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    • 4. 发明授权
    • Method and apparatus for enhancing the accuracy of CRDS measurements
    • 提高CRDS测量精度的方法和装置
    • US08264688B1
    • 2012-09-11
    • US12592559
    • 2009-11-25
    • Sze Tan
    • Sze Tan
    • G01N21/61
    • G01N21/39G01J3/28G01J3/42G01N2021/399
    • A method and apparatus for enhancing the accuracy of spectroscopic measurements using a cavity ringdown spectrometer (CRDS) is provided. A first aspect of the invention consists of a novel algorithm for the processing of ring-down data that significantly reduces the amplitude of an exponential fitting artifact, and thereby gives a better estimate of the actual loss. The primary cause of the artifact is the presence of an unwanted backwards-traveling wave that counter-propagates within the ringdown cavity. Scattering due to small imperfections at the cavity mirrors produces this wave and its intensity may be minimized by adjustment of the mirror positions during cavity construction. A second aspect of the invention consists of an apparatus for measuring the backscattered wave within a cavity to allow such cavity mirror adjustments to be made.
    • 提供了一种用于增强使用空腔衰减谱仪(CRDS)的光谱测量精度的方法和装置。 本发明的第一方面包括一种用于处理降噪数据的新算法,其显着地减少指数拟合人造物的振幅,从而给出对实际损失的更好的估计。 赝像的主要原因是存在反冲传播的不需要的向后行波。 由于腔镜的小缺陷引起的散射产生这种波,并且通过在空腔构造期间通过调整反射镜位置可以最小化其强度。 本发明的第二方面包括用于测量空腔内的后向散射波以允许进行这种空腔镜子调节的装置。
    • 8. 发明申请
    • Method and apparatus for rapidly and accurately determining a time constant from cavity ring-down data
    • 用于快速,准确地确定空腔衰减数据的时间常数的方法和装置
    • US20050012931A1
    • 2005-01-20
    • US10622323
    • 2003-07-17
    • Sze TanBernard FidricRobert Lodenkamper
    • Sze TanBernard FidricRobert Lodenkamper
    • G01J3/42G01N21/39G01N21/00
    • G01J3/42G01N21/39
    • Methods and apparatus for decreasing the time required to calculate a ring-down time from sampled ring-down data and/or increasing the accuracy of the calculated ring-down time are provided. The time required to obtain an accurate calculation of a ring-down time is reduced by performing a linear least squares fit using an estimate B1 of the background, then using the results of the fit to estimate the error in B1. The estimated error in B1 is then used to provide an improved estimate of the ring-down time. Alternatively, the time required to accurately calculate a ring-down time is reduced by averaging consecutive data points into “bins” and performing a linear least squares fit to the resulting binned signal. The parameters obtained from the fit to the binned signal are then used to obtain an improved estimate B2 of the background, and the ring-down time is calculated by performing a linear least squares fit using B2. Another method, applicable either by itself or in combination with either of the two preceding methods, is to improve accuracy by providing a low pass filter having a bandwidth related to a shortest expected ring-down time, to filter the ring-down signal before it is sampled.
    • 提供了用于减少从采样的降噪数据计算振铃时间所需的时间和/或增加计算的关闭时间的精度的方法和装置。 通过使用背景的估计B1执行线性最小二乘拟合,然后使用拟合的结果来估计B1中的误差,来减少获得准确计算消隐时间所需的时间。 然后使用B1中的估计误差来提供对减振时间的改进的估计。 或者,通过将连续的数据点平均成“bin”并对所得到的合并信号执行线性最小二乘法拟合来减少精确计算减振时间所需的时间。 然后使用从合并信号获得的参数来获得背景的改进的估计值B2,并且通过使用B2执行线性最小二乘法拟合来计算消隐时间。 另一种可以单独使用或与前述两种方法组合使用的方法之一是通过提供具有与最短期望的停机时间有关的带宽的低通滤波器来提高精度,以便在其之前对其进行滤波 被采样。
    • 10. 发明授权
    • Method and apparatus for enhancing the accuracy of CRDS measurements
    • 提高CRDS测量精度的方法和装置
    • US07646485B2
    • 2010-01-12
    • US11002603
    • 2004-12-02
    • Sze Tan
    • Sze Tan
    • G01N21/61
    • G01N21/39G01J3/28G01J3/42G01N2021/399
    • A method and apparatus for enhancing the accuracy of spectroscopic measurements using a cavity ringdown spectrometer (CRDS) is provided. A first aspect of the invention consists of a novel algorithm for the processing of ring-down data that significantly reduces the amplitude of an exponential fitting artifact, and thereby gives a better estimate of the actual loss. The primary cause of the artifact is the presence of an unwanted backwards-traveling wave that counter-propagates within the ringdown cavity. Scattering due to small imperfections at the cavity mirrors produces this wave and its intensity may be minimized by adjustment of the mirror positions during cavity construction. A second aspect of the invention consists of an apparatus for measuring the backscattered wave within a cavity to allow such cavity mirror adjustments to be made.
    • 提供了一种用于增强使用空腔衰减谱仪(CRDS)的光谱测量精度的方法和装置。 本发明的第一方面包括一种用于处理降噪数据的新算法,其显着地减少指数拟合人造物的振幅,从而给出对实际损失的更好的估计。 赝像的主要原因是存在反冲传播的不需要的向后行波。 由于腔镜的小缺陷引起的散射产生这种波,并且通过在空腔构造期间通过调整反射镜位置可以最小化其强度。 本发明的第二方面包括用于测量空腔内的后向散射波以允许进行这种空腔镜子调节的装置。