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1. 发明授权

US5424279A Pyrazole derivatives having herbicidal activity and their use 失效
标题翻译：具有除草活性的吡唑衍生物及其用途
公开(公告)号：US5424279A
公开(公告)日：1995-06-13
申请号：US270401
申请日：1994-07-05
申请人： Soji Sugai , Shigeru Mio , Toyokuni Honma , Takashi Sakamoto
发明人： Soji Sugai , Shigeru Mio , Toyokuni Honma , Takashi Sakamoto
IPC分类号： A01N47/38 , C07D231/18 , C07D231/28 , C07D233/90 , C07D401/12 , C07D403/12 , A01N43/56 , C07D231/20
CPC分类号： C07D401/12 , A01N47/38 , C07D231/18 , C07D231/28 , C07D403/12
摘要： Compounds of formula (I): ##STR1## (in which: R.sup.1 and R.sup.2 are each hydrogen, optionally substituted alkyl, optionally substituted alkenyl, alkynyl, alkoxy, aryl or pyridyl, or R.sup.1 and R.sup.2 together represent alkylene; A and B are each hydrogen, halogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkoxy, alkylthio, alkylsulfonyl, dialkylsulfamoyl, aliphatic carboxylic acyl, carboxy, --CONR.sup.a R.sup.b where R.sup.a and R.sup.b are each hydrogen or alkyl, formyl or cyano groups; D represents optionally substituted phenyl, benzyl, pyridyl or pyrimidinyl; and n is 0, 1 or 2; and salts and esters thereof) have valuable herbicidal properties, and, since they are totally innocuous to rice plants, are especially useful for the treatment of paddy fields.
摘要翻译：式（I）化合物：其中：R 1和R 2各自为氢，任选取代的烷基，任选取代的烯基，炔基，烷氧基，芳基或吡啶基，或者R 1和R 2一起表示亚烷基; A和 B各自为氢，卤素，任选取代的烷基，任选取代的烯基，任选取代的烷氧基，烷硫基，烷基磺酰基，二烷基氨磺酰基，脂族羧酸酰基，羧基，-CONR a R b，其中R a和R b各自为氢或烷基，甲酰基或氰基; D表示任选取代的苯基，苄基，吡啶基或嘧啶基; n为0,1或2;其盐和酯）具有有价值的除草性质，并且由于它们对水稻植物完全无害，特别适用于水田的处理。

2. 发明授权

US5736487A Aniline derivatives having herbicidal activity, their preparation and their use 失效
标题翻译：具有除草活性的苯胺衍生物及其制备及其应用
公开(公告)号：US5736487A
公开(公告)日：1998-04-07
申请号：US813174
申请日：1997-03-07
申请人： Soji Sugai , Hiroyuki Komai , Noriaki Kudo , Kazuo Sato , Toyokuni Honma , Junji Kadotani , Kiyoshi Koi , Mitsuru Ito
发明人： Soji Sugai , Hiroyuki Komai , Noriaki Kudo , Kazuo Sato , Toyokuni Honma , Junji Kadotani , Kiyoshi Koi , Mitsuru Ito
IPC分类号： A01N43/74 , A01N47/20 , C07D263/56 , C07D277/64 , A01N43/76 , A01N43/78
CPC分类号： C07D263/56 , A01N43/74 , A01N47/20 , C07D277/64
摘要： Compounds of formula (I): ##STR1## (wherein: R.sup.1 is optionally substituted alkyl, cycloalkyl, optionally substituted alkoxy, or optionally substituted alkylthio; R.sup.2 is hydrogen, optionally substituted alkyl, cycloalkyl, optionally substituted alkenyl, optionally substituted alkynyl or a group of formula --YR.sup.7 ; R.sup.3 is optionally substituted alkyl, cycloalkyl, optionally substituted alkoxy group, optionally substituted alkenyl, optionally substituted alkynyl, halogen, nitro or a group of formula --COR.sup.8, wherein R.sup.8 is hydrogen, alkyl, cycloalkyl or alkoxy; R.sup.4 and R.sup.5 are each hydrogen atom or alkyl; R.sup.6 is optionally substituted alkyl, cycloalkyl, optionally substituted alkoxy group, optionally substituted alkenyl, optionally substituted alkynyl, halogen, nitro, or a group of formula --COR.sup.8, as defined above; A, Q and X are each oxygen or sulfur; Y is a group of formula --CO--, --COO--, --CH.sub.2 O--, --CH.sub.2 S--, --CH.sub.2 CH.sub.2 O--, --CH.sub.2 CH.sub.2 S--, --CH.sub.2 CO--, --CH.sub.2 COO--, --CH(Me)COO--, --CH.sub.2 CH.sub.2 CO--, --CH.sub.2 OCO--, CH.sub.2 OCOO-- and --CH.sub.2 CH.sub.2 OCO--; R.sup.7 is optionally substituted alkyl group, cycloalkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted aryl, optionally substituted aralkyl, or an optionally substituted heterocycle; and m and n are each an integer from 0 to 4; and herbicidally acceptable addition salts thereof) are useful as herbicides.
摘要翻译：式（I）化合物：其中：R 1为任选取代的烷基，环烷基，任选取代的烷氧基或任选取代的烷硫基; R 2为氢，任选取代的烷基，环烷基，任选取代的烯基，任选取代的炔基或式-YR 7的基团; R 3是任选取代的烷基，环烷基，任选取代的烷氧基，任选取代的烯基，任选取代的炔基，卤素，硝基或式-COR 8的基团，其中R 8是氢，烷基，环烷基或烷氧基 R 4和R 5各自为氢原子或烷基; R 6为任选取代的烷基，环烷基，任选取代的烷氧基，任选取代的烯基，任选取代的炔基，卤素，硝基或如上定义的式-COR 8基团; Q和X各自是氧或硫; Y是式-CO-，-COO-，-CH2O-，-CH2S-，-CH2CH2O-，-CH2CH2S-，-CH2CO-，-CH2COO-，-CH（ Me）COO - ， - CH 2 CH 2 CO - ， - CH 2 OCO - ，CH 2 OOO-和-CH 2 CH 2OCO-; R 7是任选取代的烷基，环烷基，任选取代的烯基，任选取代的炔基，任选取代的芳基，任选取代的芳烷基或任选取代的杂环; m和n分别为0〜4的整数。和除草剂可接受的加成盐）可用作除草剂。

3. 发明授权

US5276033A 13-(substituted thio)acetoxymilbemycin derivatives, their preparation and their agrochemical uses 失效
标题翻译： 13-（取代硫代）乙酰氧基米尔伯霉素衍生物，其制备方法及其农用化学品用途
公开(公告)号：US5276033A
公开(公告)日：1994-01-04
申请号：US992865
申请日：1992-12-17
申请人： Toshiaki Yanai , Soji Sugai , Hideo Takeshiba , Junzo Tobitsuka , Kazuo Sato , Shinji Yokoi , Shinya Niimi , Akio Saito
发明人： Toshiaki Yanai , Soji Sugai , Hideo Takeshiba , Junzo Tobitsuka , Kazuo Sato , Shinji Yokoi , Shinya Niimi , Akio Saito
IPC分类号： A01N43/90 , A01P7/04 , C07D493/22 , C07H19/01 , A61K31/53 , A61K31/505 , C07D239/38
CPC分类号： C07H19/01 , A01N43/90
摘要： Compounds having the formula (I) ##STR1## wherein: R.sup.1 is methyl, ethyl or isopropyl; R.sup.2 is alkyl, aralkyl, cycloalkyl, cycloalkylmethyl, aryl, heterocyclic, or heterocyclic-substituted thio; R.sup.3 is hydrogen, methyl or ethyl; or R.sup.2 together with R.sup.3 is --(CH.sub.2).sub.n --, wherein n is 3,4 or 5; and A is aromatic heterocyclic; and salts thereof, are valuable agricultural and horticultural anthelmintic, acaricidal and insecticidal agents.
摘要翻译：具有式（I）的化合物（I）其中：R1是甲基，乙基或异丙基; R2是烷基，芳烷基，环烷基，环烷基甲基，芳基，杂环或杂环取代的硫代; R3是氢，甲基或乙基; 或R 2与R 3一起为 - （CH 2）n - ，其中n为3,4或5; A是芳族杂环; 和其盐是有价值的农业和园艺驱虫剂，杀螨剂和杀虫剂。

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