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1. 发明授权

US4543305A Method of pretreating carbon black powder to improve cathode performance and lithium sulfuryl chloride cell including the pretreated carbon black powder 失效
公开(公告)号：US4543305A
公开(公告)日：1985-09-24
申请号：US715808
申请日：1985-03-25
申请人： Michael Binder , Charles W. Walker, Jr. , Eric R. Petersen , William L. Wade, Jr. , Sol Gilman
发明人： Michael Binder , Charles W. Walker, Jr. , Eric R. Petersen , William L. Wade, Jr. , Sol Gilman
IPC分类号： C09C1/56 , H01M4/36 , H01M6/14 , H01M4/96
CPC分类号： C09C1/56 , H01M4/36 , H01M6/14 , C01P2006/12 , C01P2006/40
摘要： Carbon black powder is pretreated with acetone or methanol prior to cathodeabrication to improve the cathode operating voltage and increase the cathode life of lithium sulfuryl chloride electrochemical cells.

2. 发明授权

US4514478A Method of making a porous carbon cathode, a porous carbon cathode so made, and electrochemical cell including the porous carbon cathode 失效
标题翻译：制造多孔碳阴极的方法，如此制造的多孔碳阴极和包括多孔碳阴极的电化学电池
公开(公告)号：US4514478A
公开(公告)日：1985-04-30
申请号：US640265
申请日：1984-08-13
申请人： Michael Binder , Eric R. Petersen , Charles W. Walker, Jr. , William L. Wade, Jr. , Sol Gilman
发明人： Michael Binder , Eric R. Petersen , Charles W. Walker, Jr. , William L. Wade, Jr. , Sol Gilman
IPC分类号： H01M4/96 , H01M6/14
CPC分类号： H01M4/96 , H01M6/14 , Y10T29/49108 , Y10T29/49115
摘要： A porous carbon cathode for use in an electrochemical cell is made by wetg the carbon black with a 1:1 to 1:3 mixture of isopropyl alcohol:water, adding a binding agent thereto, smearing the resulting stiff paste on a thin expanded metal screen and pressing and rolling to the desired thickness, drying the cathode sheet in a vacuum oven at about 100.degree. C. for one hour while a weight is placed above and below the cathode sheet which is sandwiched between two pieces of blotting paper, the total weight applied being sufficient for the cathode to retain structural integrity, removing the weight and blotting papers and inserting the cathode sheet in an elevated drying oven at about 280.degree. C. for about one hour, and cooling the cathode sheet between blotting paper, repressing and rolling. Cathodes prepared by this method appear structurally strong, maintain their physical integrity with a minimum of cracking and flaking, and do not crumble when cut. The porous carbon cathode is particularly advantageous when included in a lithium sulfuryl chloride cell, but can be used in any system requiring porous carbon cathodes.
摘要翻译：用于电化学电池的多孔碳阴极是通过用1:1:1:1:1:1:2的异丙醇：水的混合物润湿炭黑制成的，向其中加入粘结剂，将所得的硬糊涂抹在薄的金属扩孔并压制成所需的厚度，在真空烘箱中在约100℃下干燥阴极片1小时，同时将重量置于夹在两片吸印纸之间的阴极片的上下，总重量施加足以使阴极保持结构完整性，去除重量和吸印纸并将阴极片在约280℃的升高的干燥炉中插入约1小时，并在吸印纸，压制和轧制之间冷却阴极片。通过这种方法制备的阴极在结构上很强，在最小的开裂和剥落下保持其物理完整性，切割时不会破碎。当包含在锂磺酰氯单元中时，多孔碳阴极是特别有利的，但可以用于需要多孔碳阴极的任何系统中。

3. 发明授权

US4560628A High capacity inorganic oxyhalide electrochemical cell 失效
标题翻译：高容量无机卤氧化物电化学电池
公开(公告)号：US4560628A
公开(公告)日：1985-12-24
申请号：US653116
申请日：1984-09-21
申请人： Charles W. Walker, Jr. , William L. Wade, Jr. , Michael Binder , Sol Gilman
发明人： Charles W. Walker, Jr. , William L. Wade, Jr. , Michael Binder , Sol Gilman
IPC分类号： H01M6/14 , H01M4/36
CPC分类号： H01M6/14
摘要： A high capacity lithium inorganic oxyhalide electrochemical cell is provi including lithium as the anode, carbon as the cathode, and a solution of a quaternary ammonium salt in an inorganic oxyhalide solvent as the electrolyte.
摘要翻译：提供高容量的无机卤氧化锂电化学电池，其包括锂作为阳极，碳作为阴极，以及季铵盐在无机卤氧化物溶剂中的溶液作为电解质。

4. 发明授权

US4816080A Method of washing solids with liquified gases 失效
标题翻译：用液化气洗涤固体的方法
公开(公告)号：US4816080A
公开(公告)日：1989-03-28
申请号：US913794
申请日：1986-09-29
申请人： Michael Binder , Charles W. Walker, Jr. , Robert J. Mammone , William L. Wade, Jr. , Sol Gilman
发明人： Michael Binder , Charles W. Walker, Jr. , Robert J. Mammone , William L. Wade, Jr. , Sol Gilman
IPC分类号： B08B7/00 , B08B7/04
CPC分类号： B08B7/0021
摘要： Solid materials are easily washed with liquified gas by placing the solid terial to be washed in a dry vessel under an inert atmosphere, evacuating the vessel, introducing the low temperature liquified gas solvent into the vessel, allowing the washing of the solid by the liquified gas solvent, and removing the solvent by the application of vacuum.
摘要翻译：在惰性气氛下将待洗涤的固体物质置于干燥容器中，抽真空，将低温液化气体溶剂引入容器中，使液体气体洗涤固体，固体物料容易用液化气体洗涤溶剂，并通过真空除去溶剂。

5. 发明授权

US4078893A Catalyst system for the detection and elimination of hydrogen gas 失效
标题翻译：用于检测和消除氢气的催化剂体系
公开(公告)号：US4078893A
公开(公告)日：1978-03-14
申请号：US701273
申请日：1976-06-30
申请人： Sol Gilman , Paul J. Bramhall
发明人： Sol Gilman , Paul J. Bramhall
IPC分类号： B01J23/40 , B01J23/755 , C01B3/00 , C01B5/00 , G01N31/22 , H01M10/52 , B01J8/00 , H01M8/06
CPC分类号： H01M10/52 , B01J23/40 , B01J23/755 , C01B3/00 , C01B5/00 , G01N31/224
摘要： A catalyst system for the elimination of hydrogen gas which comprises a ptetrafluoroethylene-bonded catalyst layer of carbon mixed with platinum black, a porous polytetrafluoroethylene film on the side thereof which faces the gas flow, and a metal backplate, all integrally bonded together. The assembly is particularly useful for the elimination of hydrogen gas in sealed equipment housings, for example, those containing batteries. A similar system may also be used as a detector of hydrogen by utilizing a detector paper therewith which indicates the presence of water.
摘要翻译：用于消除氢气的催化剂体系包括与铂黑混合的聚四氟乙烯键合的催化剂层，面向气流的侧面的多孔聚四氟乙烯膜和金属背板，全部结合在一起。该组件对于在密封的设备外壳中除去氢气特别有用，例如包含电池的那些。也可以使用类似的系统作为氢的检测器，利用其中的检测器纸表示水的存在。

6. 依法登记的发明

USH457H Cathode for use in high energy primary thionyl chloride cell systems and high energy primary thionyl chloride cell systems including the cathode 失效
标题翻译：用于高能初级亚硫酰氯电池系统的阴极和包括阴极的高能初级亚硫酰氯电池系统
公开(公告)号：USH457H
公开(公告)日：1988-04-05
申请号：US768271
申请日：1985-08-22
申请人： Charles W. Walker, Jr. , William L. Wade, Jr. , Michael Binder , Sol Gilman
发明人： Charles W. Walker, Jr. , William L. Wade, Jr. , Michael Binder , Sol Gilman
IPC分类号： H01M4/66 , H01M6/14
CPC分类号： H01M4/663 , H01M6/14
摘要： A cathode is provided for use in high energy primary lithium-thionyl chloe cell systems or calcium-thionyl chloride cell systems. The cathode comprises an expanded metallic current collector screen into which has been pasted a mixture of a low surface area conductive carbon black and a high surface area conductive carbon black previously mixed with a binder.

7. 发明授权

US5783324A Fuel cell including a single sheet of a polymer electrolyte membrane (PEM), the PEM being divided into regions of varying electrical and ionic conductivity 失效
标题翻译：包括单片聚合物电解质膜（PEM）的燃料电池，所述PEM被分成具有不同电导率和离子电导率的区域
公开(公告)号：US5783324A
公开(公告)日：1998-07-21
申请号：US741755
申请日：1996-11-05
申请人： Michael Binder , Sol Gilman , Robert J. Mammone
发明人： Michael Binder , Sol Gilman , Robert J. Mammone
IPC分类号： H01M8/10 , H01M8/24
CPC分类号： H01M8/241 , H01M8/1007 , H01M2300/0082
摘要： A fuel cell is provided including a single sheet film or ribbon of any leh of a Polymer Electrolyte Membrane ("PEM") wherein the PEM is divided into regions or zones of varying electrical conductivity and ionic conductivity, allowing the elimination of endplates and/or a bipolar configuration. In this non bipolar arrangement, means are provided for distributing fuel to only one side of the PEM and oxidant to only the other side of the PEM so as to prevent mixing of the fuel and oxidant.
摘要翻译：提供了一种燃料电池，其包括任何长度的聚合物电解质膜（“PEM”）的单片膜或带，其中PEM被分成具有不同导电性和离子电导率的区域或区域，允许消除端板和/或双极配置。在这种非双极性配置中，提供了仅将PEM和氧化剂一侧的燃料分配到PEM的另一侧的装置，以防止燃料和氧化剂的混合。

8. 发明授权

US4526881A Method of pretreating carbon black powder to improve cathode performance and lithium sulfuryl chloride cell including the pretreated carbon black powder 失效
标题翻译：预处理炭黑粉末以改善阴极性能的方法和包括预处理炭黑粉末的锂磺酰氯电池
公开(公告)号：US4526881A
公开(公告)日：1985-07-02
申请号：US544770
申请日：1983-10-24
申请人： Michael Binder , Charles W. Walker, Jr. , Eric R. Petersen , William L. Wade, Jr. , Sol Gilman
发明人： Michael Binder , Charles W. Walker, Jr. , Eric R. Petersen , William L. Wade, Jr. , Sol Gilman
IPC分类号： C09C1/56 , H01M4/36 , H01M6/14 , B01J21/18 , C01B31/02
CPC分类号： C09C1/56 , H01M4/36 , H01M6/14 , C01P2006/12
摘要： Carbon black powder is pretreated with acetone or methanol prior to cathodeabrication to improve the cathode operating voltage and increase the cathode life of lithium sulfuryl chloride electrochemical cells.
摘要翻译：炭黑粉末在阴极制造之前用丙酮或甲醇预处理，以改善阴极工作电压并增加锂磺酰氯电化学电池的阴极寿命。

9. 发明授权

US4303604A Method of making a high rate carbon cathode 失效
标题翻译：制造高倍率碳阴极的方法
公开(公告)号：US4303604A
公开(公告)日：1981-12-01
申请号：US140369
申请日：1980-04-14
申请人： Sol Gilman
发明人： Sol Gilman
IPC分类号： H01M4/96 , B29D9/08
CPC分类号： H01M4/96
摘要： A high rate carbon cathode is made by mixing a carbon powder having a sure area of about 1000 square meters/gram with polytetrafluoroethylene and a sufficient amount of water to form a coherent mixture. The mixture is applied to an electrically conductive screen; the cathode formed while wet to an intermediate thickness, the cathode vacuum dried at about 100 degrees C., and the cathode cold compressed to obtain a final electrode porosity of greater than 80 percent. The cathode can be used in a lithium primary cell using a solution of an inorganic lithium salt in sulfuryl chloride as the electrolyte.
摘要翻译：通过将具有约1000平方米/克的表面积的碳粉与聚四氟乙烯和足量的水混合以形成粘性混合物来制备高速碳阴极。将混合物施加到导电屏幕上; 阴极在湿润至中间厚度的同时形成，阴极在约100℃下真空干燥，并将阴极冷压缩以获得大于80％的最终电极孔隙率。阴极可以使用无机锂盐在磺酰氯作为电解质的溶液在锂原电池中使用。

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