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    • 4. 发明授权
    • Carbon material for lithium ion secondary battery
    • 锂离子二次电池用碳素材料
    • US08647776B2
    • 2014-02-11
    • US13214356
    • 2011-08-22
    • Shunsuke YamadaKeita YamaguchiTaisuke NoseHideharu Sato
    • Shunsuke YamadaKeita YamaguchiTaisuke NoseHideharu Sato
    • H01M4/583C01B31/04
    • H01M4/133C01B32/05C01B32/20C01P2002/82C01P2004/51C01P2006/11C01P2006/12C01P2006/20H01M4/1393H01M4/587H01M10/0525
    • To provide a negative electrode material capable of giving a lithium ion secondary battery that is sufficiently small in the charge/discharge irreversible capacity observed at the initial cycle stage, has excellent high-temperature storage characteristics, and reduced in the gas generation at the initial cycle stage as well as during high-temperature storage.A carbon material for lithium ion secondary battery, wherein the surface functional group amount O/C value represented by the following formula 1 is from 1 to 4% and the sum (Cl/C+S165/C) of the surface functional group amount Cl/C value represented by the following formula 2 and the surface functional group amount S165/C value represented by the following formula 3 is from 0.05 to 0.5%: O/C value (%)=O atom concentration determined based on the peak area of the spectrum of O1s in X-ray photoelectron spectroscopy (XPS) analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100  Formula 1: Cl/C value (%)=Cl atom concentration determined based on the peak area of the spectrum of Cl2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100  Formula 2: S165/C value (%)=S165 atom concentration based on the peak area of the peak near 165 eV in the spectrum corresponding to S2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100  Formula 3.
    • 为了提供能够提供在初始循环阶段观察到的充放电不可逆容量足够小的锂离子二次电池的负极材料,具有优异的高温储存特性,并且在初始循环中减少了气体产生 阶段以及高温储存期间。 一种锂离子二次电池用碳材料,其中由下式1表示的表面官能团量O / C值为1〜4%,表面官能团量Cl(C 1 / C 6) 由下式2表示的/ C值和由下式3表示的表面官能团量S165 / C值为0.05〜0.5%:O / C值(%)=基于峰面积确定的O原子浓度 基于XPS分析中的C1s光谱的峰面积确定的X射线光电子能谱(XPS)分析中的O1的光谱/ C原子浓度×100方法1:Cl / C值(%)=基于 基于XPS分析中的C1s谱的峰面积确定的XPS分析/ C原子浓度中的Cl2p的峰面积×100第2:S165 / C值(%)= S165原子浓度,基于峰面积 在XPS分析中对应于S2p的光谱中,165 eV附近的峰值 基于XPS分析中的C1s光谱的峰面积确定sis / C原子浓度×100第3期。
    • 9. 发明申请
    • CARBON MATERIAL FOR LITHIUM ION SECONDARY BATTERY
    • 用于锂离子二次电池的碳材料
    • US20120070733A1
    • 2012-03-22
    • US13214356
    • 2011-08-22
    • Shunsuke YamadaKeita YamaguchiTaisuke NoseHideharu Sato
    • Shunsuke YamadaKeita YamaguchiTaisuke NoseHideharu Sato
    • H01M4/583H01M4/64
    • H01M4/133C01B32/05C01B32/20C01P2002/82C01P2004/51C01P2006/11C01P2006/12C01P2006/20H01M4/1393H01M4/587H01M10/0525
    • To provide a negative electrode material capable of giving a lithium ion secondary battery that is sufficiently small in the charge/discharge irreversible capacity observed at the initial cycle stage, has excellent high-temperature storage characteristics, and reduced in the gas generation at the initial cycle stage as well as during high-temperature storage.A carbon material for lithium ion secondary battery, wherein the surface functional group amount O/C value represented by the following formula 1 is from 1 to 4% and the sum (Cl/C+S165/C) of the surface functional group amount Cl/C value represented by the following formula 2 and the surface functional group amount S165/C value represented by the following formula 3 is from 0.05 to 0.5%:Formula 1: O/C value (%)=O atom concentration determined based on the peak area of the spectrum of O1s in X-ray photoelectron spectroscopy (XPS) analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100 Formula 2: Cl/C value (%)=Cl atom concentration determined based on the peak area of the spectrum of Cl2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100 Formula 3: S165/C value (%)=S165 atom concentration based on the peak area of the peak near 165 eV in the spectrum corresponding to S2p in XPS analysis/C atom concentration determined based on the peak area of the spectrum of C1s in XPS analysis×100.
    • 为了提供能够提供在初始循环阶段观察到的充放电不可逆容量足够小的锂离子二次电池的负极材料,具有优异的高温储存特性,并且在初始循环中减少了气体产生 阶段以及高温储存期间。 一种锂离子二次电池用碳材料,其中由下式1表示的表面官能团量O / C值为1〜4%,表面官能团量Cl(C 1 / C 6) / C值,由下式3表示的表面官能团量S165 / C值为0.05〜0.5%:式1:O / C值(%)=基于 X射线光电子能谱(XPS)分析中的O1谱的峰面积/基于XPS分析中的C1s的光谱峰面积确定的C原子浓度×100式2:Cl / C值(%)= Cl原子 基于XPS分析中的C1s谱的峰面积确定的XPS分析/ C原子浓度中的Cl2p的峰面积确定的浓度×100式3:S165 / C值(%)= S165原子浓度 在对应于S2p的光谱中,在165eV附近的峰的峰面积 在XPS分析中,基于XPS分析中C1s的光谱峰面积确定的X原子浓度×100。