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    • 8. 发明申请
    • DETERGENTS BASED ON ALPHA-SULFONATED FATTY ESTER SURFACTANTS
    • 基于ALPHA-SULFONATED FATTY ESTER SURFACTANT的洗涤剂
    • WO2016160407A1
    • 2016-10-06
    • PCT/US2016/023525
    • 2016-03-22
    • STEPAN COMPANY
    • HOLLAND, BrianBERNHARDT, Randal, J.SAJIC, BrankoTABOR, Rick
    • C11D1/37C11D1/83
    • C11D1/28C11D1/29C11D1/37C11D1/83C11D11/0017
    • Laundry detergents useful for cold-water cleaning and a cold-water cleaning method are disclosed. The detergents comprise: (a) an a-sulfonated fatty ester surfactant comprising a compound having the formula: R 1 -CH(SO 3 M)-CO-OR 2 wherein M is hydrogen, an alkali metal, an alkaline earth metal, ammonium, and amine salt, or a mixture thereof; R 1 is an unsubstituted or hydroxy-substituted, saturated or unsaturated, linear or branched C 6 -C 16 alkyl group; and R 2 is a saturated or unsaturated linear or branched C 8 to C 12 alkyl group; and (b) an anionic surfactant, a nonionic surfactant, or a combination thereof. Surprisingly, α-sulfonated fatty ester surfactants derived from a C 8 to C 12 alcohol provide outstanding performance in removing greasy stains such as bacon grease, cooked beef fat, or beef tallow from soiled articles even at wash temperatures at or below 30°C. Detergents formulated with the surfactants outperform control cold-water detergents by a wide margin, including detergents comprising α-sulfonated fatty esters made from lower alcohols, such as methyl, butyl, or hexyl esters of α-sulfonated fatty acids.
    • 公开了用于冷水清洗的洗涤剂和冷水清洗方法。 洗涤剂包括:(a)包含具有下式的化合物的α-磺化脂肪酯表面活性剂:R1-CH(SO3M)-CO-OR2,其中M是氢,碱金属,碱土金属,铵和胺盐 ,或其混合物; R1是未取代或羟基取代的饱和或不饱和的直链或支链C 6 -C 16烷基; R2是饱和或不饱和的直链或支链C 8〜C 12烷基; 和(b)阴离子表面活性剂,非离子表面活性剂或其组合。 令人惊奇的是,即使在30℃以下的洗涤温度下,来自C8〜C12醇的α-磺化脂肪酸酯表面活性剂也可以在清除油污,煮熟的牛脂或牛脂等脏污物质方面表现出突出的表现。 用表面活性剂配制的洗涤剂大大控制冷水洗涤剂,包括由低级醇形成的α-磺化脂肪酸酯如α-磺化脂肪酸的甲基,丁基或己基酯的去污剂。