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    • 2. 发明授权
    • Method of preparing nanoparticles of lithium transition metal phosphates, lithium transition metal phosphates, and method of preparing the same
    • 锂过渡金属磷酸盐的纳米颗粒的制备方法,锂过渡金属磷酸盐及其制备方法
    • US08480987B2
    • 2013-07-09
    • US12633836
    • 2009-12-09
    • Sung Yoon Chung
    • Sung Yoon Chung
    • C01B25/30
    • C01B25/37H01M4/5825
    • Provided are lithium transition metal phosphates where the cation anti-site defects between lithium and transition metals in a lithium transition metal phosphate with a cation well-ordered olivine structure are arranged only in a 1D crystal direction, and a method of preparing the same. The method comprises adding any one selected from the group consisting of an alkali element and an element that has a valence of 5+ or any combination thereof to a solid salt comprising lithium, transition metals, and phosphorus as a starting material to produce a first intermediate material; subjecting the first intermediate to a first heat treatment at a temperature of approximately 250° C. to approximately 400° C. to produce a second amorphous material; and cooling the second intermediate material to room temperature, followed by a second heat treatment at a temperature of approximately 400° C. to approximately 800° C. to produce a final material in which the cation-distribution defect is locally clustered and the distribution has a 1D-oriented arrangement parallel to any one axis direction in the crystal.
    • 提供了锂阳离子金属磷酸盐,其中在具有阳离子良好的橄榄石结构的锂过渡金属磷酸盐中的锂和过渡金属之间的阳离子抗位点缺陷仅排列在1D晶体方向上,以及其制备方法。 该方法包括将选自碱金属元素和价数为5+的元素或其任何组合的任何一种添加到包含锂,过渡金属和磷的固体盐中作为起始材料,以产生第一中间体 材料; 在约250℃至约400℃的温度下对第一中间体进行第一次热处理以产生第二非晶材料; 并将第二中间材料冷却至室温,然后在约400℃至约800℃的温度下进行第二次热处理,以产生其中阳离子分布缺陷局部聚集并且分布具有的最终材料 与晶体中的任何一个轴方向平行的1D取向布置。
    • 3. 发明授权
    • Method for making nanoparticles of lithium transition metal phosphates
    • 制备锂过渡金属磷酸盐纳米颗粒的方法
    • US08465717B2
    • 2013-06-18
    • US12593291
    • 2007-12-28
    • Sung Yoon Chung
    • Sung Yoon Chung
    • C01B25/30
    • C01B25/45B82Y30/00H01M4/5825
    • A process for preparing a nanoparticle powder of a lithium transition metal phosphate includes mixing lithium, a transition metal and a phosphorus-containing salt as starting materials, adding an additive to the starting materials in an amount of greater than 0 at % and less than 10 at % to obtain a mixed raw material powder, subjecting the mixed powder to a first heat treatment at a temperature of 250° C. to 400° C. under a gas atmosphere for 2 to 10 hours; and subjecting the first heat-treated product to a second heat treatment at a temperature of 400° C. to 700° C. for 2 to 24 hours to uniformly form crystalline nuclei so as to induce growth of nanocrystalline particles. The additive may be any one element selected from the group consisting of sodium (Na), potassium (K), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), samarium (Sm), gadolinium (Gd) and erbium (Er).
    • 制备锂过渡金属磷酸盐的纳米颗粒粉末的方法包括将锂,过渡金属和含磷盐作为起始原料混合,向原料中加入大于0at%且小于10的量的添加剂 at%以获得混合原料粉末,在气氛下在250℃至400℃的温度下对混合粉末进行第一次热处理2至10小时; 并将第一热处理产物在400℃至700℃的温度下进行第二次热处理2至24小时以均匀地形成晶核,以诱导纳米晶体颗粒的生长。 添加剂可以是选自钠(Na),钾(K),镧(La),铈(Ce),镨(Pr),钕(Nd),钐(Sm),钆 Gd)和铒(Er)。
    • 4. 发明授权
    • Conductive lithium storage electrode
    • 导电锂储存电极
    • US08148013B2
    • 2012-04-03
    • US11901463
    • 2007-09-17
    • Yet-Ming ChiangSung-Yoon ChungJason T. BlokingAnna M. Andersson
    • Yet-Ming ChiangSung-Yoon ChungJason T. BlokingAnna M. Andersson
    • H01M4/52
    • H01M4/5825H01M4/382H01M4/523H01M4/70H01M4/74Y02C10/08Y02E60/12Y02E60/327Y02E60/328
    • A compound comprising a composition Ax(M′1-aM″a)y(XD4)z, Ax(M′1-aM″a)y(DXD4)z, or Ax(M′1-aM″a)y(X2D7)z, and have values such that x, plus y(1−a) times a formal valence or valences of M′, plus ya times a formal valence or valence of M″, is equal to z times a formal valence of the XD4, X2D7, or DXD4 group; or a compound comprising a composition (A1-aM″a)xM′y(XD4)z, (A1-aM″a)xM′y(DXD4)z (A1-aM″a)xM′y(X2D7)z and have values such that (1−a)x plus the quantity ax times the formal valence or valences of M″ plus y times the formal valence or valences of M′ is equal to z times the formal valence of the XD4, X2D7 or DXD4 group. In the compound, A is at least one of an alkali metal and hydrogen, M′ is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M″ any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001
    • 包含组合物Ax(M'1-aM“a)y(XD4)z,Ax(M'1-aM”a)y(DXD4)z或Ax(M'1-aM“a)y X2D7)z,并且具有这样的值,使得x,加y(1-a)乘以M'的正式价态或价数,加上ya乘以M“的正式价态或价数,等于z的正式化合价的z倍 XD4,X2D7或DXD4组; 或包含组合物(A1-aM“a)xM'y(XD4)z,(A1-aM”a)xM'y(DXD4)z(A1-aM“a)xM'y(X2D7)z)和 具有这样的值,使得(1-a)x加上数量ax乘以M“+ y的正式价态或价数乘以M'的正式价或价数等于XD4,X2D7或DXD4组的正式化合价的z倍 。 在化合物中,A是碱金属和氢中的至少一种,M'是第一列过渡金属,X是磷,硫,砷,钼和钨中的至少一种,M“组IIA ,IIIA,IVA,VA,VIA,VIIA,VIIIA,IB,IIB,IIIB,IVB,VB和VIB金属,D是氧,氮,碳或卤素中的至少一种,0.0001 < x,y和z大于零。 化合物在27℃下的电导率至少约为10-8S / cm。 该化合物可以是可嵌入锂或氢的掺杂磷酸锂。 该化合物可用于包括电极和蓄电池的电化学装置中,并且可以具有至少约80mAh / g的重量容量,同时以大于约C速率的化合物进行充放电。
    • 5. 发明申请
    • METHOD FOR MAKING NANOPARTICLES OF LITHIUM TRANSITION METAL PHOSPHATES
    • 制备过渡金属磷酸盐纳米粒子的方法
    • US20100074822A1
    • 2010-03-25
    • US12593291
    • 2007-12-28
    • Sung Yoon Chung
    • Sung Yoon Chung
    • C01B25/30C01B25/37
    • C01B25/45B82Y30/00H01M4/5825
    • Provided is a process for preparing a nanoparticle powder of lithium transition metal phosphate, involving synthesis of lithium transition metal phosphate (LiMPO4) (M=Fe, Mn, Co, Ni, Ti, Cu or any combination thereof) into a nanoparticle powder having a particle size of less than 100 nm to thereby significantly reduce a diffusion distance of lithium ions within particles, which consequently results in full exploitation of a capacity of an electrode material corresponding up to a theoretical capacity thereof and formation of nanoparticles having a high electrical conductivity within a short period of time, and which is also capable of achieving efficient industrial-scale production of a desired compound via a heat treatment at a low temperature of less than 600° C. for a short period of time of less than 4 hours while overcoming a shortcoming of a low electrical conductivity, using solid raw materials. The process comprises mixing lithium, a transition metal and a phosphorus-containing salt as starting materials, with addition of any one element selected from the group consisting of sodium (Na), potassium (K), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), samarium (Sm), gadolinium (Gd) and erbium (Er) in an amount of less than 10 at % to thereby inhibit nucleation in a first heat treatment, subjecting the reactants to first heat treatment at a temperature of 250° C. to 400° C. for 2 to 10 hours, and subjecting the first heat-treated materials to a second heat treatment at a temperature of 400° C. to 700° C. for 2 to 24 hours to uniformly form crystalline nuclei to induce growth of nanocrystalline particles.
    • 提供了制备锂过渡金属磷酸盐的纳米颗粒粉末的方法,包括将锂过渡金属磷酸盐(LiMPO 4)(M = Fe,Mn,Co,Ni,Ti,Cu或其任何组合)合成到具有 颗粒尺寸小于100nm,从而显着降低了锂离子在颗粒内的扩散距离,从而导致充分利用相当于其理论容量的电极材料的容量,并形成具有高电导率的纳米颗粒 短时间内,还可以通过在小于600℃的低温下的热处理在短时间内小于4小时的时间内实现有效的工业规模生产所需化合物,同时克服 导电性低的缺点,使用固体原料。 该方法包括将锂,过渡金属和含磷盐作为原料混合,加入选自钠(Na),钾(K),镧(La),铈(Ce) ,镨(Pr),钕(Nd),钐(Sm),钆(Gd)和铒(Er),其量小于10原子%,从而在第一热处理中抑制成核,使反应物首先加热 在250℃至400℃的温度下处理2至10小时,并将第一热处理材料在400℃至700℃的温度下进行第二次热处理2至24次 小时以均匀地形成晶核以诱导纳米晶体颗粒的生长。
    • 7. 发明申请
    • Conductive lithium storage electrode
    • 导电锂储存电极
    • US20090311597A1
    • 2009-12-17
    • US11901463
    • 2007-09-17
    • Yet-Ming ChiangSung-Yoon ChungJason T. BlokingAnna M. Andersson
    • Yet-Ming ChiangSung-Yoon ChungJason T. BlokingAnna M. Andersson
    • H01M4/58H01M4/36H01M4/50H01M4/52H01M4/60
    • H01M4/5825H01M4/382H01M4/523H01M4/70H01M4/74Y02C10/08Y02E60/12Y02E60/327Y02E60/328
    • A compound comprising a composition Ax(M′1-aM″a)y(XD4)z, Ax(M′1-aM″a)y(DXD4)z, or Ax(M′1-aM″a)y(X2D7)z, and have values such that x, plus y(1−a) times a formal valence or valences of M′, plus ya times a formal valence or valence of M″, is equal to z times a formal valence of the XD4, X2D7, or DXD4 group; or a compound comprising a composition (A1-aM″a)xM′y(XD4)z, (A1-aM″a)xM′y(DXD4)z (A1-aM″a)xM′y(X2D7)z and have values such that (1−a)x plus the quantity ax times the formal valence or valences of M″ plus y times the formal valence or valences of M′ is equal to z times the formal valence of the XD4, X2D7 or DXD4 group. In the compound, A is at least one of an alkali metal and hydrogen, M′ is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M″ any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001
    • 包含组合物Ax(M'1-aM'a)y(XD4)z,Ax(M'1-aM'a)y(DXD4)z或Ax(M'1-aM'a) )y(X2D7)z,并且具有这样的值,使得x,加y(1-a)乘以M'的正式价或价数,加上ya乘以M“的正式价或价数,等于z乘以 XD4,X2D7或DXD4组的正价; 或包含组合物(A1-aM'a)xM'y(XD4)z,(A1-aM'a)xM'y(DXD4)z(A1-aM'a)xM'y(X2D7) )z,并且具有这样的值,使得(1-a)x加上数量ax乘以M'+ y的形式价态或价数乘以M'的正式价或价数等于XD4的正式价的z倍, X2D7或DXD4组。 在化合物中,A为碱金属和氢中的至少一种,M'为第一列过渡金属,X为磷,硫,砷,钼,钨中的至少一种,M“为 IIA,IIIA,IVA,VA,VIA,VIIA,VIIIA,IB,IIB,IIIB,IVB,VB和VIB金属,D为氧,氮,碳或卤素中的至少一种,0.0001
    • 8. 发明授权
    • Method for single crystal growth of barium titanate and barium titanate solid solution
    • 钛酸钡和钛酸钡固溶体的单晶生长方法
    • US06758898B2
    • 2004-07-06
    • US10163526
    • 2002-06-07
    • Ho-Yong LeeJao-Suk KimJong-Bong LeeTae-Moo HurDoe-Yeon KimNong-Moon HwangByoung-Ki LeeSung-Yoon ChungSuk-Joong L. Kang
    • Ho-Yong LeeJao-Suk KimJong-Bong LeeTae-Moo HurDoe-Yeon KimNong-Moon HwangByoung-Ki LeeSung-Yoon ChungSuk-Joong L. Kang
    • C30B102
    • C30B11/00C30B29/32
    • The invention relates to a method for growing single crystals of barium titanate [BaTiO3] and barium titanate solid solutions [(BaxM1−x)(TiyN1−y)O3]. This invention is directed to a method for growing single crystals of barium titanate or barium titanate solid solutions showing the primary and secondary abnormal grain growths with increasing temperature higher than the liquid formation temperature, characterized by comprising the step for a few secondary abnormal grains to continue to grow at a temperature slightly below the critical temperature where the secondary abnormal grain growth starts to occur. The method for growing single crystals of barium titanate or barium titanate solid solutions according to this invention has the advantage of providing an effective low cost in manufacturing process for single crystals by using a conventional heat-treatment process without the need of special equipment. The method for growing single crystals of barium titanate and barium titanate solid solutions according to this invention is also applicable to other material systems showing abnormal grain growth behavior.
    • 本发明涉及一种生长钛酸钡[BaTiO3]和钛酸钡固溶体[(BaxM1-x)(TiyN1-y)O3]单晶的方法。 本发明涉及一种用于生长钛酸钡或钛酸钡固体溶液的单晶的方法,其显示出主要和次要的异常晶粒生长,其温度高于液体形成温度,其特征在于包括少量次级异常晶粒继续的步骤 在略低于次生异常晶粒生长开始发生的临界温度的温度下生长。 根据本发明的用于生长钛酸钡或钛酸钡固溶体的单晶的方法具有通过使用常规热处理工艺而不需要特殊设备来提供单晶制造工艺的有效低成本的优点。 根据本发明的用于生长钛酸钡和钛酸钡固溶体的单晶的方法也适用于显示异常晶粒生长行为的其它材料体系。
    • 10. 发明申请
    • METHOD OF PREPARING NANOPARTICLES OF LITHIUM TRANSITION METAL PHOSPHATES, LITHIUM TRANSITION METAL PHOSPHATES, AND METHOD OF PREPARING THE SAME
    • 制备过渡金属磷酸盐的纳米颗粒,过渡金属磷酸锂的方法及其制备方法
    • US20100086461A1
    • 2010-04-08
    • US12633836
    • 2009-12-09
    • Sung Yoon CHUNG
    • Sung Yoon CHUNG
    • C01B25/30
    • C01B25/37H01M4/5825
    • Provided are lithium transition metal phosphates where the cation anti-site defects between lithium and transition metals in a lithium transition metal phosphate with a cation well-ordered olivine structure are arranged only in a 1D crystal direction, and a method of preparing the same. The method comprises adding any one selected from the group consisting of an alkali element and an element that has a valence of 5+ or any combination thereof to a solid salt comprising lithium, transition metals, and phosphorus as a starting material to produce a first intermediate material; subjecting the first intermediate to a first heat treatment at a temperature of approximately 250° C. to approximately 400° C. to produce a second amorphous material; and cooling the second intermediate material to room temperature, followed by a second heat treatment at a temperature of approximately 400° C. to approximately 800° C. to produce a final material in which the cation-distribution defect is locally clustered and the distribution has a 1D-oriented arrangement parallel to any one axis direction in the crystal.
    • 提供了锂阳离子金属磷酸盐,其中在具有阳离子良好的橄榄石结构的锂过渡金属磷酸盐中的锂和过渡金属之间的阳离子抗位点缺陷仅排列在1D晶体方向上,以及其制备方法。 该方法包括将选自碱金属元素和价数为5+的元素或其任何组合的任何一种添加到包含锂,过渡金属和磷的固体盐中作为起始材料,以产生第一中间体 材料; 在约250℃至约400℃的温度下对第一中间体进行第一次热处理以产生第二非晶材料; 并将第二中间材料冷却至室温,然后在约400℃至约800℃的温度下进行第二次热处理,以产生其中阳离子分布缺陷局部聚集并且分布具有的最终材料 与晶体中的任何一个轴方向平行的1D取向布置。