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    • 1. 发明授权
    • Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks
    • 具有改进的颗粒内和颗粒间交联的浸渍合成聚异戊二烯胶乳制品
    • US08087412B2
    • 2012-01-03
    • US12194118
    • 2008-08-19
    • David M. LucasSugath AmarasekeraDave NarasimhanAdeline Ai Lin Kung
    • David M. LucasSugath AmarasekeraDave NarasimhanAdeline Ai Lin Kung
    • A61F6/02
    • C08F136/08A41D19/0055A41D19/0082A61B42/10A61F6/04A61F2006/043B29L2031/4864B32B27/32C08L9/00C08L23/20Y10T428/2982Y10T428/31924C08L2666/02
    • A synthetic polyisoprene latex emulsion has pre-vulcanization composition and post vulcanization composition. The pre-vulcanization composition comprises soluble sulfur with high S8 ring structure that is catalytically broken by a zinc dithiocarbamate. Surfactants present in the pre-vulcanization composition wets synthetic polyisoprene particles and permeates small sized sulfur and accelerator molecules into the interior of these particles thereby pre-vulcanizing the particles. The degree of pre-vulcanization is verified by isopropanol index test. The latex emulsion has post-vulcanization composition with accelerators that crosslink inter-particle region during post vulcanization cure cycle. The dipped synthetic polyisoprene article is substantially uniformly cured both in the inter-particle and intra-particle regions and reliably exhibits high cross link density, uniform distribution of double bonds in TEM and zinc segregation at the boundaries or original particles by electron microprobe analysis. The films exhibit high tensile strength, tensile modulus, tear strength, burst pressure and burst volume.
    • 合成聚异戊二烯胶乳乳液具有预硫化组合物和后硫化组合物。 预硫化组合物包含由二硫代氨基甲酸锌催化破坏的具有高S8环结构的可溶性硫。 存在于预硫化组合物中的表面活性剂润湿合成的聚异戊二烯颗粒,并将小尺寸的硫和促进剂分子渗透到这些颗粒的内部,从而预先硫化颗粒。 通过异丙醇指数试验验证预硫化程度。 胶乳乳液具有后硫化组合物,其具有在后硫化固化循环中交联颗粒间区域的促进剂。 浸渍的合成聚异戊二烯制品在颗粒间和颗粒内区域基本上均匀地固化,并且可靠地表现出高的交联密度,TEM中双键的均匀分布和边界处的锌偏析或通过电子微探针分析的原始颗粒。 该膜具有高拉伸强度,拉伸模量,撕裂强度,爆裂压力和爆破体积。