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    • 5. 发明申请
    • Latent doping of conducting polymers
    • 导电聚合物的潜在掺杂
    • US20070065590A1
    • 2007-03-22
    • US11496024
    • 2006-07-31
    • Shawn WilliamsDarin LairdCaton GoodmanChristopher GrecoJaideep Rajput
    • Shawn WilliamsDarin LairdCaton GoodmanChristopher GrecoJaideep Rajput
    • C08G75/00B05D3/02
    • H01L51/002C08L65/00H01B1/127H01L51/0003H01L51/0036H01L51/5048H01L51/5052Y02E10/549
    • Latent doping is provided wherein a conducting polymer is mixed with a dopant in solution without the doping reaction occurring unless solvent is removed. Regioregular polythiophenes are a particularly important embodiment. A composition comprising (i) at least one polymer comprising conjugation in the polymer backbone, (ii) at least one dopant for the polymer, (iii) at least one solvent for the polymer and latent dopant, wherein the polymer, the latent dopant, and the solvent are formulated so that the latent dopant does not substantially dope the polymer when formulated, but does substantially react with the polymer when the solvent is removed. Formulation of the composition can comprise adjusting the order of mixing, the amounts of the components, and the temperature. Methods of formulating the compositions and methods of using the compositions are also provided. OLED, PLED, photovoltaic, and other organic electronic devices can be fabricated.
    • 提供潜在掺杂,其中除非除去溶剂,否则导电聚合物与溶液中的掺杂剂混合而不发生掺杂反应。 区域聚噻吩是特别重要的实施方案。 一种组合物,其包含(i)至少一种包含在聚合物主链中共轭的聚合物,(ii)聚合物的至少一种掺杂剂,(iii)至少一种用于聚合物和潜在掺杂剂的溶剂,其中聚合物,潜在掺杂剂, 并且配制溶剂使得潜在掺杂剂在配制时基本上不掺杂聚合物,但当除去溶剂时基本上与聚合物反应。 组合物的配方可以包括调节混合的顺序,组分的量和温度。 还提供了配制组合物的方法和使用组合物的方法。 可以制造OLED,PLED,光电和其它有机电子器件。