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1. 发明授权

US07683145B2 Method for the emulsion polymerization of olefins 失效
标题翻译：烯烃乳液聚合方法
公开(公告)号：US07683145B2
公开(公告)日：2010-03-23
申请号：US10521117
申请日：2003-07-16
申请人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian M. Bauers
发明人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian M. Bauers
IPC分类号： C08F4/00 , C08F2/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/26 , C08F2/24 , C08F4/80 , C08F2500/02 , C08F2500/03 , C08F210/14 , C08F212/08 , C08F210/06 , C08F210/08
摘要： A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups, and wherein identical or different compounds of general formulae Ia and Ib can, optionally, be concatenated by one or several bridges, with a phosphine compound PR3′ and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z, wherein the variables are defined as follows: M is a transition metal of groups 7-10 in the periodic system of the elements; L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0-3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-alkyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.
摘要翻译：通过使通式Ia和Ib的配体或至少两种配体Ia或Ib的混合物反应来使一种或多种烯烃乳液聚合的方法，其中R分别表示一个或几个以下基团; 氢，卤素，腈，C 1 -C 12 - 烷基，C 1 -C 12 - 烷氧基，C 7 -C 13 - 芳烷基，C 6 -C 14 - 芳基，并且其中相同或不同的通式Ia和Ib化合物可以任选地，通过一个或几个桥连，与膦化合物PR3'和通式M（L2）2或M（L2）2（L1）z的金属化合物连接，其中变量定义如下：M是过渡金属在元素周期性系统中的第7-10组; L1代表具有相同或不同基团的磷烷（R5）xPH3-x或具有相同或不同基团的胺（R5）xNH3-x5，醚（R5）2O，H2O，烷醇（R5）OH，吡啶，式C5H5-x（R5） xN，CO，C 1 -C 12烷基腈，C 6 -C 14 - 芳基腈或烯属不饱和双键体系，其中x为0-3的整数，L 2表示卤化物离子R 6 x N H 3-x，其中x为 O 3和R 6表示C 1 -C 12 - 烷基和C 1 -C 6 - 烷基离子，烯丙基离子，苯甲烷离子或芳基烷基离子，其中L1和L2可以通过一个或几个共价键彼此连接，z是数字范围本发明还涉及立即使用反应产物在烯烃在水中或在含有至少50体积％的溶剂混合物中的聚合或共聚中。在乳化剂存在下，和任选地，在活化剂存在下，水分。

2. 发明申请

US20130030075A1 POLYMERS MADE OF RENEWABLE RESOURCES 有权
标题翻译：可再生能源的聚合物
公开(公告)号：US20130030075A1
公开(公告)日：2013-01-31
申请号：US13575155
申请日：2011-01-24
申请人： Stefan Mecking , Dorothee Quinzler
发明人： Stefan Mecking , Dorothee Quinzler
IPC分类号： C08G63/16 , C07C51/14 , C07C67/38 , C08G69/26 , C08G69/08
CPC分类号： C08G69/265 , C07C67/38 , C08G18/3206 , C08G18/3228 , C08G18/73 , C08G18/771 , C08G63/16 , C08G69/26 , C08G69/34 , C07C69/34
摘要： Polycondensates with long-chain linear methylene sequences, their production, a method for producing linear odd-numbered C>20 α,ω-dicarboxylic acids and derivatives thereof and applications of the polycondensates are described.
摘要翻译：描述了具有长链线性亚甲基序列的缩聚物，它们的生产，线性奇数C>20α，ω-二羧酸及其衍生物的生产方法和缩聚物的应用。

3. 发明申请

US20050250920A1 Preparation of aqueous polymer dispersions 失效
标题翻译：聚合物水分散体的制备
公开(公告)号：US20050250920A1
公开(公告)日：2005-11-10
申请号：US10524216
申请日：2003-07-24
申请人： Mubarik Chowdhry , Markus Schmid , Peter Preishuber-Pflugl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian Bauers
发明人： Mubarik Chowdhry , Markus Schmid , Peter Preishuber-Pflugl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian Bauers
IPC分类号： C08F2/24 , C08F4/26 , C08F4/80 , C08F10/00 , C08F110/02 , C08F4/00
CPC分类号： C08F110/02 , C08F4/80 , C08F2/24
摘要： A process for preparing aqueous polymer dispersions by polymerizing one or more olefins in an aqueous medium in the presence of dispersants and, if desired, of organic solvents comprises catalyzing the polymerization of said olefin(s) using one or more metal complex compounds of the formula I where at least one of the radicals R1 to R9 is necessarily in the form of a radical of the formula II below where Z is an electron-withdrawing group and n is an integer from 1 to 5.
摘要翻译：通过在水性介质中在分散剂和如果需要的情况下，有机溶剂的存在下使一种或多种烯烃聚合制备水性聚合物分散体的方法包括使用一种或多种下式的金属配合物催化所述烯烃的聚合：其中基团R 1至R 9中的至少一个必须具有以下式II的基团的形式，其中Z是吸电子基团，n 是从1到5的整数。

4. 发明授权

US5808121A Catalyst compositions and process of making polyketones therewith 失效
标题翻译：催化剂组合物及其制备方法
公开(公告)号：US5808121A
公开(公告)日：1998-09-15
申请号：US599704
申请日：1996-02-12
申请人： Wilhelm Keim , Stefan Mecking
发明人： Wilhelm Keim , Stefan Mecking
IPC分类号： B01J31/24 , C08G67/02 , C07F15/00 , B01J27/185 , B01J31/00 , C07F17/02
CPC分类号： B01J31/2247 , B01J31/2291 , B01J31/2404 , C08G67/02 , B01J2231/10 , B01J2231/12 , B01J2531/80 , B01J2531/824
摘要： There is disclosed a catalyst composition prepared by reacting together: (a) a source of a Group VIII metal, (b) a compound of the formula (I) R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3 (I) where R.sup.1 and R.sup.2 are independently an unsubstituted or substituted alkyl, cycloalkyl or aryl group, R.sup.3 is hydrogen, an unsubstituted or substituted alkyl, cycloalkyl or aryl group and R.sup.4 is a divalent organic group and (c) a source of an anion which is either non-coordinating or weakly-coordinating to the Group VIII metal. The catalyst compositions are used in the preparation of polyketones from carbon monoxide and one or more olefins. Novel compounds of the formula �(.eta..sup.3 -allyl)Pd(R.sub.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3)!A where A is a weakly or non-coordinating anion are useful as such catalysts.
摘要翻译：公开了通过一起反应制备的催化剂组合物：（a）VIII族金属源，（b）式（I）的化合物，R1R2PR4CO2R3（Ⅰ），其中R1和R2独立地是未取代或取代的烷基，环烷基或芳基，R 3是氢，未取代或取代的烷基，环烷基或芳基，R 4是二价有机基团，和（c）与VIII族金属是非配位或弱配位的阴离子源。催化剂组合物用于从一氧化碳和一种或多种烯烃制备聚酮。式[（η3-烯丙基）Pd（R1R2PR4CO2R3）] A的新型化合物，其中A是弱或非配位阴离子可用作这种催化剂。

5. 发明授权

US5525566A Palladium phosphine ligand catalyst 失效
标题翻译：钯膦配体催化剂
公开(公告)号：US5525566A
公开(公告)日：1996-06-11
申请号：US218518
申请日：1994-03-25
申请人： Wilhelm Keim , Stefan Mecking
发明人： Wilhelm Keim , Stefan Mecking
IPC分类号： B01J31/24 , C08G67/02 , B01J31/00
CPC分类号： B01J31/2247 , B01J31/2291 , B01J31/2404 , C08G67/02 , B01J2231/10 , B01J2231/12 , B01J2531/80 , B01J2531/824
摘要： There is disclosed a catalyst composition prepared by reacting together:(a) a source of a Group VIII metal,(b) a compound of the formula (I)R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3 (I) where R.sup.1 and R.sup.2 are independently an unsubstituted or substituted alkyl, cycloalkyl or aryl group, R.sup.3 is hydrogen, an unsubstituted or substituted alkyl, cycloalkyl or aryl group and R.sup.4 is a divalent organic group and(c) a source of an anion which is either non-coordinating or weakly-coordinating to the Group VIII metal.The catalyst compositions are used in the preparation of polyketones from carbon monoxide and one or more olefins. Novel compounds of the formula [(.eta..sup.3 -allyl)Pd(R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3)]Y where Y is a weakly or non-coordinating anion are useful as such catalysts.
摘要翻译：公开了通过一起反应制备的催化剂组合物：（a）VIII族金属源，（b）式（I）的化合物，R1R2PR4CO2R3（Ⅰ），其中R1和R2独立地是未取代或取代的烷基，环烷基或芳基，R 3是氢，未取代或取代的烷基，环烷基或芳基，R 4是二价有机基团，和（c）与VIII族金属是非配位或弱配位的阴离子源。催化剂组合物用于从一氧化碳和一种或多种烯烃制备聚酮。其中Y是弱或非配位阴离子的式[（η3-烯丙基）Pd（R1R2PR4CO2R3）] Y的新化合物可用作这样的催化剂。

6. 发明授权

US09096715B2 Polymers made of renewable resources 有权
标题翻译：由可再生资源制成的聚合物
公开(公告)号：US09096715B2
公开(公告)日：2015-08-04
申请号：US13575155
申请日：2011-01-24
申请人： Stefan Mecking , Dorothee Quinzler
发明人： Stefan Mecking , Dorothee Quinzler
IPC分类号： C08G63/02 , C08G69/26 , C07C67/38 , C08G18/32 , C08G18/73 , C08G18/77 , C08G63/16 , C08G69/34
CPC分类号： C08G69/265 , C07C67/38 , C08G18/3206 , C08G18/3228 , C08G18/73 , C08G18/771 , C08G63/16 , C08G69/26 , C08G69/34 , C07C69/34
摘要： Polycondensates with long-chain linear methylene sequences, their production, a method for producing linear odd-numbered C>20 α,ω-dicarboxylic acids and derivatives thereof and applications of the polycondensates are described.
摘要翻译：描述了具有长链线性亚甲基序列的缩聚物，它们的生产，线性奇数C>20α，ω-二羧酸及其衍生物的生产方法和缩聚物的应用。

7. 发明授权

US07417098B2 Method for emulsion polymerisation of olefins 失效
标题翻译：烯烃乳液聚合方法
公开(公告)号：US07417098B2
公开(公告)日：2008-08-26
申请号：US10579098
申请日：2004-11-06
申请人： Mubarik Mahmood Chowdhry , Xavier Sava , Monica Haag , Jacob Wildeson , Stefan Mecking , Ludmila Kolb
发明人： Mubarik Mahmood Chowdhry , Xavier Sava , Monica Haag , Jacob Wildeson , Stefan Mecking , Ludmila Kolb
IPC分类号： C08F4/42
CPC分类号： C08F110/02 , C08F2/22 , C08F4/80
摘要： Process for the emulsion polymerization of one or more olefins by reacting a quinoid compound with a metal compound and a phosphine compound which is substituted by at least one polar radical and subsequently using the reaction product for the polymerization or copolymerization of olefins in water or in a solvent mixture which contains at least 50% by weight of water and at least one emulsifier.
摘要翻译：通过使喹啉化合物与金属化合物反应并被至少一个极性基团取代的膦化合物反应并随后使用反应产物在烯烃在水中或在水中的聚合或共聚来使一种或多种烯烃乳液聚合的方法溶剂混合物，其含有至少50重量％的水和至少一种乳化剂。

8. 发明申请

US20050261452A1 Method for the emulsion polymerization of olefins 失效
公开(公告)号：US20050261452A1
公开(公告)日：2005-11-24
申请号：US10521117
申请日：2003-07-16
申请人： Mubarik Chowdhry , Markus Schmid , Peter Preishuber-Pflugl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian Bauers
发明人： Mubarik Chowdhry , Markus Schmid , Peter Preishuber-Pflugl , Xavier Sava , Horst Weiss , Stefan Mecking , Florian Bauers
IPC分类号： C08F2/22 , C08F2/24 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/06
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/26 , C08F2/24 , C08F4/80 , C08F2500/02 , C08F2500/03 , C08F210/14 , C08F212/08 , C08F210/06 , C08F210/08
摘要： A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups, and wherein identical or different compounds of general formulae Ia and Ib can, optionally, with a phosphine compound PR3′ and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z, wherein the variables are defined as follows: M is a transition metal of groups 7-10 in the periodic system of the elements; L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0-3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-allyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.

9. 发明授权

US07566760B2 Preparation of aqueous polymer dispersions 失效
标题翻译：聚合物水分散体的制备
公开(公告)号：US07566760B2
公开(公告)日：2009-07-28
申请号：US10524216
申请日：2003-07-24
申请人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian M. Bauers
发明人： Mubarik Mahmood Chowdhry , Markus Schmid , Peter Preishuber-Pfluegl , Xavier Sava , Horst Weiss , Stefan Mecking , Martin Zuideveld , Florian M. Bauers
IPC分类号： C08F4/26 , C08F4/70 , C08F2/22
CPC分类号： C08F110/02 , C08F4/80 , C08F2/24
摘要： The invention relates to a method for the production of aqueous polymer dispersions, by the polymerisation of one or more olefins in aqueous media in the presence of dispersing agents and optionally organic solvents, characterised in that the polymerisation of the olefin(s) is catalysed by means of one or more complex compounds of general formula (I), where at least one of the groups R1 to R9 must be in the form of a group of the following general formula (II) where Z=an electron-withdrawing group and n=a whole number from 1 to 5.
摘要翻译：本发明涉及通过在分散剂和任选的有机溶剂的存在下在水性介质中聚合一种或多种烯烃的方法来制备聚合物水分散体，其特征在于烯烃的聚合由一种或多种通式（I）的络合物的手段，其中基团R 1至R 9中的至少一个必须为以下通式（II）的基团的形式，其中Z =吸电子基团和n =从1到5的整数。

10. 发明申请

US20080182915A1 METHOD FOR EMULSION POLYMERISATION OF OLEFINS 审中-公开
标题翻译：油脂乳液聚合方法
公开(公告)号：US20080182915A1
公开(公告)日：2008-07-31
申请号：US12060503
申请日：2008-04-01
申请人： Mubarik Mahmood Chowdhry , Xavier Sava , Monica Haag , Jacob Wildeson , Stefan Mecking , Ludmila Kolb
发明人： Mubarik Mahmood Chowdhry , Xavier Sava , Monica Haag , Jacob Wildeson , Stefan Mecking , Ludmila Kolb
IPC分类号： C08J9/28 , C08F4/42 , A61K47/30
CPC分类号： C08F110/02 , C08F2/22 , C08F4/80
摘要： Process for the emulsion polymerization of one or more olefins by preparing a catalyst by reacting a quinoid compound with a metal compound and a phosphine compound which is substituted by at least one polar radical; and subsequently (co)polymerizing said one or more olefins in water or in a solvent mixture which contains at least 50% by weight of water and at least one emulsifier.
摘要翻译：通过使喹啉化合物与金属化合物反应制备催化剂和被至少一个极性基团取代的膦化合物来进行一种或多种烯烃的乳液聚合的方法; 随后（共）在水中或含有至少50重量％水和至少一种乳化剂的溶剂混合物中使所述一种或多种烯烃聚合。

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