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    • 2. 发明授权
    • Conductive polymer films grafted on organic substrates
    • 导电聚合物膜接枝在有机基底上
    • US09530965B2
    • 2016-12-27
    • US14331891
    • 2014-07-15
    • Karen K. GleasonSung Gap Im
    • Karen K. GleasonSung Gap Im
    • C08G73/06B05D3/12C08L67/00H01L51/00B05D1/00C08G61/12C09D165/00C09D179/02B05D1/18B05D3/10G02F1/15
    • H01L51/0037B05D1/185B05D1/60B05D3/10C08G61/124C08G61/125C08G61/126C09D165/00C09D179/02G02F2001/1515
    • One aspect of the invention relates to a linker-free, one-step method of grafting polymer films onto organic substrates, and the films obtained by such a method. In certain embodiments, the grafted polymer films are conductive. In certain embodiments, said grafting method utilizes the ability for Friedel-Crafts catalyst to form radical cations from organic substrates. In one embodiment, the method provides poly-3,4-ethylenedioxythiophene (PEDOT) thin films grafted to organic substrates. In other embodiments, the method is applicable to the polymerization of other monomers to yield conducting polymers, such as polyanilines, polypyrroles, polyfurans, polythiophenes and their derivatives. Remarkably, the polymer films grafted by the inventive methods show enormous increases in adhesion strength. Further, in certain embodiments, polymer patterns were easily obtained using the inventive methods and soft lithography techniques. In certain embodiments, well-defined high-density line-and-space patterns were successfully obtained. In certain embodiments, e.g., when the polymer film is conducting, the obtained conducting polymer pattern grafted on common organic substrates can be used for integrated circuitry in flexible electronics.
    • 本发明的一个方面涉及将聚合物膜接枝到有机基底上的无接头的一步法,以及通过这种方法获得的膜。 在某些实施方案中,接枝的聚合物膜是导电的。 在某些实施方案中,所述接枝方法利用了Friedel-Crafts催化剂从有机底物形成自由基阳离子的能力。 在一个实施方案中,该方法提供接枝到有机基底上的聚3,4-亚乙基二氧噻吩(PEDOT)薄膜。 在其它实施方案中,该方法适用于其它单体的聚合以产生导电聚合物,例如聚苯胺,聚吡咯,聚呋喃,聚噻吩及其衍生物。 显着地,通过本发明方法接枝的聚合物膜显示出粘合强度的巨大增加。 此外,在某些实施方案中,使用本发明的方法和软光刻技术容易地获得聚合物图案。 在某些实施例中,成功地获得了明确定义的高密度线和空间图案。 在某些实施方案中,例如,当聚合物膜导电时,所获得的接枝在共同有机衬底上的导电聚合物图案可用于柔性电子器件中的集成电路。
    • 6. 发明申请
    • Conductive Polymer Films Grafted on Organic Substrates
    • 导电聚合物膜接枝在有机基板上
    • US20100048830A1
    • 2010-02-25
    • US12525376
    • 2008-01-31
    • Karen K. GleasonSung Gap Im
    • Karen K. GleasonSung Gap Im
    • C08G73/06B05D3/12C08L67/00
    • H01L51/0037B05D1/185B05D1/60B05D3/10C08G61/124C08G61/125C08G61/126C09D165/00C09D179/02G02F2001/1515
    • One aspect of the invention relates to a linker-free, one-step method of grafting polymer films onto organic substrates, and the films obtained by such a method. In certain embodiments, the grafted polymer films are conductive. In certain embodiments, said grafting method utilizes the ability for Friedel-Crafts catalyst to form radical cations from organic substrates. In one embodiment, the method provides poly-3,4-ethylenedioxythiophene (PEDOT) thin films grafted to organic substrates. In other embodiments, the method is applicable to the polymerization of other monomers to yield conducting polymers, such as polyanilines, polypyrroles, polyfurans, polythiophenes and their derivatives. Remarkably, the polymer films grafted by the inventive methods show enormous increases in adhesion strength. Further, in certain embodiments, polymer patterns were easily obtained using the inventive methods and soft lithography techniques. In certain embodiments, well-defined high-density line-and-space patterns were successfully obtained. In certain embodiments, e.g., when the polymer film is conducting, the obtained conducting polymer pattern grafted on common organic substrates can be used for integrated circuitry in flexible electronics.
    • 本发明的一个方面涉及将聚合物膜接枝到有机基底上的无接头的一步法,以及通过这种方法获得的膜。 在某些实施方案中,接枝的聚合物膜是导电的。 在某些实施方案中,所述接枝方法利用了Friedel-Crafts催化剂从有机底物形成自由基阳离子的能力。 在一个实施方案中,该方法提供接枝到有机基底上的聚3,4-亚乙基二氧噻吩(PEDOT)薄膜。 在其它实施方案中,该方法适用于其它单体的聚合以产生导电聚合物,例如聚苯胺,聚吡咯,聚呋喃,聚噻吩及其衍生物。 显着地,通过本发明方法接枝的聚合物膜显示出粘合强度的巨大增加。 此外,在某些实施方案中,使用本发明的方法和软光刻技术容易获得聚合物图案。 在某些实施例中,成功地获得了明确定义的高密度线和空间图案。 在某些实施方案中,例如,当聚合物膜导电时,所获得的接枝在共同有机衬底上的导电聚合物图案可用于柔性电子器件中的集成电路。
    • 10. 发明申请
    • Conductive Polymer Films Grafted on Organic Substrates
    • 导电聚合物膜接枝在有机基板上
    • US20150079282A1
    • 2015-03-19
    • US14331891
    • 2014-07-15
    • Karen K. GleasonSung Gap Im
    • Karen K. GleasonSung Gap Im
    • H01L51/00
    • H01L51/0037B05D1/185B05D1/60B05D3/10C08G61/124C08G61/125C08G61/126C09D165/00C09D179/02G02F2001/1515
    • One aspect of the invention relates to a linker-free, one-step method of grafting polymer films onto organic substrates, and the films obtained by such a method. In certain embodiments, the grafted polymer films are conductive. In certain embodiments, said grafting method utilizes the ability for Friedel-Crafts catalyst to form radical cations from organic substrates. In one embodiment, the method provides poly-3,4-ethylenedioxythiophene (PEDOT) thin films grafted to organic substrates. In other embodiments, the method is applicable to the polymerization of other monomers to yield conducting polymers, such as polyanilines, polypyrroles, polyfurans, polythiophenes and their derivatives. Remarkably, the polymer films grafted by the inventive methods show enormous increases in adhesion strength. Further, in certain embodiments, polymer patterns were easily obtained using the inventive methods and soft lithography techniques. In certain embodiments, well-defined high-density line-and-space patterns were successfully obtained. In certain embodiments, e.g., when the polymer film is conducting, the obtained conducting polymer pattern grafted on common organic substrates can be used for integrated circuitry in flexible electronics.
    • 本发明的一个方面涉及将聚合物膜接枝到有机基底上的无接头的一步法,以及通过这种方法获得的膜。 在某些实施方案中,接枝的聚合物膜是导电的。 在某些实施方案中,所述接枝方法利用了Friedel-Crafts催化剂从有机底物形成自由基阳离子的能力。 在一个实施方案中,该方法提供接枝到有机基底上的聚3,4-亚乙基二氧噻吩(PEDOT)薄膜。 在其它实施方案中,该方法适用于其它单体的聚合以产生导电聚合物,例如聚苯胺,聚吡咯,聚呋喃,聚噻吩及其衍生物。 显着地,通过本发明方法接枝的聚合物膜显示出粘合强度的巨大增加。 此外,在某些实施方案中,使用本发明的方法和软光刻技术容易地获得聚合物图案。 在某些实施例中,成功地获得了明确定义的高密度线和空间图案。 在某些实施方案中,例如,当聚合物膜导电时,所获得的接枝在共同有机衬底上的导电聚合物图案可用于柔性电子器件中的集成电路。