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    • 10. 发明授权
    • Soluble conductive polymer manufacturing method thereof and display
device employing the same
    • 可溶性导电聚合物的制造方法和使用其的显示装置
    • US5616669A
    • 1997-04-01
    • US471385
    • 1995-06-06
    • Sung-ho JinShin-woong Kang
    • Sung-ho JinShin-woong Kang
    • C08F38/02C08F38/00C08F138/00
    • C08F38/00
    • A method of manufacturing a soluble conductive poly acetylene derivative represented by the following formula (I) including the steps of synthesizing a propargyl derivative by reacting a propargyl halogenide and an alkyne derivative and polymerizing the propargyl derivative in the presence of a transition metal catalyst. The thus obtained novel soluble conductive polymer can be used in a display device. ##STR1## (wherein, X is oxygen atom or sulfur atom, R.sub.1 and R.sub.2 are independently selected from the group consisting of hydrogen, C.sub.2 -C.sub.10 alkyl, C.sub.2 -C.sub.10 alkenyl; or when one of R.sub.1 and R.sub.2 is phenyl, the other is hydrogen or C.sub.1 -C.sub.10 alkyl, n is an integer between 50.about.200). The soluble conductive polymer of the present invention can be easily polymerized and has good stability and electrochromic characteristics when applied to display devices.
    • 一种制备由下式(I)表示的可溶性导电聚乙炔衍生物的方法,包括通过使炔丙基卤化物和炔衍生物反应合成炔丙基衍生物并在过渡金属催化剂存在下聚合炔丙基衍生物的步骤。 由此获得的新型可溶性导电聚合物可用于显示装置。 (I)(I)(其中X是氧原子或硫原子,R 1和R 2独立地选自氢,C 2 -C 10烷基,C 2 -C 10烯基;或者当R 1和R 2之一是苯基时, 另一个是氢或C 1 -C 10烷基,n是50分之间的整数200)。 当应用于显示装置时,本发明的可溶性导电聚合物可以容易地聚合并具有良好的稳定性和电致变色特性。