1 to 10 carbon atoms, which may be branched or include a cyclic structure; and R2 has the same meaning as mentioned above) to transesterification reaction with alcohol in the presence of a catalyst. The allyl alcohol copolymer obtained by the present invention is excellent in compatibility with various resins, electric insulating property, low water absorption, thermal stability and surface activity effect; and therefore is useful as a resin improver, components in coating agent, ink, adhesive agent and primer, high-performance wax, compatibilizer, surfactant, additive for grease, polyurethane material and polyester material.
摘要翻译：（3）和（2）表示的结构作为单体单元（式中，R 2表示碳原子数为2〜20的脂肪族烃基）的烯丙醇共聚物的制造方法，其特征在于，（1）和（2）表示的结构作为单体单元的共聚物（式中，R 1表示碳原子数1〜10的脂肪族烃基，其可以为支链状或具有环状结构; R 2具有相同的含义如上所述）在催化剂存在下与醇发生酯基转移反应。本发明获得的烯丙醇共聚物与各种树脂的相容性，电绝缘性，低吸水性，热稳定性和表面活性效果优异; 因此可用作树脂改进剂，涂料剂中的组分，油墨，粘合剂和底漆，高性能蜡，增容剂，表面活性剂，润滑脂添加剂，聚氨酯材料和聚酯材料。

2. 发明申请

WO2008062903A1 RADICALLY POLYMERIZABLE COMPOUND HAVING A DITHIOCARBONATE STRUCTURE AND A SULFUR-CONTAINING ALLYLCARBONATE 审中-公开
标题翻译：具有二硫代碳酸盐结构和含硫磺酸的无定形聚合化合物
公开(公告)号：WO2008062903A1
公开(公告)日：2008-05-29
申请号：PCT/JP2007/072999
申请日：2007-11-21
申请人： SHOWA DENKO K.K. , OYAMA, Yasuyuki , KIBINO, Nobuyuki , KAI, Kazufumi , TAJIMA, Tsuneo
发明人： OYAMA, Yasuyuki , KIBINO, Nobuyuki , KAI, Kazufumi , TAJIMA, Tsuneo
IPC分类号： C07C329/16 , C08F18/24 , B29D11/00
CPC分类号： C07C329/16 , C08F220/40 , C08F222/1006 , C08F222/24
摘要： The invention provides a radically polymerizable compound having a dithiocarbonate structure represented by formula (1) and a sulfur-containing allylcarbonate group which can give an optical material stable and little colored at the time of thermal curing reaction, having a high refractive index and an excellent transparency, production method thereof, (co) polymer of the compound, composition containing the compound and cured product thereof, andmolded product for optical material comprising the cured product. (In the formula, R 1 and R 2 each independently represents a hydrogen atom or methyl group, and X and Y each independently represents a divalent group selected from group consisting of an alkylene group having 1 to 10 carbon atoms which may be branched, an arylene group and a cycloalkylene group.)
摘要翻译：本发明提供具有式（1）表示的二硫代碳酸酯结构和含硫烯丙基碳酸酯基的自由基聚合性化合物，其可以在热固化反应时得到光学材料稳定且颜色很小，折射率高，透明性，其制造方法，化合物的（共）聚合物，含有化合物的组合物及其固化物，以及包含该固化物的光学材料的成型体。（式中，R 1和R 2各自独立地表示氢原子或甲基，X和Y各自独立地表示选自以下的二价基团：可以是支链的碳原子数为1〜10的亚烷基，亚芳基和亚环烷基）

3. 发明申请

WO2003010566A2 PLASTIC LENS MATERIAL, PLASTIC LENS COMPOSITION, PLASTIC LENS OBTAINED BY CURING THE COMPOSITION AND PROCESS FOR PRODUCING THE PLASTIC LENS 审中-公开
标题翻译：塑料透镜材料，塑料透镜组合物，通过固化组合物获得的塑料透镜以及制造塑料透镜的方法
公开(公告)号：WO2003010566A2
公开(公告)日：2003-02-06
申请号：PCT/JP2002/006521
申请日：2002-06-27
申请人： SHOWA DENKO K. K. , OOGA, Kazuhiko , HONDA, Yoshihiro , TAJIMA, Tsuneo , KAI, Kazufumi , UCHIDA, Hiroshi
发明人： OOGA, Kazuhiko , HONDA, Yoshihiro , TAJIMA, Tsuneo , KAI, Kazufumi , UCHIDA, Hiroshi
IPC分类号： G02B1/04
CPC分类号： G02B1/041 , C08F18/14 , C08L31/00
摘要： A plastic lens material comprising at least one group having formula (1) as a terminal group and a group having formula (2) as a repeating unit wherein each R 1 independently represents an allyl group or a methallyl group and each A 1 is an independent organic residue and represents one or more organic residues derived from a divalent carboxylic acid or dicarboxylic anhydride having an alicyclic structure and/or an aromatic ring structure; wherein each A 2 is an independent organic residue and represents one or more organic residues derived from a divalent carboxylic acid or dicarboxylic anhydride having an alicyclic structure and/or an aromatic ring structure, and each X is an independent organic residue and represents one or more organic residues derived from a polyhydric alcohol having an ether bond within the molecule, provided that X can further have a branched structure having a group of formula (1) as a terminal group and a group of formula (2) as a repeating unit.
摘要翻译：一种塑料透镜材料，其包含至少一个具有式（1）作为端基的基团和具有式（2）的基团作为重复单元，其中每个R 1独立地表示烯丙基或甲代烯丙基，并且每个A 1是独立的有机残基并且代表一个或多个衍生自具有脂环结构和/或芳环的二元羧酸或二羧酸酐的有机残基结构体; 其中每个A 2是独立的有机残基并且代表一个或多个衍生自具有脂环族结构和/或芳族环结构的二元羧酸或二羧酸酐的有机残基，并且每个X是独立的有机残基，并且代表分子内具有醚键的多元醇衍生的一个或多个有机残基，条件是X可以进一步具有具有式（1）的基团作为端基的分支结构和式（2）的基团）作为重复单位。

4. 发明申请

WO2002072651A1 PLASTIC LENS COMPOSITION, PLASTIC LENS, AND PROCESS FOR PRODUCING THE PLASTIC LENS 审中-公开
标题翻译：塑料镜片组合物，塑料镜片和生产塑料镜片的工艺
公开(公告)号：WO2002072651A1
公开(公告)日：2002-09-19
申请号：PCT/JP2002/001758
申请日：2002-02-26
申请人： SHOWA DENKO K. K. , OOGA, Kazuhiko , TAJIMA, Tsuneo , KAI, Kazufumi , UCHIDA, Hiroshi
发明人： OOGA, Kazuhiko , TAJIMA, Tsuneo , KAI, Kazufumi , UCHIDA, Hiroshi
IPC分类号： C08F218/16
CPC分类号： C08F218/16 , G02B1/041 , C08L31/00
摘要： A composition for plastic lenses having a viscosity suitable for application to plastic lens materials and other optical materials and capable of giving a cured material having a relatively high refractive index and a low specific gravity, a plastic lens obtained by curing the composition, and a process for producing the plastic lens. A specific dicarboxylic acid component and a specific diol component are employed and the ratio of the components is adjusted to provide the composition for plastic lenses.
摘要翻译：一种用于塑料透镜的组合物，其具有适用于塑料透镜材料和其它光学材料并且能够提供具有相对较高折射率和低比重的固化材料的粘度的塑料透镜，通过固化该组合物获得的塑料透镜，以及工艺用于生产塑料镜片。使用特定的二羧酸组分和特定的二醇组分，调节组分的比例以提供塑料透镜的组合物。

5. 发明申请

WO0196909A3 MATERIAL FOR PLASTIC LENS, PRODUCTION PROCESS OF THE MATERIAL, COMPOSITION FOR PLASTIC LENS, PLASTIC LENS OBTAINED BY CURING THE COMPOSITION, AND PRODUCTION PROCESS OF THE PLASTIC LENS 审中-公开
标题翻译：塑料镜片材料，材料的生产过程，塑料镜片的组合物，通过固化所获得的塑料镜片和塑料镜片的生产过程
公开(公告)号：WO0196909A3
公开(公告)日：2002-04-18
申请号：PCT/JP0104878
申请日：2001-06-08
申请人： SHOWA DENKO KK , OOGA KAZUHIKO , ASAI YOSHIFUMI , KAI KAZUFUMI , TAJIMA TSUNEO , UCHIDA HIROSHI
发明人： OOGA KAZUHIKO , ASAI YOSHIFUMI , KAI KAZUFUMI , TAJIMA TSUNEO , UCHIDA HIROSHI
IPC分类号： C08F18/16 , G02B1/04 , C08F18/12
CPC分类号： C08F18/16 , G02B1/041 , C08L31/06
摘要： A material for plastic lenses, comprising at least one group represented by the following formula (1) as a terminal group and a group represented by the following formula (2) as a repeating unit.wherein each R independently represents an allyl group or a methallyl group, A and A each independently represents an organic residue derived from a dicarboxylic acid or a carboxylic anhydride, and each X independently represents an organic residue derived from a polyhydric alcohol having from 2 to 3 hydroxyl groups and containing an alicyclic structure within the molecule, provided that by the ester bonding, X can have a branched structure having a group of formula (1) as a terminal group and a group of formula (2) as a repeating unit.
摘要翻译：一种塑料透镜用材料，其特征在于，含有作为末端基的下述通式（1）表示的基团和下述式（2）表示的基团作为重复单元。各R 1独立地表示烯丙基或甲代烯丙基，A 1和A 2各自独立地表示衍生自二羧酸或羧酸酐的有机残基，并且每个X独立地表示衍生自具有2至3个羟基的多元醇的有机残基并且在分子内含有脂环结构，条件是通过酯键合，X可以具有作为末端基的式（1）的基团和作为重复单元的式（2）的基团的支链结构。

6. 发明申请

WO2012033227A3 CATALYST FOR POLYMERIZING NORBORNENE MONOMERS AND A METHOD FOR PRODUCING NORBORNENE POLYMER 审中-公开
标题翻译：聚合诺尔曼单体的催化剂和生产氮烯聚合物的方法
公开(公告)号：WO2012033227A3
公开(公告)日：2012-08-16
申请号：PCT/JP2011071060
申请日：2011-09-08
申请人： SHOWA DENKO KK , FUJIBE SATOSHI , KIBINO NOBUYUKI , TAJIMA TSUNEO
发明人： FUJIBE SATOSHI , KIBINO NOBUYUKI , TAJIMA TSUNEO
IPC分类号： C08F10/14 , C07F15/00
CPC分类号： C07F15/006 , C08F4/64048 , C08F232/08
摘要： The invention relates to a catalyst for the polymerization of norbornene monomers containing transition metal complex (A) represented by formula (1); and a method for producing norbornene copolymers containing a monomer unit represented by formulae (2) and (3). Transition metal complex (A) is preferably (?-allyl) {2- [N- (2,6-diisopropylphenyl ) iminomethyl ] phenolate } palladium, (?-allyl) {2 - [N- (2, 6-diisopropylphenyl) iminomethyl] -4-fluorophenolate } palladium, (?-allyl) [2-(N-phenyliminomethyl ) phenolate] palladium and (?-allyl ) { 2- [N-(2, 6-diisopropylphenyl ) iminomethyl] -6-methylphenolate }palladium.
摘要翻译：本发明涉及含有由式（1）表示的过渡金属络合物（A）的降冰片烯单体的聚合用催化剂。以及含有由式（2）和（3）表示的单体单元的降冰片烯共聚物的制造方法。过渡金属络合物（A）优选为（β-烯丙基）{2- [N-（2,6-二异丙基苯基）亚氨基甲基]苯酚}钯，（α-烯丙基）{2- [N-（2,6-二异丙基苯基）（α-烯丙基）[2-（N-苯基亚氨基甲基）酚盐]钯和（α-烯丙基）{2- [N-（2,6-二异丙基苯基）亚氨基甲基] -6-甲基苯酚盐 }钯。

7. 发明申请

WO2011013844A2 PRODUCTION METHOD OF ALLYL ALCOHOL COPOLYMER 审中-公开
标题翻译：乙醇共聚物的生产方法
公开(公告)号：WO2011013844A2
公开(公告)日：2011-02-03
申请号：PCT/JP2010/063133
申请日：2010-07-28
申请人： SHOWA DENKO K.K. , KIBINO Nobuyuki , HETSUGI Yukiharu , TAJIMA Tsuneo
发明人： KIBINO Nobuyuki , HETSUGI Yukiharu , TAJIMA Tsuneo
IPC分类号： C08F216/08
CPC分类号： C08F216/08 , C08F8/14 , C08F232/08 , C08F218/02
摘要： The present invention relates to a method for producing an allyl alcohol copolymer comprising structures represented by formulae (3) and (2) as monomer units (in the formulae, R 2 represents an aliphatic hydrocarbon group having 2 to 20 carbon atoms), comprising subjecting a copolymer comprising structures represented by formulae (1) and (2) as monomer units (in the formulae, R 1 represents an aliphatic hydrocarbon group having 1 to 10 carbon atoms, which may be branched or include a cyclic structure; and R 2 has the same meaning as mentioned above) to transesterification reaction with alcohol in the presence of a catalyst. The allyl alcohol copolymer obtained by the present invention is excellent in compatibility with various resins, electric insulating property, low water absorption, thermal stability and surface activity effect; and therefore is useful as a resin improver, components in coating agent, ink, adhesive agent and primer, high-performance wax, compatibilizer, surfactant, additive for grease, polyurethane material and polyester material.
摘要翻译：本发明涉及一种烯丙醇共聚物的制造方法，其包含由式（3）和（2）表示的结构作为单体单元（式中，R2表示碳原子数2〜20的脂肪族烃基），其中，包含由式（1）和（2）表示的结构的共聚物作为单体单元（在该式中，R1表示可以是支链或包含环状结构的具有1-10个碳原子的脂族烃基;并且R 2具有相同的含义如上所述）与催化剂存在下与醇进行酯交换反应。通过本发明获得的烯丙醇共聚物与各种树脂的相容性优异，电绝缘性，低吸水性，热稳定性和表面活性效果优异; 因此可用作树脂改良剂，涂料剂，油墨，粘合剂和底漆中的组分，高性能蜡，增容剂，表面活性剂，油脂添加剂，聚氨酯材料和聚酯材料。

8. 发明申请

WO2006033438A1 RADICALLY POLYMERIZABLE SULFUR-CONTAINING COMPOUND AND RADICALLY POLYMERIZABLE SULFUR-CONTAINING POLYMER 审中-公开
标题翻译：含硫酸的可聚合硫酸化合物和含硫酸的可聚合硫酸聚合物
公开(公告)号：WO2006033438A1
公开(公告)日：2006-03-30
申请号：PCT/JP2005/017658
申请日：2005-09-20
申请人： SHOWA DENKO K.K. , OHTA, Keisuke , TAJIMA, Tsuneo , KAI, Kazufumi , OYAMA, Yasuyuki
发明人： OHTA, Keisuke , TAJIMA, Tsuneo , KAI, Kazufumi , OYAMA, Yasuyuki
IPC分类号： C07D327/04 , C08G75/28 , C08G71/00 , C08K5/46 , C08F299/00 , C08F290/14
CPC分类号： C08K5/46 , C07D327/04 , C08F216/1466 , C08F220/38 , C08G75/28
摘要： The invention relates to a radically polymerizable sulfur-containing compound having a group represented by formula (1) and at least one selected from among groups represented by formulae (2) to (4) , a radically polymerizable sulfur-containing polymer obtained by subjecting the compound to cationic ring-opening (co)polymerization, production process thereof, a composition containing the sulfur-containing compound and/or the sulfur-containing polymer, and a cured product obtained from the composition……………. (1)(2) (3) (4)………….( R 1 to R 6 each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.) The cured product obtained from the radically polymerizable sulfur-containing compound and the radically polymerizable sulfur-containing polymer having a high refractive index is useful as an optical material, especially for lens material.
摘要翻译：本发明涉及具有由式（1）表示的基团和选自式（2）至（4）表示的基团中的至少一种的自由基聚合性含硫化合物，通过使化合物与阳离子开环（共）聚合反应，其制备方法，含有含硫化合物和/或含硫聚合物的组合物，以及由该组合物得到的固化物。（1）（2）（3）（4）。（R

9. 发明申请

WO03010566A3 PLASTIC LENS MATERIAL, PLASTIC LENS COMPOSITION, PLASTIC LENS OBTAINED BY CURING THE COMPOSITION AND PROCESS FOR PRODUCING THE PLASTIC LENS 审中-公开
标题翻译：塑料镜片材料，塑料镜片组合物，通过固化组合物获得的塑料镜片和用于生产塑料镜片的方法
公开(公告)号：WO03010566A3
公开(公告)日：2003-05-30
申请号：PCT/JP0206521
申请日：2002-06-27
申请人： SHOWA DENKO KK , OOGA KAZUHIKO , HONDA YOSHIHIRO , TAJIMA TSUNEO , KAI KAZUFUMI , UCHIDA HIROSHI
发明人： OOGA KAZUHIKO , HONDA YOSHIHIRO , TAJIMA TSUNEO , KAI KAZUFUMI , UCHIDA HIROSHI
IPC分类号： C08F2/46 , C08F18/14 , G02B1/04 , C08F218/14
CPC分类号： G02B1/041 , C08F18/14 , C08L31/00
摘要： A plastic lens material comprising at least one group having formula (1) as a terminal group and a group having formula (2) as a repeating unit wherein each R independently represents an allyl group or a methallyl group and each A is an independent organic residue and represents one or more organic residues derived from a divalent carboxylic acid or dicarboxylic anhydride having an alicyclic structure and/or an aromatic ring structure; wherein each A is an independent organic residue and represents one or more organic residues derived from a divalent carboxylic acid or dicarboxylic anhydride having an alicyclic structure and/or an aromatic ring structure, and each X is an independent organic residue and represents one or more organic residues derived from a polyhydric alcohol having an ether bond within the molecule, provided that X can further have a branched structure having a group of formula (1) as a terminal group and a group of formula (2) as a repeating unit.
摘要翻译：一种塑料透镜材料，其包含至少一个具有式（1）作为末端基的基团和具有式（2）作为重复单元的基团，其中每个R 1独立地表示烯丙基或甲代烯丙基，并且每个A < 是独立的有机残基，代表一种或多种衍生自具有脂环结构和/或芳环结构的二元羧酸或二羧酸酐的有机残基; 其中每个A 2是独立的有机残基并且代表衍生自具有脂环结构和/或芳环结构的二元羧酸或二羧酸酐的一种或多种有机残基，并且每个X是独立的有机残基并且代表一个或更多的衍生自分子内具有醚键的多元醇的有机残基，条件是X可以进一步具有具有式（1）的基团作为末端的支链结构和作为重复单元的式（2）的基团。

10. 发明申请

WO2002079140A1 NOVEL POLYVALENT CARBOXYLIC ACID ESTERS AND THEIR USE IN PLASTIC LENS COMPOSITIONS 审中-公开
标题翻译：新型多价羧酸酯及其在塑料镜片组合物中的应用
公开(公告)号：WO2002079140A1
公开(公告)日：2002-10-10
申请号：PCT/JP2002/002155
申请日：2002-03-07
申请人： SHOWA DENKO K. K. , OOGA, Kazuhiko , TAJIMA, Tsuneo , KAI, Kazufumi , UCHIDA, Hiroshi
发明人： OOGA, Kazuhiko , TAJIMA, Tsuneo , KAI, Kazufumi , UCHIDA, Hiroshi
IPC分类号： C07C69/78
CPC分类号： C07C69/82 , C07C69/76
摘要： A compound favored with low viscosity, capable of providing a cured product having high refractive index, and suitable for application to optical materials, including plastic lens material, radical polymerizable flame retardant and the like, as well as a process for producing the compound, a plastic lens composition using the compound, a plastic lens obtained by curing the composition and a process for producing the plastic lens. A novel aromatic ring-containing polyvalent (meth)allyl ester derived from a polyvalent carboxylic acid of trivalent or greater valent is employed.
摘要翻译：具有低粘度的化合物，能够提供具有高折射率的固化产物，并且适用于光学材料，包括塑料透镜材料，自由基聚合性阻燃剂等，以及该化合物的制备方法使用该化合物的塑料透镜组合物，通过固化该组合物获得的塑料透镜和用于制造塑料透镜的方法。使用衍生自三价以上的多元羧酸的新颖的含芳环的多价（甲基）烯丙基酯。

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